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Degradability of chlorophenols using ferrate(VI) in contaminated groundwater
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  • 作者:M. Homolková ; P. Hrabák ; M. Kolář…
  • 关键词:Degradability ; Ferrate ; Fe(VI) ; Pentachlorophenol ; Chlorophenols ; Complex contaminated water
  • 刊名:Environmental Science and Pollution Research
  • 出版年:2016
  • 出版时间:January 2016
  • 年:2016
  • 卷:23
  • 期:2
  • 页码:1408-1413
  • 全文大小:319 KB
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  • 作者单位:M. Homolková (1)
    P. Hrabák (1)
    M. Kolář (2)
    M. Černík (1)

    1. Faculty of Mechatronics, Informatics and Interdisciplinary Studies & Institute for Nanomaterials, Advanced Technologies and Innovations, Technical University of Liberec, Studentská 1402/2, Liberec, 461 17, Czech Republic
    2. Regional Centre of Advanced Technologies and Materials, Palacký University in Olomouc, Šlechtitelů 11, 783 71, Olomouc, Czech Republic
  • 刊物类别:Earth and Environmental Science
  • 刊物主题:Environment
    Environment
    Atmospheric Protection, Air Quality Control and Air Pollution
    Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
    Industrial Pollution Prevention
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1614-7499
文摘
The production and use of chlorophenolic compounds in industry has led to the introduction of many xenobiotics, among them chlorophenols (CPs), into the environment. Five CPs are listed in the priority pollutant list of the U.S. EPA, with pentachlorophenol (PCP) even being proposed for listing under the Stockholm Convention as a persistent organic pollutant (POP). A green procedure for degrading such pollutants is greatly needed. The use of ferrate could be such a process. This paper studies the degradation of CPs (with an emphasis on PCP) in the presence of ferrate both in a spiked demineralized water system as well as in real contaminated groundwater. Results proved that ferrate was able to completely remove PCP from both water systems. Investigation of the effect of ferrate purity showed that even less pure and thus much cheaper ferrate was applicable. However, with decreasing ferrate purity, the degradability of CPs may be lower. Keywords Degradability Ferrate Fe(VI) Pentachlorophenol Chlorophenols Complex contaminated water

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