印度犀牛角的化学成分分析
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摘要
本文以印度犀牛角为主要研究对象,利用傅里叶变换红外光谱仪、X射线荧光光谱仪、全自动氨基酸分析仪分析其红外光谱、化学成分等特征,旨在为犀牛角替代品、人工合成品的研究提供部分基础数据。结果表明:红外光谱中氨基酸、磷脂酸、牛磺酸等相关的吸收峰明显;犀牛角主要的无机成分为CaO、Fe_2O_3、K_2O、ZnO、SiO_2等;氨基酸含量为481. 01 mg/g,药用氨基酸含量丰富,氨基酸组成与标准蛋白的贴近度为0. 74。结果表明犀牛角具有较高的营养价值。
In this paper,Indian rhino horn is the main object of study. Fourier transform infrared spectroscopy(FTIR),X-ray fluorescence spectroscopy(XRF)and automatic amino acid analyzer were used to analyze the infrared spectroscopy and chemical composition of rhinoceros horn,in order to provide basic data for the research of rhinoceros horn substitutes and synthetic products. The results showed that the absorption peaks of amino acids,phosphatidic acid and taurine were obvious in infrared spectra. The main inorganic components of rhinoceros horn are CaO,Fe_2O_3,K_2O,ZnO,SiO_2,etc. Amino acid content is 481. 01 mg/g,medicinal amino acid content is rich,and the closeness of amino acid composition standard protein is 0. 74. The result indicates that the rhino horn has high nutritional value.
In this paper,Indian rhino horn is the main object of study. Fourier transform infrared spectroscopy(FTIR),X-ray fluorescence spectroscopy(XRF)and automatic amino acid analyzer were used to analyze the infrared spectroscopy and chemical composition of rhinoceros horn,in order to provide basic data for the research of rhinoceros horn substitutes and synthetic products. The results showed that the absorption peaks of amino acids,phosphatidic acid and taurine were obvious in infrared spectra. The main inorganic components of rhinoceros horn are CaO,Fe_2O_3,K_2O,ZnO,SiO_2,etc. Amino acid content is 481. 01 mg/g,medicinal amino acid content is rich,and the closeness of amino acid composition standard protein is 0. 74. The result indicates that the rhino horn has high nutritional value.
引文
[1]Zhu W W,Lan J J.Amino acid composition analysis and nutritional value evaluation of rhinoceros horn[J].Jiangsu Agricultural Sciences,2013,41(4):289290.朱伟伟,蓝建京.犀牛角氨基酸组成分析与营养价值评价[J].江苏农业科学,2013,41(4):289290.
[2]Damian Carrington,Hai W.The exotic price of rhinoceros horn makes bloody all over the world[J].University English,2017(5):3034.Damian Carrington,海威.犀牛角的离奇价格让血腥弥漫全球[J].大学英语,2017(5):3034.
[3]Zhou J M.Study on identification methods of rhinoceros horn and its products[D].Harbin:Northeast Forestry University,2010.周晶梅.犀牛角及其制品鉴定识别方法的研究[D].哈尔滨:东北林业大学,2010.
[4]Mu L Y.Analysis and identification of rhinoceros horn and its products by optical microscope and infrared spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2014,31(1):16.木丽云.犀牛角及其制品的显微镜和红外光谱分析鉴定[J].光谱实验室,2014,31(1):16.
[5]Fan W X,Zhu F K,He H L.Comparative study on trace elements in heat clearing Chinese medicinal herbs[J].Chinese Journal of Pharmaceutical Analysis,2010(2):310313.范文秀,朱芳坤,郝海玲.清热类中药中微量元素的比较研究[J].药物分析杂志,2010(2):310313.
[6]Yao X,Zhou G S,Tang Y P,et al,Evaluation and analysis of inorganic elements in Ginkgo biloba leaves by microwave digestionICPAES[J].Spectroscopy and Spectral Analysis,2013,33(3):808812.姚鑫,周桂生,唐于平,等.采用微波消解ICPAES法对不同产地果用银杏叶无机元素分析与评价[J].光谱学与光谱分析,2013,33(3):808812.
[7]Chen M H,Sun R H,Hu B C.The influence of serum magnesium level on the prognosis of critically ill patients[J].Chinese Critical Care Medicine.2015,27(3):213217.陈敏华,孙仁华,呼邦传.重症患者血清镁水平对预后的影响[J].中华危重病急救医学,2015,27(3):213217.
[8]Jiang P P,Han Y,Gu S H,et al.Determination of amino acids in five edible fungi and their nutritional evaluation[J].Amino Acids and Biotic Resources,2009,31(2):6771.姜萍萍,韩烨,顾赛红,等.五种食用菌氨基酸含量的测定及营养评价[J].氨基酸和生物资源,2009,31(2):6771.
[9]Jiang J Y,Zhao M,He Z,et al.Nutrition composition and evaluation of six edible dragonfly naiads[J].Biotic Resources,2017,39(5):4249.蒋筠雅,赵敏,何钊,等.六种食用蜻蜓稚虫营养成分分析和评价[J].生物资源,2017,39(5):4249.
[10]Jiang Z M,Wu Y T N,Wang S,et al.Amino acid composition and nutritional quality evaluation of wild Amygdalus pedunculatus Pall.Kernels from different growing regions[J].Food Science,2016,37(4):7782.姜仲茂,乌云塔娜,王森,等.不同产地野生长柄扁桃仁氨基酸组成及营养价值评价[J].食品科学,2016,37(4):7782.
[11]Wang J H.Medicinal Amino Acids[J].Pharmaceuticals abroad.Synthetic Drugs.Biochemical Drugs.Catalogue of Preparations,1982(4):3740.王建华.药用氨基酸[J].国外医药.合成药.生化药.制剂分册,1982(4):3740.
[12]Huang Q F,Deng Z J,Bi X X,et al.Meta analysis of the effect of arginine on immune function in patients with colorectal cancer[J].Journal of Qiqihar University of Medicine,2016,37(2):151152.黄秋芬,邓卓娟,毕晓霞,等.精氨酸强化肠外营养对结直肠癌患者免疫功能影响的Meta分析[J].齐齐哈尔医学院学报,2016,37(2):151152.
[13]LiaO X Y,Huang X Y,Feng L M,et al.Analysis of antibacterial activity of glycine[J].Food Safety Guide,2016,33:152154.廖夏云,黄小云,冯丽敏,等.甘氨酸的抑菌作用分析[J].食品安全导刊,2016,33:152154.
[2]Damian Carrington,Hai W.The exotic price of rhinoceros horn makes bloody all over the world[J].University English,2017(5):3034.Damian Carrington,海威.犀牛角的离奇价格让血腥弥漫全球[J].大学英语,2017(5):3034.
[3]Zhou J M.Study on identification methods of rhinoceros horn and its products[D].Harbin:Northeast Forestry University,2010.周晶梅.犀牛角及其制品鉴定识别方法的研究[D].哈尔滨:东北林业大学,2010.
[4]Mu L Y.Analysis and identification of rhinoceros horn and its products by optical microscope and infrared spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2014,31(1):16.木丽云.犀牛角及其制品的显微镜和红外光谱分析鉴定[J].光谱实验室,2014,31(1):16.
[5]Fan W X,Zhu F K,He H L.Comparative study on trace elements in heat clearing Chinese medicinal herbs[J].Chinese Journal of Pharmaceutical Analysis,2010(2):310313.范文秀,朱芳坤,郝海玲.清热类中药中微量元素的比较研究[J].药物分析杂志,2010(2):310313.
[6]Yao X,Zhou G S,Tang Y P,et al,Evaluation and analysis of inorganic elements in Ginkgo biloba leaves by microwave digestionICPAES[J].Spectroscopy and Spectral Analysis,2013,33(3):808812.姚鑫,周桂生,唐于平,等.采用微波消解ICPAES法对不同产地果用银杏叶无机元素分析与评价[J].光谱学与光谱分析,2013,33(3):808812.
[7]Chen M H,Sun R H,Hu B C.The influence of serum magnesium level on the prognosis of critically ill patients[J].Chinese Critical Care Medicine.2015,27(3):213217.陈敏华,孙仁华,呼邦传.重症患者血清镁水平对预后的影响[J].中华危重病急救医学,2015,27(3):213217.
[8]Jiang P P,Han Y,Gu S H,et al.Determination of amino acids in five edible fungi and their nutritional evaluation[J].Amino Acids and Biotic Resources,2009,31(2):6771.姜萍萍,韩烨,顾赛红,等.五种食用菌氨基酸含量的测定及营养评价[J].氨基酸和生物资源,2009,31(2):6771.
[9]Jiang J Y,Zhao M,He Z,et al.Nutrition composition and evaluation of six edible dragonfly naiads[J].Biotic Resources,2017,39(5):4249.蒋筠雅,赵敏,何钊,等.六种食用蜻蜓稚虫营养成分分析和评价[J].生物资源,2017,39(5):4249.
[10]Jiang Z M,Wu Y T N,Wang S,et al.Amino acid composition and nutritional quality evaluation of wild Amygdalus pedunculatus Pall.Kernels from different growing regions[J].Food Science,2016,37(4):7782.姜仲茂,乌云塔娜,王森,等.不同产地野生长柄扁桃仁氨基酸组成及营养价值评价[J].食品科学,2016,37(4):7782.
[11]Wang J H.Medicinal Amino Acids[J].Pharmaceuticals abroad.Synthetic Drugs.Biochemical Drugs.Catalogue of Preparations,1982(4):3740.王建华.药用氨基酸[J].国外医药.合成药.生化药.制剂分册,1982(4):3740.
[12]Huang Q F,Deng Z J,Bi X X,et al.Meta analysis of the effect of arginine on immune function in patients with colorectal cancer[J].Journal of Qiqihar University of Medicine,2016,37(2):151152.黄秋芬,邓卓娟,毕晓霞,等.精氨酸强化肠外营养对结直肠癌患者免疫功能影响的Meta分析[J].齐齐哈尔医学院学报,2016,37(2):151152.
[13]LiaO X Y,Huang X Y,Feng L M,et al.Analysis of antibacterial activity of glycine[J].Food Safety Guide,2016,33:152154.廖夏云,黄小云,冯丽敏,等.甘氨酸的抑菌作用分析[J].食品安全导刊,2016,33:152154.