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• 作者：L. Kh. Minacheva (1)
  V. E. Baulin (2) (3)
  I. S. Ivanova (1)
  E. N. Pyatova (1)
  I. P. Kalashnikova (2)
  A. V. Churakov (1)
  V. S. Sergienko (1)
  A. Yu. Tsivadze (3)
  
• 刊名：Russian Journal of Inorganic Chemistry
• 出版年：2013
• 出版时间：August 2013
• 年：2013
• 卷：58
• 期：8
• 页码：919-927
• 全文大小：315KB
• 参考文献：1. V. E. Baulin, L. Kh. Minacheva, I. S. Ivanova, et al., Russ. J. Inorg. Chem. 56, 1222 (2011). CrossRef
  2. V. E. Baulin, L. Kh. Minacheva, I. S. Ivanova, et al Russ. J. Inorg. Chem. 57, 802 (2012). CrossRef
  3. V. E. Baulin, L. Kh. Minacheva, I. S. Ivanova, et al., Russ. J. Inorg. Chem. 56, 1232 (2011). CrossRef
  4. A. Yu. Tsivadze, V. E. Baulin, D. V. Baulin, et al., RF Patent No. 2391349, Byul. Izobret., no. 16 (2010).
  5. L. Kh. Minacheva, I. S. Ivanova, I. K. Kireeva, et al., Russ. J. Inorg. Chem. 45, 1184 (2000).
  6. E. A. Materova, A. L. Grekovich, and S. U. Didina, Elektrokhimiya 8, 1829 (1972).
  7. Recommendations for nomenclature of ion-selective electrodes, Pure Appl. Chem. 48, 127 (1976).
  8. G. M. Sheldrick, SADABS, Program for Scaling and Correction of Area Detector Data, Univ. of G?ttingen, G?ttingen, Germany, 1997.
  9. G. M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, Univ. of G?ttingen, G?ttingen, Germany, 1997.
  10. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, Univ. of G?ttingen, G?ttingen, Germany, 1997.
  11. / Host-Guest Complex Chemistry: Synthesis, Structures, Applications, Ed. by F. Vogtle and E. Weber (Spinger, Berlin, 1984; Mir, Moscow, 1988).
  12. N. G. Bokii, Yu. T. Struchkov, A. E. Kalinin, et al., Itogi Nauki Tekh., Ser. Kristallokhim. 12, 82 (1977).
  13. Y. Ruban and V. Zabel, Crys. Struct. Commun. 5, 671 (1976).
  14. C. P. Brock, W. B. Schweizer, and J. D. Dunitz, J. Am. Chem. Soc. 107, 6964 (1985). CrossRef
  15. A. L. Spek, Acta Crystallogr. Sect. C 43, 1233 (1987). CrossRef
  16. I. S. Ivanova, V. V. Dorokhov, E. N. Pyatova, et al., Russ. J. Coord. Chem. 31, 151 (2005). CrossRef
  17. K. Kumura, H. Tamura, and T. Shono, J. Electroanal. Chem. 105, 335 (1979). CrossRef
  18. V. E. Baulin, I. S. Ivanova, E. N. Pyatova, et al., Russ. J. Inorg. Chem. 57, 1443 (2012). CrossRef
  19. V. E. Baulin, M. A. Kiskin, I. S. Ivanova, et al., Russ. J. Inorg. Chem. 57, 671 (2012). CrossRef
  20. I. K. Kireeva, N. B. Generalova, V. A. Trofimov, et al., Zh. Neorg. Khim. 36, 1464 (1991).
  21. I. A. Charushnikova, V. E. Baulin, M. A. Fedoseev, et al., Russ. J. Coord. Chem. 36, 148 (2010). CrossRef
  
• 作者单位：L. Kh. Minacheva (1)
  V. E. Baulin (2) (3)
  I. S. Ivanova (1)
  E. N. Pyatova (1)
  I. P. Kalashnikova (2)
  A. V. Churakov (1)
  V. S. Sergienko (1)
  A. Yu. Tsivadze (3)
  
  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
  2. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia
  3. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
  

文摘

The synthesis of 1,5-bis(2-dihydroxyphosphoryl-4-ethylphenoxy)-3-oxapentane [(HO)2(O)P(C6H3CH2CH3)(OCH2CH2)2O(C6H3CH2CH3)P(O)(OH)2] (H4K2) and single crystal X-ray diffraction study of H4K2 · 2H2O (I) are described. The crystals are orthorhombic, a = 33.291(4) ?, b = 8.9374(10) ?, c = 8.1021(9) ?, V = 2410.6(5) ?3, Z = 4, space group Cmc21, R = 0.0484 for 2566 reflections with I > 2σ(I). In I, the molecules of H4K2 are hydrogen-bonded to two crystallographically independent H2O molecules to give neutral conglomerates H4K2 · 2H2O. The electroanalytical characteristics of poly(vinyl chloride) membranes based on H4K2 were tested. Cu2+ and Zn2+ complexes with H4K2 and Er3+, Nd3+, and complexes with H4K2, 1,5-bis[2-(dihydroxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane, 1,5-bis[2-(dihydroxyphosphinyl)phenoxy]-3-oxapentane, and 1,8-bis[2-(dihydroxyphosphinyl)phenoxy]-3,6-dioxaoctane were prepared.