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MOFs在阴离子型重金属离子处理中的应用
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  • 英文篇名:Application of MOFs in Heavy Metal Ions of Anionic Treatment
  • 作者:龚建康 ; 宋啟旺 ; 师睿 ; 张正彪
  • 英文作者:Gong Jiankang;Song Qiwang;Shi Rui;Zhang Zhengbiao;School of Chemistry and Chemical Engineering,Zhaotong University;
  • 关键词:金属有机框架材料 ; 阴离子型重金属离子 ; 吸附法
  • 英文关键词:metal organic frameworks materials;;heavy metal ions of anionic;;adsorption
  • 中文刊名:SDHG
  • 英文刊名:Shandong Chemical Industry
  • 机构:昭通学院化学化工学院;
  • 出版日期:2019-06-08
  • 出版单位:山东化工
  • 年:2019
  • 期:v.48;No.357
  • 基金:昭通学院校级科研项目(2018xj12)
  • 语种:中文;
  • 页:SDHG201911090
  • 页数:2
  • CN:11
  • ISSN:37-1212/TQ
  • 分类号:200-201
摘要
近年来,金属有机骨架材料(简称MOFs)已用作吸附剂应用于液相体系中,因其具有高比表面积、不饱和金属位点,表面强带电性和易功能化等特性,使其对目标物具有强大的吸附潜力,促使本身在水体环境污染治理方面已经成为一个研究的热点。综述了MOFs材料对水体中阴离子型重金属离子的吸附去除现状及总结了吸附机理,并展望了该材料在液相体系中的今后应用发展前景。
        In recent years,a new type of metal organic framework(MOFs) has been used as an adsorbent in liquid phase,the material has great adsorption potential for the target compounds,with high surface area,unsaturated metal site,electrical properties of the surface and can be functionalized easily,which has become a research hotspot in water environment pollution management.Their application status and mechanism in adsorption removal of the heavy metal ions of anionic in aquatic environment were summarized,and pointed out the prospect of development application of this material in in aquatic environment in future.
引文
[1]Wang J F,Wu P F,Chen J,et al.Biodegradation of microcystin-rr by a new isolated sphingopyxis sp.USTB-05[J].Journal of Chemical Engineering,2010,18(1):108-112.
    [2]Hasan Z B,Jhung S H.Removal of hazardous organics from water using metal-organic frameworks (MOFs):plausible mechanisms for selective adsorptions[J].Journal of Hazardous Materials,2015,283:329-339.
    [3]Guo Q H,Tian J.Removal of fluoride and arsenate from aqueous solution by hydrocalumite via precipitation and anion exchange[J].Chemical Engineering Journal,2013,231:121-131.
    [4]Wu D,Yang Q,Zhong C,et al.Revealing the structure-property relationships of metal-organic frameworks for CO2 capture from flue gas[J].Langmuir,2012,28(33):12094-12099.
    [5]Lee J Y,Farha O K,Roberts J,et al.Metalorganic framework materials as catalysts[J].Chemical Society Reviews,2009,38:1450-1459.
    [6]Rocha J,Carlos L D,Paz F A A,et al.Luminescent multifunctional lanthanides-based metal-organic frameworks[J].Chemical Society Reviews,2011,40:926-940.
    [7]Horcajada P,Gref R,Baati T,et al.Metal-organic frameworks in biomedicine[J].Chemical Reviews,2012,112:1232-1268.
    [8]Li Z Q,Yang J C,Sui K W,et al.Facile synthesis of metal-organic framework MOF-808 for arsenic removal[J].Materials Letters,2015,160:412-414.
    [9]Jian M P,Liu B,Zhang G S,et al.Adsorptive removal of arsenic from aqueous solution by zeolitic imidazolate framework-8 (ZIF-8) nanoparticles[J].Journal of Colloids and Surfaces A:Physicochem Eng Aspects,2015,465:67-76.
    [10]Massoudinejad M,Ghaderpoori M,Shahsavani A,et al.Ethylenediamine-functionalized cubic ZIF-8 for arsenic adsorption from aqueous solution:Modeling,isotherms,kinetics and thermodynamics[J].Journal of Molecular Liquids,2018,255:263-268.
    [11]Liu Z M,Chen J,Wu Y C,et al.Synthesis of magnetic orderly mesoporous α-Fe2O3 nanocluster derived from MIL-100(Fe) for rapid and efficient arsenic(III,V) removal[J].Journal of Hazardous Materials,2018,343:304-314.
    [12]Howarth A J,Katz M J,Wang T C,et al.High efficiency adsorption and removal of selenate and selenite from water using metal-organic frameworks[J].Journal of the American Chemical Society,2015,137:7488-7494.
    [13]Yang H O,Chen D N,Chang G J,et al.Selective capture of toxic selenite anions by bismuth-based metal-organic frameworks[J].Angewandte Chemie International Edition,2018,57(40):13197-13201.
    [14]Li L L,Feng X Q,Han R P,et al.Cr(VI) removal via anion exchange on a silver-triazolate MOF[J].Journal of Hazardous Materials,2017,321:622-628.

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