Risk-based characterization of contaminated industrial sites using a multivariate statistical and GIS-based approach in Anniston,Alabama .

详细信息   

• 作者：Ha ; HoeHun.
• 学历：Doctor
• 年：2011
• 关键词：soil and serum PCBs ; socioeconomic status ; contami
• 导师：Rogerson, Peter,eadvisorOlson, Jamesecommittee memberBian, Lingecommittee member
• 毕业院校：State University of New York
• Department：Geography
• ISBN：9781124934716
• CBH：3475321
• Country：USA
• 语种：English
• FileSize：17654285
• Pages：181

文摘

Polychlorinated biphenyls PCBs) were produced in Anniston, AL, and used in various commercial applications from 1929 until their ban in the mid-1970s due to concerns about their environmental and biological persistence and toxicity. The principle objective of this dissertation is to identify socioeconomic and spatial patterns, trends and the distributions of soil PCBs and heavy metals, and serum PCBs in Anniston, AL using Geographic Information Systems GIS) and spatial statistics. The study is based on EPA soil data, and Anniston Community Health Survey ACHS) data and neurocognitive data both derived from Agency for Toxic Substance and Disease Registry ATSDR). This study hypothesizes that increased levels of both soil and serum PCBs are related to increased exposures of residents to pollution sources, residential locations, and low socioeconomic status. An association is suspected between the unusually high levels of soil and serum PCBs and potential contaminating sources Monsanto plant and its nearest streams). The spatial distribution of both soil and serum PCBs in the study area is heterogeneous. Two-spatial regression models show statistically significant associations between proximity of residential property to potential contaminating sources and increased levels of both soil and serum PCBs. Living in poor neighborhoods and low socioeconomic status communities in Anniston has higher risks of soil PCB exposure and potentially results in increased levels of PCBs in their serum. Two community health studies conducted based on population-based survey data constituted sources of information for this dissertation. In the first health study, serum from 766 ACHS adult participants was analyzed for a total of thirty five ortho-substituted PCBs by the Center for Disease Control and Preventions National Center for Environmental Health laboratory. The second study consists of serum PCB levels for 321 children residing in Anniston and neighbouring communities. Comparisons of these studies at varying distances from suspected sources of contamination reveals a significantly positive association between soil PCB levels and levels of PCBs in serum of subjects residing near the suspected sources of contamination. In the two health studies, residents living in close proximity to the Monsanto plant and its nearest streams show significant associations between soil and serum PCB levels r＞ 0.50, p＝0.009 for the ACHS and r＞ 0.62, p＝0.001 for the neurocognitive study). This study also hypothesizes that the spatial distribution of 11 heavy metals in the soil is generally non-homogeneous and that their potential sources are different. Three clusters that share similar distribution patterns and suspected sources of heavy metal pollution were detected using Principal Component Analysis PCA) and Self Organizing Map SOM) methods. Soil Pb lead), Cd cadmium), Cu copper) and Zn zinc) are primarily attributed to anthropogenic activities, such as operations of chemical foundries and major railroads, whereas the presence of Co cobalt) and Mn manganese), and V vanadium) alone are also associated with natural sources such as soil texture, pedogenesis and soil hydrology. A Geographically Weighted Regression GWR) model also found statistically significant associations between soil lead concentrations and anthropogenic activities metal casting foundry and railroads).