工业中脱硫技术研究现状及进展
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摘要
分别介绍了工业废气脱硫在不同条件下对脱硫技术的选用,主要包括湿法脱硫、干法脱硫、加氢脱硫、非加氢脱硫,以及新兴的生物脱硫和以羰基金属作为脱硫剂的主要脱硫方法。对这些脱硫方法及其适用范围进行归纳总结,并对不同脱硫技术的脱除效率进行说明。最后展望了未来脱硫技术的发展趋势。
The desulfurization of industrial exhaust gas under different conditions is presented in terms of desulphurization technology selection,including wet desulphurization technology and dry desulphurization technology,hydro-desulphurization-technology and non hydro-desulphurization-technology,as well as the emerging biological desulphurization technology and carbonyl metal-based desulphurization technology.The application scope and removal efficiency of various desulphurization technologies are summarized.At last,the future development trend of desulphurization technologies is propected.
The desulfurization of industrial exhaust gas under different conditions is presented in terms of desulphurization technology selection,including wet desulphurization technology and dry desulphurization technology,hydro-desulphurization-technology and non hydro-desulphurization-technology,as well as the emerging biological desulphurization technology and carbonyl metal-based desulphurization technology.The application scope and removal efficiency of various desulphurization technologies are summarized.At last,the future development trend of desulphurization technologies is propected.
引文
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2 Ling Lixia,Han Peide,et al.DFT study on the regeneration mechanism of ZnO surface during the desulfurization of H2S[J].Fuel Process Technol,2013,109:49
3 陈焕章,李永丹,赵地顺.催化裂化汽油脱硫技术进展[J].化工科技,2004(3):46
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5 Zhao Ning,Li Li,Pan Siwei,et al.Sulfur poisoning and regeneration of SCR catalyst based on V2O5/TiO2[J].Adv Mater Res,2014,1010-1012:880
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7 王雪芹,吕宝航,刘江玲.干法烟气脱硫技术研究现状及进展[J].天津化工,2008,22(6):4
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9 Kang Xuming,Liu Sumei,Zhang Guoling.Reduced inorganic sulfurin the sediments of the yellow sea and east China sea[J].Acta Oceanologica Sinica,2014,33(9):100
10 Dondi Daniele,Zeffiro Alberto,Speltini Andrea,et al.The role of inorganic sulfur compounds in the pyrolysis of Kraft lignin[J].J Anal Appl Pyrolysis,2014,107:53
11 Kadijani Javad Alaei,Narimani Elhameh,Kadijani Hessameddin Alaei.Oxidative desulfurization of inorganic sulfur compounds in the presence of molybdenum complex and acetone as catalysts[J].Petroleum Coal,2014,56(1):116
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13 Yue Changtao,Li Shuyuan,Song He.Thermochemical sulfate reduction simulation experiments on the formation and distribution of organic sulfur compounds in the tuha crude oil[J].Bull Korean Chem Soc,2014,35(7):2057
14 赵业军,郑天庆.精脱硫工艺和加氢脱硫催化剂的研究[J].辽宁化工,2010,39(1):43
15 赵志海.生产清洁燃料的氧化脱硫技术新进展[J].当代石油化工,2002,10(7):26
16 刘影,徐忠贤.汽油脱硫的方法与优缺点比较[J].石油科技,2002,17(2):62
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18 徐如人,庞文琴.无机合成和制备化学[M].北京:高等教育出版社,2001:321
19 冯钰,高金森,徐春明.汽油清净分散剂聚异丁烯琥桲酰亚胺的合成工艺条件[J].石化科技,2002,9(4):238
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21 柯明,周爱国,赵振盛,等.FCC汽油烷基化脱硫技术进展[J].化工进展,2006,25(4):357
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23 项光明.液柱喷射烟气脱硫研究[D].北京:清华大学,2003
24 马苗云.燃煤电厂湿法烟气脱硫系统优化控制的仿真运行研究[D].北京:华北电力大学,2011
25 张艳维.汽油脱硫的方法与优缺点比较[J].精细石油化工进展,2011,5(7):48
26 姜成英,王蓉,刘会洲.石油和煤微生物脱硫技术的研究进展[J].过程工程学报,2001,1(1):80
27 Peter K,Vollhardt C,Schore Neil E.Organic Chemistry[M].New York:W H Freeman and Company,1999:1124
28 李建强,钮根林.催化裂化汽油脱硫技术研究及进展[J].天然气与石油,2003,21(2):26
29 刘振华.影响改良ADA法气体脱硫因素浅析[J].煤化工,1995(4):19
30 钱伯章.石油化工进展及市场分析[J].天然气与石油,2002,20(3):28
31 钱伯章,朱建芳.低硫和超低硫汽油生产技术发展[J].天然气与石油,2008,26(2):57
32 Chen Chihkuei,Lo Shanglien,Chen Tingyu.Regeneration and reuse of leachate from a municipal solid waste landfill[J].J Environ Biol,2014,35(6):1123
33 何小超,郑经堂,于维钊.过硫酸铵氧化活性炭对噻吩吸附等温线的研究[C]//第十一届全国青年催化学术会议论文集(下).昆明,2011
34 Wu Qiong,You Ruirong Clark Malcolm,et al.Pb(Ⅱ)removal from aqueous solution by a low-cost adsorbent dry desulfurization slag[J].Appl Surf Sci,2014,314:129
35 Steinbrecht Dieter,Weng Martin.Small-scale flameless fluidized bed combustion-perspectives for energetic utilization of difficult fuels[J].Combust Sci Technol,2014,186(4-5):529
36 Stallmann Olaf,Heinz Gerhard,Koss Peter Ulrich.Desulfurization in a regenerative calcium cycle system:US,20120188666[P].2012
37 Al-Degs Yahya S,Al-Ghouti Mohammad A.Influence of diesel acidification on dibenzothiophene removal:A new desulfurization practice[J].Sep Purif Technol,2015,139:1
38 Song Lechun,Bian Yinghui,Chen Jinshe,et al.Desulfurization performance of Cu(Ⅱ)-Ce(Ⅳ)/13Xzeolites for C4hydrocarbon[J].Adv Mater Res,2014,1743:926
39 Ramalakshmi Rongala,Bhattacharyya Moulika,Rao Chokkapu Eswara,et al.Synthesis,structure and chemistry of low-boron containing molybdaborane:Arachno-[Cp*Mo(CO)2B3H8][J].J Organometall Chem,DOI:10.1016/j.jorganchem.2014.12.031
40 Quaroni Luca,Zobi Fabio.Cellular imaging with metal carbonyl complexes[J].Inorg Chem Biol,DOI:10.100219781118682975.ch5
41 Gasser Gilles,Gasser Robin B,Hess Jeannine.Organometallic 2-cyano-2-aminobenzoate propyl derivates and their use as anthelmintics:EP,19860301986[P].1986
42 郭峰.络合铁法脱除H2S工艺研究[D].北京:中国石油大学,2007
43 祝文书,罗国华,徐新,等.大孔磺酸树脂CT175催化噬吩与异丁烯烷基化硫转移反应的研究[J].石油化工,2004,33(5):424
44 郑慧敏,刘清才,杨剑,等.烟气脱硫中亚硫酸钙的氧化动力学分析[J].重庆工学院学报:自然科学版,2009(1):169
2 Ling Lixia,Han Peide,et al.DFT study on the regeneration mechanism of ZnO surface during the desulfurization of H2S[J].Fuel Process Technol,2013,109:49
3 陈焕章,李永丹,赵地顺.催化裂化汽油脱硫技术进展[J].化工科技,2004(3):46
4 Shen Meiqing,Wen Huaiyou,Hao Teng,et al.Deactivation mechanism of SO2 on Cu/SAPO-34 NH3-SCR catalysts:Structure and active Cu2+[J].Catal Sci Technol,2015,5(3):1741
5 Zhao Ning,Li Li,Pan Siwei,et al.Sulfur poisoning and regeneration of SCR catalyst based on V2O5/TiO2[J].Adv Mater Res,2014,1010-1012:880
6 Smirnov Mikhail Yu,Kalinkin Alexander V,Pashis Andrei V,et al.Interaction of SO2with Pt model supported catalysts studied by XPS[J].J Phys Chem C,2014,118(38):22120
7 王雪芹,吕宝航,刘江玲.干法烟气脱硫技术研究现状及进展[J].天津化工,2008,22(6):4
8 Ozdemir Mehmet,Eryavuz Abdullah,Avci Gulcan,et al.Effects of supplementation of inorganic sulfur on some biochemical parameters in Angora goat's diet containing high nitrate levels[J].Turkish J Veterinary Animal Sci,2014,38(5):526
9 Kang Xuming,Liu Sumei,Zhang Guoling.Reduced inorganic sulfurin the sediments of the yellow sea and east China sea[J].Acta Oceanologica Sinica,2014,33(9):100
10 Dondi Daniele,Zeffiro Alberto,Speltini Andrea,et al.The role of inorganic sulfur compounds in the pyrolysis of Kraft lignin[J].J Anal Appl Pyrolysis,2014,107:53
11 Kadijani Javad Alaei,Narimani Elhameh,Kadijani Hessameddin Alaei.Oxidative desulfurization of inorganic sulfur compounds in the presence of molybdenum complex and acetone as catalysts[J].Petroleum Coal,2014,56(1):116
12 Kang Phil-Goo,Mitchell Myron J,Mayer Bernhard,et al.Isotopic evidence for determining the sources of dissolved organic sulfur in a forested catchment[J].Environ Sci Technol,2014,48(19):11259
13 Yue Changtao,Li Shuyuan,Song He.Thermochemical sulfate reduction simulation experiments on the formation and distribution of organic sulfur compounds in the tuha crude oil[J].Bull Korean Chem Soc,2014,35(7):2057
14 赵业军,郑天庆.精脱硫工艺和加氢脱硫催化剂的研究[J].辽宁化工,2010,39(1):43
15 赵志海.生产清洁燃料的氧化脱硫技术新进展[J].当代石油化工,2002,10(7):26
16 刘影,徐忠贤.汽油脱硫的方法与优缺点比较[J].石油科技,2002,17(2):62
17 唐孝炎.大气环境化学[M].北京:高等教育出版社,1990
18 徐如人,庞文琴.无机合成和制备化学[M].北京:高等教育出版社,2001:321
19 冯钰,高金森,徐春明.汽油清净分散剂聚异丁烯琥桲酰亚胺的合成工艺条件[J].石化科技,2002,9(4):238
20 Mortrenx A,et al.Industrial applications of homogeneous catalysis[M].New York,Dordrecht:D.Reidel Puh.Co,1988:19
21 柯明,周爱国,赵振盛,等.FCC汽油烷基化脱硫技术进展[J].化工进展,2006,25(4):357
22 孔华.石灰石湿法烟气脱硫技术的试验和理论研究[D].杭州:浙江大学,2001
23 项光明.液柱喷射烟气脱硫研究[D].北京:清华大学,2003
24 马苗云.燃煤电厂湿法烟气脱硫系统优化控制的仿真运行研究[D].北京:华北电力大学,2011
25 张艳维.汽油脱硫的方法与优缺点比较[J].精细石油化工进展,2011,5(7):48
26 姜成英,王蓉,刘会洲.石油和煤微生物脱硫技术的研究进展[J].过程工程学报,2001,1(1):80
27 Peter K,Vollhardt C,Schore Neil E.Organic Chemistry[M].New York:W H Freeman and Company,1999:1124
28 李建强,钮根林.催化裂化汽油脱硫技术研究及进展[J].天然气与石油,2003,21(2):26
29 刘振华.影响改良ADA法气体脱硫因素浅析[J].煤化工,1995(4):19
30 钱伯章.石油化工进展及市场分析[J].天然气与石油,2002,20(3):28
31 钱伯章,朱建芳.低硫和超低硫汽油生产技术发展[J].天然气与石油,2008,26(2):57
32 Chen Chihkuei,Lo Shanglien,Chen Tingyu.Regeneration and reuse of leachate from a municipal solid waste landfill[J].J Environ Biol,2014,35(6):1123
33 何小超,郑经堂,于维钊.过硫酸铵氧化活性炭对噻吩吸附等温线的研究[C]//第十一届全国青年催化学术会议论文集(下).昆明,2011
34 Wu Qiong,You Ruirong Clark Malcolm,et al.Pb(Ⅱ)removal from aqueous solution by a low-cost adsorbent dry desulfurization slag[J].Appl Surf Sci,2014,314:129
35 Steinbrecht Dieter,Weng Martin.Small-scale flameless fluidized bed combustion-perspectives for energetic utilization of difficult fuels[J].Combust Sci Technol,2014,186(4-5):529
36 Stallmann Olaf,Heinz Gerhard,Koss Peter Ulrich.Desulfurization in a regenerative calcium cycle system:US,20120188666[P].2012
37 Al-Degs Yahya S,Al-Ghouti Mohammad A.Influence of diesel acidification on dibenzothiophene removal:A new desulfurization practice[J].Sep Purif Technol,2015,139:1
38 Song Lechun,Bian Yinghui,Chen Jinshe,et al.Desulfurization performance of Cu(Ⅱ)-Ce(Ⅳ)/13Xzeolites for C4hydrocarbon[J].Adv Mater Res,2014,1743:926
39 Ramalakshmi Rongala,Bhattacharyya Moulika,Rao Chokkapu Eswara,et al.Synthesis,structure and chemistry of low-boron containing molybdaborane:Arachno-[Cp*Mo(CO)2B3H8][J].J Organometall Chem,DOI:10.1016/j.jorganchem.2014.12.031
40 Quaroni Luca,Zobi Fabio.Cellular imaging with metal carbonyl complexes[J].Inorg Chem Biol,DOI:10.100219781118682975.ch5
41 Gasser Gilles,Gasser Robin B,Hess Jeannine.Organometallic 2-cyano-2-aminobenzoate propyl derivates and their use as anthelmintics:EP,19860301986[P].1986
42 郭峰.络合铁法脱除H2S工艺研究[D].北京:中国石油大学,2007
43 祝文书,罗国华,徐新,等.大孔磺酸树脂CT175催化噬吩与异丁烯烷基化硫转移反应的研究[J].石油化工,2004,33(5):424
44 郑慧敏,刘清才,杨剑,等.烟气脱硫中亚硫酸钙的氧化动力学分析[J].重庆工学院学报:自然科学版,2009(1):169