原位淋洗法修复重金属污染土壤研究进展
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摘要
总结并分析了原位淋洗技术中淋洗剂、淋洗条件和淋洗方式优化的研究进展和不足,概述了原位淋洗法现场处理系统和淋洗方法的研究现状,指出寻找一种对所有重金属都有高去除率的新型淋洗剂是研究的关键,如何结合其余重金属土壤修复方法,使淋洗剂均匀渗入土层,保证各土层都具有均匀高效的淋洗效果将会是以后研究的重点,水力梯度对污染土壤中重金属去除效果的影响是以后新的研究热点。
This paper summarized and analyzed the research progress and deficiency of flushing agent,flushing conditions and flushing methods in the in-situ flushing technology,summarize the research status of in-situ flushing system and flushing method.Finally,it pointed out that finding a new type of flushing agent with high removal rate for all heavy metals is the key to the research,and how to combine the other heavy metal soil remediation methods,making the drenching lotion evenly infiltrated into the soil layer,ensuring that all soil layers have uniform and efficient leaching effect will be the focus of future research.The effect of hydraulic gradient on the removal of heavy metals in contaminated soil is a new research hotspot in the future.
This paper summarized and analyzed the research progress and deficiency of flushing agent,flushing conditions and flushing methods in the in-situ flushing technology,summarize the research status of in-situ flushing system and flushing method.Finally,it pointed out that finding a new type of flushing agent with high removal rate for all heavy metals is the key to the research,and how to combine the other heavy metal soil remediation methods,making the drenching lotion evenly infiltrated into the soil layer,ensuring that all soil layers have uniform and efficient leaching effect will be the focus of future research.The effect of hydraulic gradient on the removal of heavy metals in contaminated soil is a new research hotspot in the future.
引文
[1] Song Q,Li J.A review on human health consequences of metals exposure to e-waste in China[J].Environmental Pollution,2015,196:450-461.
[2] Liu L,Zhang X,Zhong T.Pollution and health risk assessment of heavy metals in urban soil in China[J].Human & Ecological Risk Assessment an International Journal,2016,22(2):424-434.
[3] Yu K,Xu J,Jiang X,et al.Stabilization of heavy metals in soil using two organo-bentonites[J].Chemosphere,2017,184:884-891.
[4] Beiergrohslein Erik.The use of surfactants in removal of zinc,lead and cadmium from contaminated soils[D].Oklahoma:Oklahoma State University,1998.
[5] Zhao F J,Ma Y,Zhu Y G,et al.Soil contamination in China:current status and mitigation strategies[J].Environmental Science & Technology,2015,49(2):750-759.
[6] Yuan Y,Xiang M,Liu C,et al.Geochemical characteristics of heavy metal contamination induced by a sudden wastewater discharge from a smelter[J].Journal of Geochemical Exploration,2017,176:33-41.
[7] Mann M J.Full-scale and pilot-scale soil washing[J].Journal of Hazardous Materials,1999,66(1/2):119-136.
[8] Ali H,Khan K,Sajad M A.Phytoremediation of heavy metals-concepts and applications[J].Chemosphere,2013,91(7):869-881.
[9] Naghipour D,Taghavi K,Jaafari J,et al.Statistical modeling and optimization of the phosphorus biosorption by modified Lemna minor from aqueous solution using response surface methodology (RSM)[J].Desalination & Water Treatment,2015,1(1):1-12.
[10] Borggaard O,Holm P E,Jensen J,et al.Cleaning heavy metal contaminated soil with soluble humic substances instead of synthetic polycarboxylic acids[J].Acta Agriculturae Scandinavica,2011,61(6):577-581.
[11] Paria S.Surfactant-enhanced remediation of organic contaminated soil and water[J].Adv Colloid Interface Sci,2008,138(1):24-58.
[12] Laha S,Tansel B,Ussawarujikulchai A.Surfactant-soil interactions during surfactant-amended remediation of contaminated soils by hydrophobic organic compounds:a review[J].Journal of Environmental Management,2009,90 (1):95-100.
[13] Chitimus A D,Nedeff V,Mosnegutu E F,et al.In situ soil flushing-studies on remediation efficiency of polluted sandy soils with organic acids[J].Environmental Engineering and Management Journal,2012,11(12):2163-2168.
[14] 李玉双,胡晓钧,孙铁珩,等.污染土壤淋洗修复技术研究进展[J].生态学杂志,2011,30(3):596-602.
[15] Juhasz A L,Smith E,Smith J,et al.In situ remediation of DDT-contaminated soil using a two-phase cosolvent flushing-fungal biosorption process[J].Water,Air and Soil Pollution,2003,147(1/2/3/4):263-274.
[16] 张乃明.重金属污染土壤修复理论与实践[M].北京:化学工业出版社,2017.
[17] Dermont G,Bergeon M,Mercier G,et al.Soil washing for metal removal:a review of physical/chemical technologies and field applications[J].Journal of Hazardous Materials,2008,152(1):1-31.
[18] Mulligan C N,Yong R N,Gibbs B F.Surfactant-enhanced remediation of contaminated soil[J].Engineering Geology,2001,60(1):371-380.
[19] 孙涛,陆扣萍,王海龙.不同淋洗剂和淋洗条件下重金属污染土壤淋洗修复研究进展[J].浙江农林大学学报,2015,32(1):140-149.
[20] 周芙蓉,钟礼春,杨寿南.复合淋洗剂对镉污染土壤的淋洗效果[J].安徽农业科学,2017,45(23):52-54.
[21] 张佳,陈鸿汉,张岩坤,等.柠檬酸淋洗去除土壤中铬的实验研究[J].环境科学学报,2016,35(7):2247-2253.
[22] 刘霞,王建涛,张萌,等.螯合剂和生物表面活性剂对 Cu、Pb 污染塿土的淋洗修复[J].环境科学,2013,34(4):1590-1597.
[23] Zhao B,Che H.Column flushing of Cu(II) from sandy loess soil using citric acid[C]//International Conference on Application of Materials Science & Environmental Materials.Singapore:World Scientific,2016:199-207.
[24] Maity J P,Huang Y M,Hsu C M.Removal of Cu,Pb and Zn by foam fractionation and a soil washing process from contaminated industrial soils using soapberry-derived saponin:A comparative effectiveness assessment[J].Chemosphere,2013,92(10):1286-1293.
[25] Torres L G,Lopez R B,Beltran M.Removal of As,Cd,Cu,Ni,Pb and Zn from a highly contaminated industrial soil using surfactant enhanced soil washing[J].Physics and Chemistry of the Earth,2012,37/38/39:30-36.
[26] Mulligan C N,Yong R N,Gibbs B F.Surfactant enhanced remediation of contaminated soil:a review[J].Engineering Geology,2001,60(1/2/3/4):371-380.
[27] 刘艺芸,张连红,崔爽,等.多氨基多醚基甲叉膦酸土柱淋洗修复镉污染土壤[J].辽宁石油化工大学学报,2016,36(4):1-4.
[28] 刘培亚,李玉姣,胡鹏杰,等.复合淋洗剂土柱淋洗法修复Cd、Pb污染土壤[J].环境工程,2015,33(1):163-167.
[29] 吴烈善,咸思雨,孔德超,等.单宁酸与柠檬酸复合淋洗去除土壤中重金属 Cd 的研究[J].环境工程,2016,34(8):178-181.
[30] Zhao B,Wang H.Simultaneous removal of phenanthrene and Ni(II) co-contaminants from sandy soil column by Triton X-100 and citric acid flushing[J].Nature Environment & Pollution Technology,2017,16(2):607-613.
[31] Naghipour D,Jaafari J,Ashrafi S D,et al.Remediation of heavy metals contaminated silty clay loam soil by column extraction with ethylenediaminetetraacetic acid and nitrilo triacetic acid[J].Journal of Environmental Engineering,2017,143(8):04017026.
[32] Papassiopi N,Tambouris S,A Kontopoulos.Removal of heavy metals from calcareous contaminated soils by EDTA leaching[J].Water,Air and Soil Pollution,1999,109(1/2/3/4):1-15.
[33] Kim C,Ong S K.Effects of amorphous iron on extraction of lead-contaminated soil with EDTA[J].Practice Periodical of Hazardous Toxic and Radioactive Waste Management,2000,4(1):6-23.
[34] Pichtel J,Covey A,Lukscay K.Removal of lead and chromium from contaminated soil:column studies[J].Proceedings of the Indiana Academy of Science,1997,106:95-104.
[35] 可欣,张昀,李培军,等.利用酒石酸土柱淋洗法修复重金属污染土壤[J].深圳大学学报:理工版,2009,26(3):240-245.
[36] 陈杰.有机酸淋洗法和固化稳定化法修复重金属污染土壤研究[D].杭州:浙江大学,2015.
[37] 焦维琦.新型可生物降解螯合剂GLDA 淋洗修复重金属污染土壤研究[D].长春:吉林大学,2017.
[38] 孙玉焕,关峰,徐小龙,等.柱淋洗法修复铬污染土壤的效果研究[J].环境保护科学,2016,42(3):113-118.
[39] Reddy K R,Al-Hamdan A Z.Enhanced sequential flushing process for removal of mixed contaminants from soils[J].Water,Air and Soil Pollution,2013,224(12):1-13.
[40] 李璐,胡竹云,王惠芸,等.一种污染土有组织渗流原位强制净化方法:中国,201210241287.8[P].2012-10-17.
[41] 张海秀,吕正勇,宋登慧,等.原位多层水平井淋洗土壤修复方法和装置:中国,201710684049.7[P].2017-10-24.
[42] 刘晓月,李娟,刘登彪,等.一种三维井淋洗联合稳定化原位修复重金属污染土壤的方法:中国,201710433174.0[P].2017-09-15.
[43] 张辉,黄新建.一种重金属污染土壤化学联合淋洗修复方法:中国,201310092382.0[P].2013-09-25.
[2] Liu L,Zhang X,Zhong T.Pollution and health risk assessment of heavy metals in urban soil in China[J].Human & Ecological Risk Assessment an International Journal,2016,22(2):424-434.
[3] Yu K,Xu J,Jiang X,et al.Stabilization of heavy metals in soil using two organo-bentonites[J].Chemosphere,2017,184:884-891.
[4] Beiergrohslein Erik.The use of surfactants in removal of zinc,lead and cadmium from contaminated soils[D].Oklahoma:Oklahoma State University,1998.
[5] Zhao F J,Ma Y,Zhu Y G,et al.Soil contamination in China:current status and mitigation strategies[J].Environmental Science & Technology,2015,49(2):750-759.
[6] Yuan Y,Xiang M,Liu C,et al.Geochemical characteristics of heavy metal contamination induced by a sudden wastewater discharge from a smelter[J].Journal of Geochemical Exploration,2017,176:33-41.
[7] Mann M J.Full-scale and pilot-scale soil washing[J].Journal of Hazardous Materials,1999,66(1/2):119-136.
[8] Ali H,Khan K,Sajad M A.Phytoremediation of heavy metals-concepts and applications[J].Chemosphere,2013,91(7):869-881.
[9] Naghipour D,Taghavi K,Jaafari J,et al.Statistical modeling and optimization of the phosphorus biosorption by modified Lemna minor from aqueous solution using response surface methodology (RSM)[J].Desalination & Water Treatment,2015,1(1):1-12.
[10] Borggaard O,Holm P E,Jensen J,et al.Cleaning heavy metal contaminated soil with soluble humic substances instead of synthetic polycarboxylic acids[J].Acta Agriculturae Scandinavica,2011,61(6):577-581.
[11] Paria S.Surfactant-enhanced remediation of organic contaminated soil and water[J].Adv Colloid Interface Sci,2008,138(1):24-58.
[12] Laha S,Tansel B,Ussawarujikulchai A.Surfactant-soil interactions during surfactant-amended remediation of contaminated soils by hydrophobic organic compounds:a review[J].Journal of Environmental Management,2009,90 (1):95-100.
[13] Chitimus A D,Nedeff V,Mosnegutu E F,et al.In situ soil flushing-studies on remediation efficiency of polluted sandy soils with organic acids[J].Environmental Engineering and Management Journal,2012,11(12):2163-2168.
[14] 李玉双,胡晓钧,孙铁珩,等.污染土壤淋洗修复技术研究进展[J].生态学杂志,2011,30(3):596-602.
[15] Juhasz A L,Smith E,Smith J,et al.In situ remediation of DDT-contaminated soil using a two-phase cosolvent flushing-fungal biosorption process[J].Water,Air and Soil Pollution,2003,147(1/2/3/4):263-274.
[16] 张乃明.重金属污染土壤修复理论与实践[M].北京:化学工业出版社,2017.
[17] Dermont G,Bergeon M,Mercier G,et al.Soil washing for metal removal:a review of physical/chemical technologies and field applications[J].Journal of Hazardous Materials,2008,152(1):1-31.
[18] Mulligan C N,Yong R N,Gibbs B F.Surfactant-enhanced remediation of contaminated soil[J].Engineering Geology,2001,60(1):371-380.
[19] 孙涛,陆扣萍,王海龙.不同淋洗剂和淋洗条件下重金属污染土壤淋洗修复研究进展[J].浙江农林大学学报,2015,32(1):140-149.
[20] 周芙蓉,钟礼春,杨寿南.复合淋洗剂对镉污染土壤的淋洗效果[J].安徽农业科学,2017,45(23):52-54.
[21] 张佳,陈鸿汉,张岩坤,等.柠檬酸淋洗去除土壤中铬的实验研究[J].环境科学学报,2016,35(7):2247-2253.
[22] 刘霞,王建涛,张萌,等.螯合剂和生物表面活性剂对 Cu、Pb 污染塿土的淋洗修复[J].环境科学,2013,34(4):1590-1597.
[23] Zhao B,Che H.Column flushing of Cu(II) from sandy loess soil using citric acid[C]//International Conference on Application of Materials Science & Environmental Materials.Singapore:World Scientific,2016:199-207.
[24] Maity J P,Huang Y M,Hsu C M.Removal of Cu,Pb and Zn by foam fractionation and a soil washing process from contaminated industrial soils using soapberry-derived saponin:A comparative effectiveness assessment[J].Chemosphere,2013,92(10):1286-1293.
[25] Torres L G,Lopez R B,Beltran M.Removal of As,Cd,Cu,Ni,Pb and Zn from a highly contaminated industrial soil using surfactant enhanced soil washing[J].Physics and Chemistry of the Earth,2012,37/38/39:30-36.
[26] Mulligan C N,Yong R N,Gibbs B F.Surfactant enhanced remediation of contaminated soil:a review[J].Engineering Geology,2001,60(1/2/3/4):371-380.
[27] 刘艺芸,张连红,崔爽,等.多氨基多醚基甲叉膦酸土柱淋洗修复镉污染土壤[J].辽宁石油化工大学学报,2016,36(4):1-4.
[28] 刘培亚,李玉姣,胡鹏杰,等.复合淋洗剂土柱淋洗法修复Cd、Pb污染土壤[J].环境工程,2015,33(1):163-167.
[29] 吴烈善,咸思雨,孔德超,等.单宁酸与柠檬酸复合淋洗去除土壤中重金属 Cd 的研究[J].环境工程,2016,34(8):178-181.
[30] Zhao B,Wang H.Simultaneous removal of phenanthrene and Ni(II) co-contaminants from sandy soil column by Triton X-100 and citric acid flushing[J].Nature Environment & Pollution Technology,2017,16(2):607-613.
[31] Naghipour D,Jaafari J,Ashrafi S D,et al.Remediation of heavy metals contaminated silty clay loam soil by column extraction with ethylenediaminetetraacetic acid and nitrilo triacetic acid[J].Journal of Environmental Engineering,2017,143(8):04017026.
[32] Papassiopi N,Tambouris S,A Kontopoulos.Removal of heavy metals from calcareous contaminated soils by EDTA leaching[J].Water,Air and Soil Pollution,1999,109(1/2/3/4):1-15.
[33] Kim C,Ong S K.Effects of amorphous iron on extraction of lead-contaminated soil with EDTA[J].Practice Periodical of Hazardous Toxic and Radioactive Waste Management,2000,4(1):6-23.
[34] Pichtel J,Covey A,Lukscay K.Removal of lead and chromium from contaminated soil:column studies[J].Proceedings of the Indiana Academy of Science,1997,106:95-104.
[35] 可欣,张昀,李培军,等.利用酒石酸土柱淋洗法修复重金属污染土壤[J].深圳大学学报:理工版,2009,26(3):240-245.
[36] 陈杰.有机酸淋洗法和固化稳定化法修复重金属污染土壤研究[D].杭州:浙江大学,2015.
[37] 焦维琦.新型可生物降解螯合剂GLDA 淋洗修复重金属污染土壤研究[D].长春:吉林大学,2017.
[38] 孙玉焕,关峰,徐小龙,等.柱淋洗法修复铬污染土壤的效果研究[J].环境保护科学,2016,42(3):113-118.
[39] Reddy K R,Al-Hamdan A Z.Enhanced sequential flushing process for removal of mixed contaminants from soils[J].Water,Air and Soil Pollution,2013,224(12):1-13.
[40] 李璐,胡竹云,王惠芸,等.一种污染土有组织渗流原位强制净化方法:中国,201210241287.8[P].2012-10-17.
[41] 张海秀,吕正勇,宋登慧,等.原位多层水平井淋洗土壤修复方法和装置:中国,201710684049.7[P].2017-10-24.
[42] 刘晓月,李娟,刘登彪,等.一种三维井淋洗联合稳定化原位修复重金属污染土壤的方法:中国,201710433174.0[P].2017-09-15.
[43] 张辉,黄新建.一种重金属污染土壤化学联合淋洗修复方法:中国,201310092382.0[P].2013-09-25.