• journal_title：American Mineralogist
• Contributor：Ernesto Mesto ; Emanuela Schingaro ; Fernando Scordari ; Luisa Ottolini
• Publisher：Mineralogical Society of America
• Date：2006-
• Format：text/html
• Language：en
• Identifier：10.2138/am.2006.1882
• journal_abbrev：American Mineralogist
• issn：0003-004X
• volume：91
• issue：1
• firstpage：182
• section：Articles

Mt. Vulture trioctahedral micas-1M mainly consist of phlogopite-annite solid solutions with a minor component of brittle micas. However, both Li-free and Li- and F-rich compositions may coexist in the same volcano-stratigraphic level. We report the results of electron microprobe analysis (EMPA), secondary ion mass spectrometry (SIMS), and single-crystal X-ray diffraction (SCXRD) for three crystals (LC7-27Go, LC7-3Go, and LC7-1R) that are representative of both compositions.

EMPA and SIMS showed that sample LC7-1R is richer in TiO₂ , Li₂O, and F and poorer in H₂O than the other samples.

Structure refinements using anisotropic displacement parameters for the three samples, performed in space group C2/m, converged at 3.46 ≤ R ≤ 4.34, 3.89 ≤ R_w ≤ 4.39. When considering bond distances, the three samples can be described as homo-octahedral whereas mean atomic numbers suggest that only LC7-1R is meso-octahedral. Significant differences occur among the samples for some distortion parameters commonly used for micas. In particular, LC7-1R displays higher values of BLD_M2, shift_M2 and lower values of Δ_K-O4 and t_K-O4 than those of samples LC7-3Go and LC7-27Go. These differences are ascribed to F- and Ti-substitutions.

Cation distributions were obtained by combining EMPA, SIMS, and SCXRD data after analysis of the effect of normalization schemes commonly used in mica formula recalculation. In LC7-3Go and LC7-27Go, Ti is incorporated according to the Ti-Tschermak mechanism, whereas more than one Ti-substitution mechanism occurs in LC7-1R. For the latter sample, octahedral vacancies are present leading to a complex substitution pattern and complex structural distortions related to the special octahedral compositions that were determined.