有机硅耐高温涂料的研究进展
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摘要
主要介绍了有机硅耐高温涂料的耐高温机理,阐述了纯有机硅涂料、改性有机硅涂料和有机-无机复合涂料的研究情况,讨论了颜填料对耐高温涂层性能的影响,并展望了有机硅耐高温涂料的发展趋势。
The mechanism of the silicone high temperature resistant coatings is introduced.And the research progress in the pure silicone coatings,modified silicone coatings and inorganic-organic hybrid coatings is reviewed. The influences of the different pigment and filler on the heat resistant property of the coatings are discussed. Finally,the future trends of the high temperature resistant coatings are given.
The mechanism of the silicone high temperature resistant coatings is introduced.And the research progress in the pure silicone coatings,modified silicone coatings and inorganic-organic hybrid coatings is reviewed. The influences of the different pigment and filler on the heat resistant property of the coatings are discussed. Finally,the future trends of the high temperature resistant coatings are given.
引文
[1]冯海猛,王力.有机硅耐高温涂料的研究进展[J].化工文摘,2008(6):29-30.
[2]孙振红,周晓红,孙玲,等.耐高温有机硅涂料的研制[J].上海涂料,2011,49(3):14-17.
[3]沈孝忠,王兆安,田育廉.有机硅耐高温涂料防腐蚀性能分析[J].涂料工业,2004,34(5):48-50.
[4]杨宏波,刘朝辉,丁逸栋,等.金属表面耐高温防腐涂料的研究进展[J].表面技术,2017,46(3):216-222.
[5]JOVANOVIC J D,GOVEDARICA M N,DVORNIC P R,et al.The thermogravimetric analysis of some polysiloxanes[J].Polymer Degradation and Stability,1998,61(1):87-93.
[6]黎春阳,李国军,樊欣,等.耐高温甲基苯基硅树脂的合成[J].有机硅材料,2016,30(1):5-10.
[7]施彦斌.环氧改性有机硅涂料的制备及性能研究[D].北京:北京化工大学,2006.
[8]陈琳.有机硅基耐高温涂层研究[D].哈尔滨:哈尔滨工业大学,2011.
[9]冯海猛.环氧-有机硅涂料的制备与耐热性能的研究[D].青岛:山东科技大学,2009.
[10]王海侨,李营,苟国立,等.有机硅耐高温涂料二次成膜机理的探讨[J].涂料工业,2005,35(10):17-20.
[11]何岩.有机-无机复合型防腐耐高温涂料的制备与研究[D].大连,大连交通大学,2014.
[12]孙举涛,黄玉东,曹海琳,等.耐高温有机硅树脂的合成及其耐热和固化性能研究[J].航空材料学报,2005,25(1):25-29.
[13]金晶,徐晓秋,杨雄发,等.聚硅氧烷热稳定性研究进展[J].化工新型材料,2010,38(1):17-19.
[14]ZHOU W,YANG H,GUO X,et al.Thermal degradation behaviors of some branched and linear polysiloxanes[J].Polymer Degradation and Stability,2006,91(7):1471-1475.
[15]张翠梅.梯形聚甲基/苯基倍半硅氧烷耐高温涂料的制备和性能测试[J].现代涂料与涂装,2007,10(3):10-12.
[16]高萌,刘兰轩,汪洋,等.耐高温有机硅树脂的制备及其涂层的性能研究[J].上海涂料,2017,55(3):20-23.
[17]王海侨,李营,荀国立,等.有机硅耐高温涂料的研究[J].北京化工大学学报(自然科学版),2006,33(1):59-62.
[18]马克超,姜逸倩,柳艳君,等.甲基苯基硅树脂的制备及其在耐高温涂料中的应用[J].现代化工,2013,33(4):91-94.
[19]安娜.耐高温耐腐蚀改性聚氨酯有机硅涂层的合成和表征[D].北京:北京化工大学,2012.
[20]郭斌,陈战利,高勇,等.常温固化有机硅/聚氨酯耐高温涂料的制备及性能研究[J].现代涂料与涂装,2009,12(8):19-20.
[21]RODRGUEZ R,ALARCN C D L H,EKANAYAKE P,et al.Correlation of silicone incorporation into hybrid acrylic coatings with the resulting hydrophobic and thermal properties[J].Macromolecules,2008,41(22):8537-8546.
[22]黄东勤,张子勇.含有机硅和丙烯酸树脂的有机-无机杂化涂料[J].涂料工业,2006,36(2):25-28.
[23]王峥,郝超伟,马清芳,等.国内有机硅耐高温涂料研究进展[J].杭州师范大学学报(自然科学版),2011,10(6):510-513.
[24]TAO Z,YANG S,CHEN J,et al.Synthesis and characterization of imide ring and siloxane-containing cycloaliphatic epoxy resins[J].European Polymer Journal,2007,43(4):1470-1479.
[25]刘强,杜传芹,任卫东.环氧有机硅耐高温涂料的性能研究及应用探讨[J].涂料技术与文摘,2016,37(11):33-36.
[26]廉卫珍,张国梁,马春风,等.耐高温防腐隔热涂料的制备与性能[J].高分子材料科学与工程,2017,33(6):152-156.
[27]刘仲阳,孔志元,何庆迪,等.水性聚有机硅氧烷仿陶瓷涂料的研究进展[J].有机硅材料,2014,28(3):227-331.
[28]YOSHINAGA I,YAMADA N,KATAYAMA S.Effect of inorganic components on thermal stability of methylsiloxane-based inorganic/orgnaic hybrids[J].Journal of Sol-Gel Science and Technology,2005,35(1):21-26.
[29]董洪亮.有机硅改性硅溶胶复合涂料的制备与性能研究[D].大连,大连交通大学,2009.
[30]赵红梅,甘礼华,刘明贤,等.硅铝复合树脂的制备及其涂层性能[J].合成树脂及塑料,2012,29(3):14-17.
[31]SCHIAVON M A,ARMELIN N A,YOSHIDA I V P.Novel poly(borosiloxane)precursors to amorphous Si BCOceramics[J].Materials Chemistry and Physics,2008,112(3):1047-1054.
[32]李力锋.一种瓷膜涂料及其生产方法:中国,CN101445677A[P].2009-06-03.
[33]范琳.有机硅陶瓷化耐高温涂层的制备及附着力改善[D].大连,大连理工大学,2017.
[34]肖业鹏,冯伟,周立清,等.耐高温颜填料的种类及其应用[J].广州化工,2013,41(8):22-24.
[35]王荣国,李二明,史崇明.W-800℃有机硅耐高温涂料配方研究[J].河北化工,2005,(5):51-52.
[36]ZHAO J,LUO W,QI L,et al.The high-temperature resistance properties of polysiloxane/Al coatings with low infrared emissivity[J].Coatings,2018,8(4):125.
[37]刘宏宇,张松.室温自干型有机硅耐高温涂料的研究[J].有机硅材料,2009,23(6):375-378.
[38]GIAVERI S,GRONCHI P,BARZONI A.IPN polysiloxane-epoxy resin for high temperature coatings:structure effects on layer performance after 450℃treatment[J].Coatings,2017,7(12):213.
[39]邓天彩,区卓琨.耐高温防腐涂料的研究[J].科技创新导报,2012(16):6-7.
[40]孙振红,李华明,周晓红,等.W61-800各色有机硅耐高温涂料研究[J].中国涂料,2011,26(12):34-36.
[2]孙振红,周晓红,孙玲,等.耐高温有机硅涂料的研制[J].上海涂料,2011,49(3):14-17.
[3]沈孝忠,王兆安,田育廉.有机硅耐高温涂料防腐蚀性能分析[J].涂料工业,2004,34(5):48-50.
[4]杨宏波,刘朝辉,丁逸栋,等.金属表面耐高温防腐涂料的研究进展[J].表面技术,2017,46(3):216-222.
[5]JOVANOVIC J D,GOVEDARICA M N,DVORNIC P R,et al.The thermogravimetric analysis of some polysiloxanes[J].Polymer Degradation and Stability,1998,61(1):87-93.
[6]黎春阳,李国军,樊欣,等.耐高温甲基苯基硅树脂的合成[J].有机硅材料,2016,30(1):5-10.
[7]施彦斌.环氧改性有机硅涂料的制备及性能研究[D].北京:北京化工大学,2006.
[8]陈琳.有机硅基耐高温涂层研究[D].哈尔滨:哈尔滨工业大学,2011.
[9]冯海猛.环氧-有机硅涂料的制备与耐热性能的研究[D].青岛:山东科技大学,2009.
[10]王海侨,李营,苟国立,等.有机硅耐高温涂料二次成膜机理的探讨[J].涂料工业,2005,35(10):17-20.
[11]何岩.有机-无机复合型防腐耐高温涂料的制备与研究[D].大连,大连交通大学,2014.
[12]孙举涛,黄玉东,曹海琳,等.耐高温有机硅树脂的合成及其耐热和固化性能研究[J].航空材料学报,2005,25(1):25-29.
[13]金晶,徐晓秋,杨雄发,等.聚硅氧烷热稳定性研究进展[J].化工新型材料,2010,38(1):17-19.
[14]ZHOU W,YANG H,GUO X,et al.Thermal degradation behaviors of some branched and linear polysiloxanes[J].Polymer Degradation and Stability,2006,91(7):1471-1475.
[15]张翠梅.梯形聚甲基/苯基倍半硅氧烷耐高温涂料的制备和性能测试[J].现代涂料与涂装,2007,10(3):10-12.
[16]高萌,刘兰轩,汪洋,等.耐高温有机硅树脂的制备及其涂层的性能研究[J].上海涂料,2017,55(3):20-23.
[17]王海侨,李营,荀国立,等.有机硅耐高温涂料的研究[J].北京化工大学学报(自然科学版),2006,33(1):59-62.
[18]马克超,姜逸倩,柳艳君,等.甲基苯基硅树脂的制备及其在耐高温涂料中的应用[J].现代化工,2013,33(4):91-94.
[19]安娜.耐高温耐腐蚀改性聚氨酯有机硅涂层的合成和表征[D].北京:北京化工大学,2012.
[20]郭斌,陈战利,高勇,等.常温固化有机硅/聚氨酯耐高温涂料的制备及性能研究[J].现代涂料与涂装,2009,12(8):19-20.
[21]RODRGUEZ R,ALARCN C D L H,EKANAYAKE P,et al.Correlation of silicone incorporation into hybrid acrylic coatings with the resulting hydrophobic and thermal properties[J].Macromolecules,2008,41(22):8537-8546.
[22]黄东勤,张子勇.含有机硅和丙烯酸树脂的有机-无机杂化涂料[J].涂料工业,2006,36(2):25-28.
[23]王峥,郝超伟,马清芳,等.国内有机硅耐高温涂料研究进展[J].杭州师范大学学报(自然科学版),2011,10(6):510-513.
[24]TAO Z,YANG S,CHEN J,et al.Synthesis and characterization of imide ring and siloxane-containing cycloaliphatic epoxy resins[J].European Polymer Journal,2007,43(4):1470-1479.
[25]刘强,杜传芹,任卫东.环氧有机硅耐高温涂料的性能研究及应用探讨[J].涂料技术与文摘,2016,37(11):33-36.
[26]廉卫珍,张国梁,马春风,等.耐高温防腐隔热涂料的制备与性能[J].高分子材料科学与工程,2017,33(6):152-156.
[27]刘仲阳,孔志元,何庆迪,等.水性聚有机硅氧烷仿陶瓷涂料的研究进展[J].有机硅材料,2014,28(3):227-331.
[28]YOSHINAGA I,YAMADA N,KATAYAMA S.Effect of inorganic components on thermal stability of methylsiloxane-based inorganic/orgnaic hybrids[J].Journal of Sol-Gel Science and Technology,2005,35(1):21-26.
[29]董洪亮.有机硅改性硅溶胶复合涂料的制备与性能研究[D].大连,大连交通大学,2009.
[30]赵红梅,甘礼华,刘明贤,等.硅铝复合树脂的制备及其涂层性能[J].合成树脂及塑料,2012,29(3):14-17.
[31]SCHIAVON M A,ARMELIN N A,YOSHIDA I V P.Novel poly(borosiloxane)precursors to amorphous Si BCOceramics[J].Materials Chemistry and Physics,2008,112(3):1047-1054.
[32]李力锋.一种瓷膜涂料及其生产方法:中国,CN101445677A[P].2009-06-03.
[33]范琳.有机硅陶瓷化耐高温涂层的制备及附着力改善[D].大连,大连理工大学,2017.
[34]肖业鹏,冯伟,周立清,等.耐高温颜填料的种类及其应用[J].广州化工,2013,41(8):22-24.
[35]王荣国,李二明,史崇明.W-800℃有机硅耐高温涂料配方研究[J].河北化工,2005,(5):51-52.
[36]ZHAO J,LUO W,QI L,et al.The high-temperature resistance properties of polysiloxane/Al coatings with low infrared emissivity[J].Coatings,2018,8(4):125.
[37]刘宏宇,张松.室温自干型有机硅耐高温涂料的研究[J].有机硅材料,2009,23(6):375-378.
[38]GIAVERI S,GRONCHI P,BARZONI A.IPN polysiloxane-epoxy resin for high temperature coatings:structure effects on layer performance after 450℃treatment[J].Coatings,2017,7(12):213.
[39]邓天彩,区卓琨.耐高温防腐涂料的研究[J].科技创新导报,2012(16):6-7.
[40]孙振红,李华明,周晓红,等.W61-800各色有机硅耐高温涂料研究[J].中国涂料,2011,26(12):34-36.