Manganese dissolution from LiMn2O4 cathodes at elevated temperature: methylene methanedisulfonate as electrolyte additive
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- 作者：Renheng Wang ; Xinhai Li ; Zhixing Wang…
- 关键词：Methylene methanedisulfonate ; Non ; aqueous electrolyte ; Elevated temperature ; Lithium manganese oxide spinel
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：20
- 期：1
- 页码：19-28
- 全文大小：3,165 KB
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Xinhai Li (1)
Zhixing Wang (1)
Huajun Guo (1)
1. School of Metallurgy and Environment, Central South University, Changsha, 410083, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
Diethyl carbonate (DEC) electrolyte decomposition reactions resulting from PF5 attacked produce HF by several side reaction steps. The resulting HF can dissolve the Mn from spinel-type lithium manganese oxide (LiMn2O4). To verify that methylene methanedisulfonate (MMDS) suppress Mn3+ dissolution mechanism of lithium manganese oxide spinel cathode using methylene methanedisulfonate as electrolyte additive at elevated temperature, a DEC-based electrolyte using MMDS as electrolyte additive is developed in this work. The linear sweep voltammetry (LSV) indicates the start oxidation potential of the electrolyte with 0.5 wt% MMDS is around 3.83 V (vs. Li/Li+), which is lower than the control (4.12 V). Self-discharge and inductively coupled plasma-atomic emission spectrometry (ICP-AES) reveal that Mn3+ dissolution from the spinel cathode is hindered. The results of electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) demonstrate that MMDS would help to form the stable passivation film, which would effectively suppress to oxidize the control electrolyte solvents and HF generation is suppressed, and result in less Mn3+ dissolution from the spinel cathode.