基于多金属氧酸盐和贵金属的纳米复合材料的研究进展
|
摘要
基于多金属氧酸盐和贵金属纳米粒子的纳米复合材料,既具有多金属氧酸盐(POMs)可调控的多样结构、丰富的组成、高的电荷密度及可逆的氧化还原性,又具有贵金属纳米材料良好的生物相容性、高的光学活性和催化活性等特性,这些性质使基于POMs和贵金属纳米的复合材料能够应用于催化、生物医药、生物传感等领域.本文作者主要论述近年来基于多金属氧酸盐和贵金属的纳米复合材料的合成、性质及应用的研究现状,并对其前景进行展望.
Nanocomposites based on polyoxometallates and noble metal nanoparticles not only possesses diverse structure,rich composition,high charge density and reversible redox activity regulated of polyoxometalates(POMs),but also have good biocompatibility,high optical activity,catalytic activity and other features of noble metal nanomaterials. These properties make the composites based on POMs and noble metal nanomaterials suitable for catalysis,biomedicine,biosensing,etc. The synthesis,properties and applications of the nanocomposites based on POMs and noble metals in recent years are discussed,and the prospect is predicted in this review.
Nanocomposites based on polyoxometallates and noble metal nanoparticles not only possesses diverse structure,rich composition,high charge density and reversible redox activity regulated of polyoxometalates(POMs),but also have good biocompatibility,high optical activity,catalytic activity and other features of noble metal nanomaterials. These properties make the composites based on POMs and noble metal nanomaterials suitable for catalysis,biomedicine,biosensing,etc. The synthesis,properties and applications of the nanocomposites based on POMs and noble metals in recent years are discussed,and the prospect is predicted in this review.
引文
[1]LONG D L,BURKHOLDER E,CRONIN L.Polyoxometalate clusters,nanostructures and materials:from selfassembly to designer materials and devices[J].Chemical Society Reviews,2007,36(1):105-121.
[2]CHARRON G,GIUSTI A,MAZERAT S,et al.Assembly of a magnetic polyoxometalate on SWNTs[J].Nanoscale,2010,2(1):139-144.
[3]PROUST A,MATT B,VILLANNEAU R,et al.Functionalization and post-functionalization:a step towards polyoxometalate-based materials[J].Chemical Society Reviews,2012,41(22):7605-7622.
[4]SADAKANE M,STECKHAN E.Electrochemical properties of polyoxometalates as electrocatalysts[J].Chemical Reviews,1998,98(1):219-238.
[5]LONG D L,TSUNASHIMA R,CRONIN L.Polyoxometalates:building blocks for functional nanoscale systems[J].Angewandte Chemie International Edition,2010,49(10):1736-1758.
[6]ZHENG S T,YANG G Y.Recent advances in paramagnetic-TM-substituted polyoxometalates(TM=Mn,Fe,Co,Ni,Cu)[J].Chemical Society Reviews,2012,41(22):7623-7646.
[7]李然,李岩岩,赵俊伟.基于六缺位Dawson型磷钨酸盐衍生物的研究进展[J].化学研究,2016,27(3):269-279.LI R,LI Y Y,ZHAO J W.Research progress on dawsontype phosphotungstate derivatives based on six-vacancy[J].Chemical Research,2016,27(3):269-279.
[8]WANG X,ZHUANG J,PENG Q,et al.A general strategy for nanocrystal synthesis[J].Nature,2005,437(7055):121-124.
[9]HYEON T.Chemical synthesis of magnetic nanoparticles[J].Chemical Communications,2003,8:927-934.
[10]HARUTA M.When gold is not noble:catalysis by nanoparticles[J].The Chemical Record,2003,3(2):75-87.
[11]DANIEL M C,ASTRUC D.Gold nanoparticles:assembly,supramolecular chemistry,quantum-size-related properties,and applications toward biology,catalysis,and nanotechnology[J].Chemical Reviews,2004,104(1):293-346.
[12]BIGALL N C,HRTLING T,KLOSE M,et al.Monodisperse platinum nanospheres with adjustable diameters from10 to 100 nm:synthesis and distinct optical properties[J].Nano Letters,2008,8(12):4588-4592.
[13]SHARMA S,AHMAD N,PRAKASH A,et al.Synthesis of crystalline Ag nanoparticles(Ag NPs)from microorganisms[J].Materials Sciences and Applications,2010,1(1):1-7
[14]COZZOLI P D,PELLEGRINO T,MANNA L.Synthesis,properties and perspectives of hybrid nanocrystal structures[J].Chemical Society Reviews,2006,35(11):1195-1208.
[15]马晨光,方宁,李春艳,等.多酸-纳米粒子复合物的研究进展[J].化学研究,2017,28(3):386-390.MA C G,FANG N,LI C Y,et al.Research progress on polyacid-nanoparticle composites[J].Chemical Research,2017,28(3):386-390.
[16]BABAKHANIAN A,KAKI S,AHMADI M,et al.Development ofα-polyoxometalate-polypyrrole-Au nanoparticles modified sensor applied for detection of folic acid[J].Biosensors and Bioelectronics,2014,60:185-190.
[17]YOLA M L,ATAR N,EREN T,et al.Sensitive and selective determination of aqueous triclosan based on gold nanoparticles on polyoxometalate/reduced graphene oxide nanohybrid[J].RSC Advances,2015,5(81):65953-65962.
[18]ZHANG Y,BO X,NSABIMANA A,et al.Green and facile synthesis of an Au nanoparticles@polyoxometalate/ordered mesoporous carbon tri-component nanocomposite and its electrochemical applications[J].Biosensors and Bioelectronics,2015,66:191-197.
[19]ZHANG Y,WANG H,YAO Q,et al.Facile and green decoration of Pd nanoparticles on macroporous carbon by polyoxometalate with enhanced electrocatalytic ability[J].RSC Advances,2016,6(46):39618-39626.
[20]GAO S,WU Z,PAN D,et al.Preparation and characterization of polyoxometalate-Ag nanoparticles composite multilayer films[J].Thin Solid Films,2011,519(7):2317-2322.
[21]ZHANG H,XU X,LIN H,et al.Silver nanocrystal-decorated polyoxometalate single-walled nanotubes as nanoreactors for desulfurization catalysis at room temperature[J].Nanoscale,2017,9(35):13334-13340.
[22]张立新.核壳结构微纳米材料应用技术[M].北京:国防工业出版社,2010:144-156.ZHANG L X.Core-shell structure of micro-nano materials application technology[M].Beijing:National Defense Industry Press,2010:144-156.
[23]李元敬,张春艳,卢万峰,等.新型纳米银/多酸复合抗菌洗涤剂的合成及抗菌性能研究[J].北华大学学报(自然科学版),2017,18(2):155-159.LI Y J,ZHANG C Y,LU W F,et al.Studies on the synthesis and antibacterial activity of a novel nanosilver/polyacid composite antibacterial detergent[J].Journal of Beihua University(Natural Science),2017,18(2):155
[24]孔育梅.钼系纳米材料的合成、表征及性能研究[D].长春:东北师范大学,2006.KONG Y M.Synthesis,characterization and properties of molybdenum-based nanomaterials[D].Changchun:Northeast Normal University,2006.
[25]GUO Y,HU C,JIANG S,et al.Heterogeneous photodegradation of aqueous hydroxy butanedioic acid by microporous polyoxometalates[J].Applied Catalysis B:Environmental,2002,36(1):9-17.
[26]GUO Y,WANG Y,HU C,et al.Microporous polyoxometalates POMs/Si O2:synthesis and photocatalytic degradation of aqueous organocholorine pesticides[J].Chemistry of Materials,2000,12(11):3501-3508.
[27]CHAMBERS R C,HILL C L.Comparative study of polyoxometalates and semiconductor metal oxides as catalysts.Photochemical oxidative degradation of thioethers[J].Inorganic Chemistry,1991,30(13):2776-2781.
[28]TEXIER I,OUAZZANI J,DELAIRE J,et al.Study of the mechanisms of the photodegradation of atrazine in the presence of two photocatalysts:Ti O2and Na4W10O32[J].Tetrahedron,1999,55(11):3401-3412.
[29]ANTONARAKI S,ANDROULAKI E,DIMOTIKALI D,et al.Photolytic degradation of all chlorophenols with polyoxometallates and H2O2[J].Journal of Photochemistry and Photobiology A:Chemistry,2002,148(1):191-197.
[30]LIU R,WANG P,WANG X,et al.UV-and visible-light photocatalytic activity of simultaneously deposited and doped Ag/Ag(I)-Ti O2photocatalyst[J].The Journal of Physical Chemistry C,2012,116(33):17721-17728.
[31]BAI Y Y,LU Y,LIU J K.An efficient photocatalyst for degradation of various organic dyes:Ag@Ag2Mo O4-Ag Br composite[J].Journal of Hazardous Materials,2016,307:26-35.
[32]XIN X,LANG J,WANG T,et al.Construction of novel ternary component photocatalyst Sr0.25H1.5Ta2O6·H2O coupled with C3N4and Ag toward efficient visible light photocatalytic activity for environmental remediation[J].Applied Catalysis B:Environmental,2016,181:197-209.
[33]PATIL S S,MALI M G,TAMBOLI M S,et al.Green approach for hierarchical nanostructured Ag-Zn O and their photocatalytic performance under sunlight[J].Catalysis Today,2016,260:126-134.
[34]SHI H,YU Y,ZHANG Y,et al.Polyoxometalate/Ti O2/Ag composite nanofibers with enhanced photocatalytic performance under visible light[J].Applied Catalysis B:Environmental,2018,221:280-289.
[35]LI S,YU X,ZHANG G,et al.Green chemical decoration of multiwalled carbon nanotubes with polyoxometalate encapsulated gold nanoparticles:visible light photocatalytic activities[J].Journal of Materials Chemistry,2011,21(7):2282-2287.
[36]FANG X,KGERLER P,FURUKAWA Y,et al.Molecular growth of a core-shell polyoxometalate[J].Angewandte Chemie International Edition,2011,50(22):5212-5216.
[37]WANG S S,YANG G Y.Recent advances in polyoxometalate-catalyzed reactions[J].Chemical Reviews,2015,115(11):4893-4962.
[38]QIU H J,ITO Y,CONG W,et al.Nanoporous graphene with single-atom nickel dopants:An efficient and stable catalyst for electrochemical hydrogen production[J].Angewandte Chemie International Edition,2015,54(47):14031-14035.
[39]CAI Z,LI F,WU P,et al.Synthesis of nitrogen-doped graphene quantum dots at low temperature for electrochemical sensing trinitrotoluene[J].Analytical chemistry,2015,87(23):11803-11811.
[40]DENG Y,XIE Y,ZOU K,et al.Review on recent advances in nitrogen-doped carbons:preparations and applications in supercapacitors[J].Journal of Materials Chemistry A,2016,4(4):1144-1173.
[41]HADIDI L,DAVARI E,IQBAL M,et al.Spherical nitrogen-doped hollow mesoporous carbon as an efficient bifunctional electrocatalyst for Zn-air batteries[J].Nanoscale,2015,7(48):20547-20556.
[42]SHEN G,SUN X,ZHANG H,et al.Nitrogen-doped ordered mesoporous carbon single crystals:aqueous organicorganic self-assembly and superior supercapacitor performance[J].Journal of Materials Chemistry A,2015,3(47):24041-24048.
[43]ZOLADEK S,RUTKOWSKAA I A,SKORUPSKA K,et al.Fabrication of polyoxometallate-modified gold nanoparticles and their utilization as supports for dispersed platinum in electrocatalysis[J].Electrochim Acta,2011,56:10744-10750.
[44]JAMEEL U,ZHU M,CHEN X,et al.Recent progress of synthesis and applications in polyoxometalate and nanogold hybrid materials[J].Journal of Materials Science,2016,51(5):2181-2198.
[45]AN D,YE A,DENG W,et al.Selective conversion of cellobiose and cellulose into gluconic acid in water in the presence of oxygen,catalyzed by polyoxometalate-supported gold nanoparticles[J].Chemistry-A European Journal,2012,18(10):2938-2947.
[46]DAIMA H K,SELVAKANNAN P R,KANDJANI A E,et al.Synergistic influence of polyoxometalate surface corona towards enhancing the antibacterial performance of tyrosine-capped Ag nanoparticles[J].Nanoscale,2014,6(2):758-765.
[2]CHARRON G,GIUSTI A,MAZERAT S,et al.Assembly of a magnetic polyoxometalate on SWNTs[J].Nanoscale,2010,2(1):139-144.
[3]PROUST A,MATT B,VILLANNEAU R,et al.Functionalization and post-functionalization:a step towards polyoxometalate-based materials[J].Chemical Society Reviews,2012,41(22):7605-7622.
[4]SADAKANE M,STECKHAN E.Electrochemical properties of polyoxometalates as electrocatalysts[J].Chemical Reviews,1998,98(1):219-238.
[5]LONG D L,TSUNASHIMA R,CRONIN L.Polyoxometalates:building blocks for functional nanoscale systems[J].Angewandte Chemie International Edition,2010,49(10):1736-1758.
[6]ZHENG S T,YANG G Y.Recent advances in paramagnetic-TM-substituted polyoxometalates(TM=Mn,Fe,Co,Ni,Cu)[J].Chemical Society Reviews,2012,41(22):7623-7646.
[7]李然,李岩岩,赵俊伟.基于六缺位Dawson型磷钨酸盐衍生物的研究进展[J].化学研究,2016,27(3):269-279.LI R,LI Y Y,ZHAO J W.Research progress on dawsontype phosphotungstate derivatives based on six-vacancy[J].Chemical Research,2016,27(3):269-279.
[8]WANG X,ZHUANG J,PENG Q,et al.A general strategy for nanocrystal synthesis[J].Nature,2005,437(7055):121-124.
[9]HYEON T.Chemical synthesis of magnetic nanoparticles[J].Chemical Communications,2003,8:927-934.
[10]HARUTA M.When gold is not noble:catalysis by nanoparticles[J].The Chemical Record,2003,3(2):75-87.
[11]DANIEL M C,ASTRUC D.Gold nanoparticles:assembly,supramolecular chemistry,quantum-size-related properties,and applications toward biology,catalysis,and nanotechnology[J].Chemical Reviews,2004,104(1):293-346.
[12]BIGALL N C,HRTLING T,KLOSE M,et al.Monodisperse platinum nanospheres with adjustable diameters from10 to 100 nm:synthesis and distinct optical properties[J].Nano Letters,2008,8(12):4588-4592.
[13]SHARMA S,AHMAD N,PRAKASH A,et al.Synthesis of crystalline Ag nanoparticles(Ag NPs)from microorganisms[J].Materials Sciences and Applications,2010,1(1):1-7
[14]COZZOLI P D,PELLEGRINO T,MANNA L.Synthesis,properties and perspectives of hybrid nanocrystal structures[J].Chemical Society Reviews,2006,35(11):1195-1208.
[15]马晨光,方宁,李春艳,等.多酸-纳米粒子复合物的研究进展[J].化学研究,2017,28(3):386-390.MA C G,FANG N,LI C Y,et al.Research progress on polyacid-nanoparticle composites[J].Chemical Research,2017,28(3):386-390.
[16]BABAKHANIAN A,KAKI S,AHMADI M,et al.Development ofα-polyoxometalate-polypyrrole-Au nanoparticles modified sensor applied for detection of folic acid[J].Biosensors and Bioelectronics,2014,60:185-190.
[17]YOLA M L,ATAR N,EREN T,et al.Sensitive and selective determination of aqueous triclosan based on gold nanoparticles on polyoxometalate/reduced graphene oxide nanohybrid[J].RSC Advances,2015,5(81):65953-65962.
[18]ZHANG Y,BO X,NSABIMANA A,et al.Green and facile synthesis of an Au nanoparticles@polyoxometalate/ordered mesoporous carbon tri-component nanocomposite and its electrochemical applications[J].Biosensors and Bioelectronics,2015,66:191-197.
[19]ZHANG Y,WANG H,YAO Q,et al.Facile and green decoration of Pd nanoparticles on macroporous carbon by polyoxometalate with enhanced electrocatalytic ability[J].RSC Advances,2016,6(46):39618-39626.
[20]GAO S,WU Z,PAN D,et al.Preparation and characterization of polyoxometalate-Ag nanoparticles composite multilayer films[J].Thin Solid Films,2011,519(7):2317-2322.
[21]ZHANG H,XU X,LIN H,et al.Silver nanocrystal-decorated polyoxometalate single-walled nanotubes as nanoreactors for desulfurization catalysis at room temperature[J].Nanoscale,2017,9(35):13334-13340.
[22]张立新.核壳结构微纳米材料应用技术[M].北京:国防工业出版社,2010:144-156.ZHANG L X.Core-shell structure of micro-nano materials application technology[M].Beijing:National Defense Industry Press,2010:144-156.
[23]李元敬,张春艳,卢万峰,等.新型纳米银/多酸复合抗菌洗涤剂的合成及抗菌性能研究[J].北华大学学报(自然科学版),2017,18(2):155-159.LI Y J,ZHANG C Y,LU W F,et al.Studies on the synthesis and antibacterial activity of a novel nanosilver/polyacid composite antibacterial detergent[J].Journal of Beihua University(Natural Science),2017,18(2):155
[24]孔育梅.钼系纳米材料的合成、表征及性能研究[D].长春:东北师范大学,2006.KONG Y M.Synthesis,characterization and properties of molybdenum-based nanomaterials[D].Changchun:Northeast Normal University,2006.
[25]GUO Y,HU C,JIANG S,et al.Heterogeneous photodegradation of aqueous hydroxy butanedioic acid by microporous polyoxometalates[J].Applied Catalysis B:Environmental,2002,36(1):9-17.
[26]GUO Y,WANG Y,HU C,et al.Microporous polyoxometalates POMs/Si O2:synthesis and photocatalytic degradation of aqueous organocholorine pesticides[J].Chemistry of Materials,2000,12(11):3501-3508.
[27]CHAMBERS R C,HILL C L.Comparative study of polyoxometalates and semiconductor metal oxides as catalysts.Photochemical oxidative degradation of thioethers[J].Inorganic Chemistry,1991,30(13):2776-2781.
[28]TEXIER I,OUAZZANI J,DELAIRE J,et al.Study of the mechanisms of the photodegradation of atrazine in the presence of two photocatalysts:Ti O2and Na4W10O32[J].Tetrahedron,1999,55(11):3401-3412.
[29]ANTONARAKI S,ANDROULAKI E,DIMOTIKALI D,et al.Photolytic degradation of all chlorophenols with polyoxometallates and H2O2[J].Journal of Photochemistry and Photobiology A:Chemistry,2002,148(1):191-197.
[30]LIU R,WANG P,WANG X,et al.UV-and visible-light photocatalytic activity of simultaneously deposited and doped Ag/Ag(I)-Ti O2photocatalyst[J].The Journal of Physical Chemistry C,2012,116(33):17721-17728.
[31]BAI Y Y,LU Y,LIU J K.An efficient photocatalyst for degradation of various organic dyes:Ag@Ag2Mo O4-Ag Br composite[J].Journal of Hazardous Materials,2016,307:26-35.
[32]XIN X,LANG J,WANG T,et al.Construction of novel ternary component photocatalyst Sr0.25H1.5Ta2O6·H2O coupled with C3N4and Ag toward efficient visible light photocatalytic activity for environmental remediation[J].Applied Catalysis B:Environmental,2016,181:197-209.
[33]PATIL S S,MALI M G,TAMBOLI M S,et al.Green approach for hierarchical nanostructured Ag-Zn O and their photocatalytic performance under sunlight[J].Catalysis Today,2016,260:126-134.
[34]SHI H,YU Y,ZHANG Y,et al.Polyoxometalate/Ti O2/Ag composite nanofibers with enhanced photocatalytic performance under visible light[J].Applied Catalysis B:Environmental,2018,221:280-289.
[35]LI S,YU X,ZHANG G,et al.Green chemical decoration of multiwalled carbon nanotubes with polyoxometalate encapsulated gold nanoparticles:visible light photocatalytic activities[J].Journal of Materials Chemistry,2011,21(7):2282-2287.
[36]FANG X,KGERLER P,FURUKAWA Y,et al.Molecular growth of a core-shell polyoxometalate[J].Angewandte Chemie International Edition,2011,50(22):5212-5216.
[37]WANG S S,YANG G Y.Recent advances in polyoxometalate-catalyzed reactions[J].Chemical Reviews,2015,115(11):4893-4962.
[38]QIU H J,ITO Y,CONG W,et al.Nanoporous graphene with single-atom nickel dopants:An efficient and stable catalyst for electrochemical hydrogen production[J].Angewandte Chemie International Edition,2015,54(47):14031-14035.
[39]CAI Z,LI F,WU P,et al.Synthesis of nitrogen-doped graphene quantum dots at low temperature for electrochemical sensing trinitrotoluene[J].Analytical chemistry,2015,87(23):11803-11811.
[40]DENG Y,XIE Y,ZOU K,et al.Review on recent advances in nitrogen-doped carbons:preparations and applications in supercapacitors[J].Journal of Materials Chemistry A,2016,4(4):1144-1173.
[41]HADIDI L,DAVARI E,IQBAL M,et al.Spherical nitrogen-doped hollow mesoporous carbon as an efficient bifunctional electrocatalyst for Zn-air batteries[J].Nanoscale,2015,7(48):20547-20556.
[42]SHEN G,SUN X,ZHANG H,et al.Nitrogen-doped ordered mesoporous carbon single crystals:aqueous organicorganic self-assembly and superior supercapacitor performance[J].Journal of Materials Chemistry A,2015,3(47):24041-24048.
[43]ZOLADEK S,RUTKOWSKAA I A,SKORUPSKA K,et al.Fabrication of polyoxometallate-modified gold nanoparticles and their utilization as supports for dispersed platinum in electrocatalysis[J].Electrochim Acta,2011,56:10744-10750.
[44]JAMEEL U,ZHU M,CHEN X,et al.Recent progress of synthesis and applications in polyoxometalate and nanogold hybrid materials[J].Journal of Materials Science,2016,51(5):2181-2198.
[45]AN D,YE A,DENG W,et al.Selective conversion of cellobiose and cellulose into gluconic acid in water in the presence of oxygen,catalyzed by polyoxometalate-supported gold nanoparticles[J].Chemistry-A European Journal,2012,18(10):2938-2947.
[46]DAIMA H K,SELVAKANNAN P R,KANDJANI A E,et al.Synergistic influence of polyoxometalate surface corona towards enhancing the antibacterial performance of tyrosine-capped Ag nanoparticles[J].Nanoscale,2014,6(2):758-765.