食用植物油掺伪鉴别技术研究进展
|
摘要
食用植物油掺伪情况时有发生,原因之一是缺少有效的鉴别技术,从而较难发现并认定掺伪行为。国内外对食用植物油掺伪鉴别技术进行了大量研究,取得了一些成果,文章对这些成果进行了综述,并对食用植物油掺伪鉴别技术的发展方向进行了展望,旨在为食用植物油掺伪鉴别新技术的开发及食品安全监管提供理论参考与技术支持。
The adulteration of edible vegetable oil occurs from time to time,one of the reasons is the lack of effective identification technology,so it is difficult to find and identify the adulteration behavior. A large number of researches have been carried out at home and abroad on the identification technology of adulteration of edible vegetable oil. Some achievements have been made,and these achievements were summarized in this paper,and the development direction of adulteration identification technology of edible vegetable oil was prospected. The aim was to provide theoretical reference and technical support for the development of new technology for identification of adulteration of edible vegetable oil and the supervision of food safety.
The adulteration of edible vegetable oil occurs from time to time,one of the reasons is the lack of effective identification technology,so it is difficult to find and identify the adulteration behavior. A large number of researches have been carried out at home and abroad on the identification technology of adulteration of edible vegetable oil. Some achievements have been made,and these achievements were summarized in this paper,and the development direction of adulteration identification technology of edible vegetable oil was prospected. The aim was to provide theoretical reference and technical support for the development of new technology for identification of adulteration of edible vegetable oil and the supervision of food safety.
引文
[1]赵瑾,邹涛,陈宇迪,等.DSC方法在特级初榨橄榄油掺假鉴别中的应用[J].分析测试学报,2017,36(5):655-659.
[2]褚璇,王伟,赵昕,等.近红外光谱和特征光谱的山茶油掺假鉴别方法研究[J].光谱学与光谱分析,2017,37(1):75-79.
[3]王武,王建明,李颖,等.傅里叶变换近红外光谱结合RVM与新聚类算法鉴别灵芝孢子油多样掺假类别[J].光谱学与光谱分析,2017,37(4):1064-1068.
[4]孙通,吴宜青,许朋,等.近红外光谱联合CARS-PLS-LDA的山茶油检测[J].核农学报,2015,29(5):925-931.
[5]孙通,吴宜青,李晓珍,等.基于近红外光谱和子窗口重排分析的山茶油掺假检测[J].光学学报,2015,35(6):342-349.
[6]邓平建,耿艺介,梁裕,等.快速鉴别掺伪橄榄油的拉曼光谱-聚类分析方法[J].中国油脂,2015(2):50-55.
[7]杨坤,褚昆昆,朱祥,等.几种典型食用油脂拉曼光谱分析研究[J].粮食与油脂,2015,28(11):56-58.
[8] LI Y,FANG T,ZHU S,et al. Detection of olive oil adulteration with waste cooking oil via Raman spectroscopy combined with iPLS and SiPLS[J].Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2018,189:37-43.
[9] ZHU W,WANG X,CHEN L. Rapid detection of peanut oil adulteration using low-field nuclear magnetic resonance and chemometrics[J].Food Chemistry,2017,216:268-274.
[10]杨扬,殷乐,尹芳华,等.几种食用油的核磁共振光谱特征与地沟油的快速检测[J].中国油脂,2015,40(7):45-50.
[11]朱绍华,张帆,王美玲,等.稳定同位素比质谱法鉴别茶油中掺杂玉米油研究[J].中国食物与营养,2013,19(3):8-10.
[12]郭莲仙,梁福睿,梁一,等.基于稳定碳同位素示踪技术的商品植物油掺杂鉴别研究[J].现代食品科技,2014,30(5):292-296.
[13] HU J,WEI F,DONG X Y,et al. Characterization and quantification of triacylglycerols in peanut oil by off-line comprehensive two-dimensional liquid chromatography coupled with atmospheric pressure chemical ionization mass spectrometry[J].Journal of Separation Science,2013,36(2):288-300.
[14]赵海燕,龚灿,许旭.反相液相色谱-质谱法使用甲酸甲胺改善甘油三酯电喷雾离子化检测灵敏度[J].分析化学,2017,45(9):1323-1329.
[15] NG T T,SO P K,ZHENG B,et al. Rapid screening of mixed edible oils and gutter oils by matrix-assisted laser desorption/ionization mass spectrometry[J].Analytica Chimica Acta,2015,884:70-76.
[16]王龙星,金静,王淑秋,等.非正常食用油鉴别新方法(一):三种辣椒碱残留量的液相色谱-质谱分析[J].色谱,2012,30(11):1094-1099.
[17] MA F,YANG Q,MATTHAUS B,et al. Simultaneous determination of capsaicin and dihydrocapsaicin for vegetable oil adulteration by immunoaffinity chromatography cleanup coupled with LCMS/MS[J].Journal of Chromatography B Analytical Technologies in the Biomedical&Life Sciences,2016,1021:137.
[18]国振,李秀琴,高方园,等.液相色谱-同位素稀释质谱法检测食用油中辣椒碱类化合物[J].化学试剂,2016,38(6):491-495.
[19]周永生,罗士平,孔泳.固相萃取-气相色谱-质谱联用检测地沟油中胆固醇[J].色谱,2012,30(2):207-210.
[20] ZHAO H,WANG Y,XU X,et al. Detection of adulterated vegetable oils containing waste cooking oils based on the contents and ratios of cholesterol,β-sitosterol,and campesterol by Gas chromatography/mass spectrometry[J].Journal of Aoac International,2015,98(6):1645-1654.
[21]于瑞祥,杨瑞钰,方晓明,等.植物油中甾醇烯类物质的检测研究[J].中国油脂,2012,37(6):81-85.
[22] ROCA M,GALLARDOGUERRERO L,MINGUEZMOSQUERA M I,et al. Control of olive oil adulteration with copper-chlorophyll derivatives[J].Journal of Agricultural&Food Chemistry,2010,58(1):51-56.
[23]宋书锋,王丹,杨杰,等.橄榄油中叶绿素铜的筛查及确证[J].中华预防医学杂志,2015,49(1):45-49.
[24] LIAN W N,SHIUE J,WANG H H,et al. Rapid detection of copper chlorophyll in vegetable oils based on surface-enhanced Raman spectroscopy[J].Food Additives&Contaminants Part A Chemistry Analysis Control Exposure&Risk Assessment,2015,32(5):627-634.
[25] PEREZ-CAMINO M C,CERT A,ROMERO-SEGURA A,et al.Alkyl esters of fatty acids a useful tool to detect soft deodorized olive oils[J].J Agr Food Chem,2008,56(15):6740-6744.
[26] GOMEZCOCA R B,MOREDA W,PEREZCAMINO M C. Fatty acid alkyl esters presence in olive oil vs. organoleptic assessment[J].Food Chem,2012,135(3):1205-1209.
[27]侯靖,刘梦婷,江小明,等.橄榄油中脂肪酸烷基酯含量测定[J].中国油脂,2018,43(1):140-143.
[2]褚璇,王伟,赵昕,等.近红外光谱和特征光谱的山茶油掺假鉴别方法研究[J].光谱学与光谱分析,2017,37(1):75-79.
[3]王武,王建明,李颖,等.傅里叶变换近红外光谱结合RVM与新聚类算法鉴别灵芝孢子油多样掺假类别[J].光谱学与光谱分析,2017,37(4):1064-1068.
[4]孙通,吴宜青,许朋,等.近红外光谱联合CARS-PLS-LDA的山茶油检测[J].核农学报,2015,29(5):925-931.
[5]孙通,吴宜青,李晓珍,等.基于近红外光谱和子窗口重排分析的山茶油掺假检测[J].光学学报,2015,35(6):342-349.
[6]邓平建,耿艺介,梁裕,等.快速鉴别掺伪橄榄油的拉曼光谱-聚类分析方法[J].中国油脂,2015(2):50-55.
[7]杨坤,褚昆昆,朱祥,等.几种典型食用油脂拉曼光谱分析研究[J].粮食与油脂,2015,28(11):56-58.
[8] LI Y,FANG T,ZHU S,et al. Detection of olive oil adulteration with waste cooking oil via Raman spectroscopy combined with iPLS and SiPLS[J].Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2018,189:37-43.
[9] ZHU W,WANG X,CHEN L. Rapid detection of peanut oil adulteration using low-field nuclear magnetic resonance and chemometrics[J].Food Chemistry,2017,216:268-274.
[10]杨扬,殷乐,尹芳华,等.几种食用油的核磁共振光谱特征与地沟油的快速检测[J].中国油脂,2015,40(7):45-50.
[11]朱绍华,张帆,王美玲,等.稳定同位素比质谱法鉴别茶油中掺杂玉米油研究[J].中国食物与营养,2013,19(3):8-10.
[12]郭莲仙,梁福睿,梁一,等.基于稳定碳同位素示踪技术的商品植物油掺杂鉴别研究[J].现代食品科技,2014,30(5):292-296.
[13] HU J,WEI F,DONG X Y,et al. Characterization and quantification of triacylglycerols in peanut oil by off-line comprehensive two-dimensional liquid chromatography coupled with atmospheric pressure chemical ionization mass spectrometry[J].Journal of Separation Science,2013,36(2):288-300.
[14]赵海燕,龚灿,许旭.反相液相色谱-质谱法使用甲酸甲胺改善甘油三酯电喷雾离子化检测灵敏度[J].分析化学,2017,45(9):1323-1329.
[15] NG T T,SO P K,ZHENG B,et al. Rapid screening of mixed edible oils and gutter oils by matrix-assisted laser desorption/ionization mass spectrometry[J].Analytica Chimica Acta,2015,884:70-76.
[16]王龙星,金静,王淑秋,等.非正常食用油鉴别新方法(一):三种辣椒碱残留量的液相色谱-质谱分析[J].色谱,2012,30(11):1094-1099.
[17] MA F,YANG Q,MATTHAUS B,et al. Simultaneous determination of capsaicin and dihydrocapsaicin for vegetable oil adulteration by immunoaffinity chromatography cleanup coupled with LCMS/MS[J].Journal of Chromatography B Analytical Technologies in the Biomedical&Life Sciences,2016,1021:137.
[18]国振,李秀琴,高方园,等.液相色谱-同位素稀释质谱法检测食用油中辣椒碱类化合物[J].化学试剂,2016,38(6):491-495.
[19]周永生,罗士平,孔泳.固相萃取-气相色谱-质谱联用检测地沟油中胆固醇[J].色谱,2012,30(2):207-210.
[20] ZHAO H,WANG Y,XU X,et al. Detection of adulterated vegetable oils containing waste cooking oils based on the contents and ratios of cholesterol,β-sitosterol,and campesterol by Gas chromatography/mass spectrometry[J].Journal of Aoac International,2015,98(6):1645-1654.
[21]于瑞祥,杨瑞钰,方晓明,等.植物油中甾醇烯类物质的检测研究[J].中国油脂,2012,37(6):81-85.
[22] ROCA M,GALLARDOGUERRERO L,MINGUEZMOSQUERA M I,et al. Control of olive oil adulteration with copper-chlorophyll derivatives[J].Journal of Agricultural&Food Chemistry,2010,58(1):51-56.
[23]宋书锋,王丹,杨杰,等.橄榄油中叶绿素铜的筛查及确证[J].中华预防医学杂志,2015,49(1):45-49.
[24] LIAN W N,SHIUE J,WANG H H,et al. Rapid detection of copper chlorophyll in vegetable oils based on surface-enhanced Raman spectroscopy[J].Food Additives&Contaminants Part A Chemistry Analysis Control Exposure&Risk Assessment,2015,32(5):627-634.
[25] PEREZ-CAMINO M C,CERT A,ROMERO-SEGURA A,et al.Alkyl esters of fatty acids a useful tool to detect soft deodorized olive oils[J].J Agr Food Chem,2008,56(15):6740-6744.
[26] GOMEZCOCA R B,MOREDA W,PEREZCAMINO M C. Fatty acid alkyl esters presence in olive oil vs. organoleptic assessment[J].Food Chem,2012,135(3):1205-1209.
[27]侯靖,刘梦婷,江小明,等.橄榄油中脂肪酸烷基酯含量测定[J].中国油脂,2018,43(1):140-143.