柴达木盆地英西地区渐新统硫酸盐硫同位素组成及其地质意义
|
摘要
对柴达木盆地英西地区渐新统沉积环境和硫酸盐硫同位素组成进行了研究,刻画了硫化氢气体的形成机理及其对储层的改造作用,提出英西地区渐新统发生的TSR为其硫酸盐硫同位素组成的主控因素之一,并对储集层物性具有一定的改善作用。主要取得3项进展:①研究区为干旱气候、缺氧还原环境的咸化半深深湖沉积。Sr/Ba平均值为6.71,Fe/Mn平均值为44.35,(Fe+Al)/(Ca+Mg)平均值为0.45,以咸化半深—深湖沉积为主;Sr/Cu平均值为148.24,为干旱气候;U/Th平均值为0.55, w(V+Ni+Mn)平均值为495.77μg/g, V/(V+Ni)平均值为0.63,Ni/Co平均值为2.28,Cu/Zn平均值为1.00,为缺氧还原环境;②研究区硫酸盐硫同位素δ~(34)S偏重,主要受控于沉积环境和TSR硫同位素的分馏作用。硫酸盐种类主要包括硬石膏、芒硝、钙芒硝、天青石和重晶石等,以硬石膏分布最为广泛,其硫同位素δ~(34)S平均值为32.23‰,较同期海水明显偏重;③TSR对储集层物性、孔隙的连通具有一定的改善作用。TSR的产物H_2S具有较强的溶蚀能力,可进入酸性流体难以进入的极小空间进行溶蚀改造,虽然其伴生的方解石沉淀可占据一定量的储集空间,但硫酸盐的消耗可产生一定量的次生孔隙,对储集层物性起到改善作用。
Objectives: Study the sedimentary environment and sulfate sulfur isotope composition of the Oligocene Series in the Yingxi area,Qaidam Basin,and its geological significance.Methods: The characteristics of main and trace elements,sulfate type,sulfate isotope composition and main controlling factors,the formation mechanism of H_2S gas and its transformation effect on reservoirs were carried out.Resultst:(1) The average value of Sr/Ba in the study area is 6.71,the average Fe/Mn is 44.35,and the average value of( Fe+Al)/( Ca +Mg) is 0. 45,which is the sedimentation of semi-deep lake in salinization; the average value of Sr/Cu is 148.24,which is arid climate; the average value of U/Th is 0.55,the average value of V+Ni+Mn is 495.77 μg/g,the average value of V/( V+Ni) is 0.63,and the average value of Ni/Co is 2.28. The Cu/Zn average value is 1.00,which is an anoxic reduction environment.(2) There are many kinds of sulfates in the study area,including CaSO_4,Na_2SO_4 and CaNa_2(SO_4)_2,SrSO_4 and BaSO_4. Among them,CaSO_4 is the most widely distributed,and the average value of sulfur isotope δ~(34)S is 32. 23‰,which is obviously heavier than seawater in the same period. It is mainly controlled by a relatively closed sedimentary environment and fractionation of TSR sulfur isotope;(3) TSR generally has a certain improvement effect on reservoir physical properties,although its associated calcite precipitation can occupy a certain amount of storage space. However,the consumption of sulfate can produce a certain amount of secondary pores. More importantly,the product of hydrogen sulfide in the TSR has a strong ability to dissolve,and can enter a very small space where the acidic fluid is difficult to enter.Conclusions: It is proposed that the TSR of the Oligocene in the Yingxi area,Qaidam Basin,is the main controlling factor of the sulfate sulfur isotope composition,and it has a certain improvement effect on the reservoir physical properties.
Objectives: Study the sedimentary environment and sulfate sulfur isotope composition of the Oligocene Series in the Yingxi area,Qaidam Basin,and its geological significance.Methods: The characteristics of main and trace elements,sulfate type,sulfate isotope composition and main controlling factors,the formation mechanism of H_2S gas and its transformation effect on reservoirs were carried out.Resultst:(1) The average value of Sr/Ba in the study area is 6.71,the average Fe/Mn is 44.35,and the average value of( Fe+Al)/( Ca +Mg) is 0. 45,which is the sedimentation of semi-deep lake in salinization; the average value of Sr/Cu is 148.24,which is arid climate; the average value of U/Th is 0.55,the average value of V+Ni+Mn is 495.77 μg/g,the average value of V/( V+Ni) is 0.63,and the average value of Ni/Co is 2.28. The Cu/Zn average value is 1.00,which is an anoxic reduction environment.(2) There are many kinds of sulfates in the study area,including CaSO_4,Na_2SO_4 and CaNa_2(SO_4)_2,SrSO_4 and BaSO_4. Among them,CaSO_4 is the most widely distributed,and the average value of sulfur isotope δ~(34)S is 32. 23‰,which is obviously heavier than seawater in the same period. It is mainly controlled by a relatively closed sedimentary environment and fractionation of TSR sulfur isotope;(3) TSR generally has a certain improvement effect on reservoir physical properties,although its associated calcite precipitation can occupy a certain amount of storage space. However,the consumption of sulfate can produce a certain amount of secondary pores. More importantly,the product of hydrogen sulfide in the TSR has a strong ability to dissolve,and can enter a very small space where the acidic fluid is difficult to enter.Conclusions: It is proposed that the TSR of the Oligocene in the Yingxi area,Qaidam Basin,is the main controlling factor of the sulfate sulfur isotope composition,and it has a certain improvement effect on the reservoir physical properties.
引文
蔡春芳,赵龙.2016.热化学硫酸盐还原作用及其对油气与储集层的改造作用:进展与问题.矿物岩石地球化学通报,35(5):851～859.
陈启林.2007.大型咸化湖盆地层岩性油气藏有利条件与勘探方向-以柴达木盆地柴西南古近纪为例.岩性油气藏,19(1):46～51.
丁悌平,黎红,张国柄,李延河,李金城.1987.六氟化硫法测量33S/32S,34S/32S和36S/32S的方法研究.矿床地质,6(4):83～95.
方少仙,侯方浩.2013.碳酸盐岩成岩作用.北京:地质出版社:136.
国家能源局.2010.中华人民共和国石油天然气行业标准SY/T6168-2009——气藏分类.北京:石油工业出版社:5.
黄成刚,黄思静,吴素娟,陈启林.2006.100Ma来海水的锶同位素组成演化及主要控制因素.地球科学与环境学报,28(2):19～25.
黄成刚,袁剑英,曹正林,张世铭,王莹,佘敏.2015.咸化湖盆储层中咸水流体与岩石矿物相互作用实验模拟研究.矿物岩石地球化学通报,34(2):345～350.
黄成刚,袁剑英,吴梁宇,张小军,吴丽荣,潘星.2016.湖相白云岩成因模式及研究方法探讨.岩性油气藏,38(2):7～15.
黄成刚,倪祥龙,马新民,高妍芳,张昭,杨森,崔俊,赵权.2017a.致密湖相碳酸盐岩油气富集模式及稳产、高产主控因素.西北大学学报(自然科学版),47(5):724～738.
黄成刚,王建功,吴丽荣,倪祥龙,杨森,吴梁宇.2017b.古近系湖相碳酸盐岩储集特征与含油性分析——以柴达木盆地英西地区为例.中国矿业大学学报,46(5):909～922.
黄成刚,常海燕,崔俊,李亚锋,路艳平,李翔,马新民,吴梁宇.2017c.柴达木盆地西部地区渐新世沉积特征与油气成藏模式.石油学报,38(11):1230～1243.
黄成刚,李智勇,倪祥龙,马新民,张世铭,高妍芳,杨森,崔俊,伍坤宇.2017d.柴达木盆地英西地区E盐类矿物成因及油气地质意义.现代地质,31(4):779～790.
黄思静,石和,张萌,沈立成.2001.锶同位素地层学研究进展.地球科学进展.16(2):194～200.
李乐,姚光庆.2016.讨论:青藏高原北缘酒泉盆地青西凹陷白垩系湖相热水沉积原生白云岩.中国科学:地球科学,46(3):406～410.
李任伟,辛茂安.1989.东濮盆地蒸发岩的成因.沉积学报,7(4):141～147.
李兴远,周永章,安燕飞,吕文超,白明亮.2015.钦—杭成矿带南段丰村铅锌矿区下园垌矿段围岩微量元素的地球化学特征及其意义.地学前缘,22(2):131～143.
林耀庭.2003.四川盆地三叠纪海相沉积石膏和卤水的硫同位素研究.盐湖研究,11(2):1～7.
刘成林,王弭力,焦鹏程.1999.新疆罗布泊盐湖氢氧锶硫同位素地球化学及钾矿成矿物质来源.矿床地质,18(3):268～275.
刘群,陈郁华,李银彩.1987.中国中、新生代陆源碎屑—化学岩型盐类沉积.北京:科学技术出社.
卢耀如,张凤娥,阎葆瑞,郭秀红.2002.硫酸盐岩岩溶发育机理与有关地质环境效应.地球学报,23(1):1～6.
邱楠生,顾先觉.2000.柴达木盆地西部新生代的构造—热演化研究.地质科学,35(4):456～464.
史忠生,陈开远,何生.2005.东濮盐湖古近系锶、硫、氧同位素组成及古环境意义.地球科学(中国地质大学学报),30(6):430～436.
孙镇城.1997.中国新生代咸化湖泊沉积环境与油气生成.北京:石油工出版社.
王春连,刘成林,徐海明,王立成,沈立建.2013.湖北江陵凹陷古新统沙市组四段硫酸盐硫同位素组成及其地质意义.吉林大学学报(地球科学版),43(3):691～703.
颜开,刘成林,王九一,王春连,徐海明,王春林,余小灿,孟令阳.2018.江陵凹陷南缘盐井—申津渡凹地始新统硫同位素特征及古气候和物质来源探讨.地质学报,92(8):1647～1660.
远光辉,操应长,张林晔,王艳忠,李晓艳,葸克来,贾珍臻.2013.论碎屑岩储层成岩过程中有机酸的溶蚀增孔能力.地学前缘,20(5):207～219.
袁剑英,黄成刚,夏青松,曹正林,赵凡,万传治,潘星.2016.咸化湖盆碳酸盐岩储层特征及孔隙形成机理——以柴西地区始新统下干柴沟组为例.地质论评,62(1):111～126.
张浩,陈刚,朱玉双,黄成刚,杨爽,斯扬,李雪,薛钊.2017.柴达木盆地英西地区渐新统热液改造型白云岩的发现及意义.地质科技情报,36(1):87～97.
张华,刘成林,曹养同,孙宏伟,王立成.2013.塔里木古海湾新生代海退时限及方式的初步探讨.地球学报,34(5):577～584.
赵海彤,张永生,邢恩袁,王琳霖,于冬冬,商雯君,桂宝玲,李凯.2018.陕北盐盆中奥陶统马五段蒸发岩硫同位素特征及其古环境意义.地质学报,92(8):1680～1692.
赵加凡,陈小宏,金龙.2005.柴达木盆地第三纪盐湖沉积环境分析.西北大学学报(自然科学版),35(3):342～346.
郑喜玉,唐渊,徐昶.1988.西藏盐湖.北京:科学技术出版社.
周宾,关平,魏恒飞,张永庶,付玲,于川淇.2017.柴达木盆地扎哈泉地区致密油新类型的发现及其特征.北京大学学报(自然科学版),53(1):37～49.
朱光有,张水昌,梁英波,马永生,戴金星,周国源.2006.TSR对深部碳酸盐岩储层的溶蚀改造——四川盆地深部碳酸盐岩优质储层形成的重要方式.岩石学报,22(8):2182～2194.
朱光有,费安国,赵杰,刘策.2014.TSR成因H2S的硫同位素分馏特征与机制.岩石学报,30(12):3772～3786.
Ault W U,Kulp J L.1959.Isotopic geochemistry of sulphur.Geochim.Cosmochim.Acta,16(4):201～235.
Bouch J E,Milodowski A E,Ambrose K.2004.Contrasting patterns of pore-system modification due to dolomitization and fracturing in Dinantian basin-margin carbonates from the UK.In:Braithwaite C J R,Rizzi G,Darke G.eds.The Geometry and Petrogenesis of Dolomite Hydrocarbon Reservoirs.London:Geological Society Special Publication,235:325～348.
Cai Chunfang,Zhao Long.2016&.Thermochemical sulfate reduction and its effects on petroleum composition and reservoir quality:advances and problems.Bulletin of Mineralogy Petrology and Geochemistry,35(5):851～859.
Chambers L A,Trudinger P A.1979.Microbiological fractionation of stable sulfur isotopes:a review and critique.Geomicrobiology Journal,(3):249～293.
Chen Qilin.2007.Favorable condition and exploration prospecting of lithologic hydrocarbon reservoir in large-scale saline basin——Case study on the Eogene in the southwest of Qaidam basin.Lithologic Reservoirs,19(1):46～51.
Claypool G E,Holser W T,Kaplan I R,Sakai H,Zak I.1980.The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation.Chemical Geology,28(80):199～260.
Ding Tiping,Li Hong,Zhang Guobing,Li Yanhe,Li Jincheng.1987&.A study on determining 33S/32S,34S/32S and 36S/32S by SF6 method.Mineral Deposits,6(4):83～95.
Fang Shaoxian,Hou Fanghao.2013#.Diagenesis of Carbonate Rocks.Beijing:Geological Publishing House:1～136.
Fry B,Cox J,Gest H,Hayes J M.1986.Discrimination between 34S and 32S during bacterial metabolism of inorganic sulfur compounds.Journal of Bacteriology,165(1):328～330.
Hatch J R,Leventhal J S.1992.Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian(Missourian) Stark Shale Member of the Dennis Limestone,Wabaunsee County,Kansas,U S A.Chemical Geology,99(1～3):65～82.
Holser W T,Kaplan I R.1966.Isotope geochemistry of sedimentary sulfates.Chem.Geol.,1:93～135.
Huang Chenggang,Ni Xianglong,Ma Xinming,Gao Yanfang,Zhang Zhao,Yang Sen,Cui Jun,Zhao Quan.2017a&.Sedimentary characteristics and hydrocarbon accumulation model of Oligocene Series in the Western Qaidam Basin,China.Acta Petrolei Sinica,38(11):1230～1243.
Huang Chenggang,Huang Sijing,Wu Sujuan,Chen Qilin.2006&.Sr-isotope composition and evolvement in sea water over past 100 Ma and control factors.Journal of Earth Sciences and Environment,28(2):19～25.
Huang Chenggang,Wang Jiangong,Wu Lirong,Ni Xianglong,Yang Sen,Wu Liangyu.2017b&.Origin of salt minerals and oil—gas geological significance of E reservoirs in saline lacustrine basin of the Yingxi area,Qaidam Basin.Geoscience,31(4):779～790.
Huang Chenggang,Chang Haiyan,Cui Jun,Li Yafeng,Lu Yanping,Li Xiang,Ma Xinmin,Wu Liangyu.2017c&.Petroleum and gas enrichment pattern and major controlling factors of stable and high production of tight lacustrine carbonate rock reservoirs:A case study of the Yingxi area in Qaidam Basin.Journal of Northwest University(Natural Science Edition),47(5):724～738.
Huang Chenggang,Li Zhiyong,Ni Xianglong,Ma Xinmin,Zhang Shiming,Gao Yanfang,Yang Sen,Cui Jun,Wu Kunyu.2017d&.Characteristics of lacustrine carbonate reservoirs in Paleogene and oil-bearing property analysis:A case study of the Yingxi area from the Western Qaidam Basin.Journal of China University of Mining & Technology,46(5):909～922.
Huang Chenggang,Yuan Jianying,Cao Zhenglin,Zhang Shiming,Wang Ying,Se Min.2015&.The study of simulate experiment about the saline fluid—rock interaction in clastic reservoir in saline lacustrine basin.Bulletin of Mineralogy,Petrology and Geochemist,34(2):345～350.
Huang Chenggang,Yuan Jianying,Wu Liangyu,Zhang Xiaojun,Wu Lirong,Pan Xing.2016&.Origin of continental facies dolomite and research methods in lacustrine basin.Lithologic Reservoirs,38(1):7～15.
Huang Chenggang,Yuan,Xiaoyu Song Chunhui,Yuan Jianying,Ni Xianglong,Ma Xinming,Zhang Shiming.2018.Characteristics,origin,and role of salt minerals in the process of hydrocarbon accumulation in the saline lacustrine basin of the Yingxi Area,Qaidam,China.Carbonates Evaporites,33(3):431～446.DOI 10.1007/s13146-017-0350-9
Huang Sijing,Shi He,Zhang Meng,Shen Licheng.2001&.Progress in strontium isotope stratigraphy.Advance In Earth Sciences,16(2):194～200.
Jones B,Manning D A C.1994.Comparison of geological indices used for the interpretation of palaeoredox conditions in ancient mud-stones.Chemical Geology,111:111～129.
Kampschulte A,Strauss H.2004.The sulfur isotopic evolution of Phanerozoic seawater based on the analysis of structurally substituted sulfate in carbonates.Chemical Geology,204:255～286.
Kaplan I R,Rittenberg S C.1964.Microbiological fractionation of sulfur isotopes.J.Gen.Microbiol.,34(2):195～212.
Li Le,Yao Guangqing.2016&.Primary dolostone related to the Cretaceous lacustrine hydrothermal sedimentation in Qingxi sag,Jiuquan Basin on the northern Tibetan Plateau:Discussion.Science China Earth Sciences,46(3):406～410.
Li Renwei,Xin Mao’an.1989&.Origin of evaporates of Dongpu Basin.Acta Sedimentologica Sinica,7(4):141～147.
Li Xingyuan,Zhou Yongzhang,An Yanfei,L Wenchao,Bai Mingliang.2015&.Geochemical characteristics of trace elements and their implications for the Xiayuandong ore section of Fengcun lead—zinc deposits in Qingzhou—Hangzhou metallogenic belt.Earth Science Fontiers,22(2):131～143.
Lin Yaoting.2003&.Sulfur isotope study of Triassic marine sedimentary gypsum and brine in the Sichuan basin.Journal Of Salt Lake Research,11(2):1～7.
Liu Chenglin,Wang Mili,Jiao Pengcheng.1999&.Hydrogen,oxygen,strontium and sulfur isotopic geochemistry and potash-forming material sources of Lop Salt Lake,Xinjiang.Mineral Deposits,18(3):268～275.
Liu Qun,Chen Yuhua,Li Yincai.1987&.Mesozoic and Cenozoic Salt Deposition of Terrigenous Clastic Chemical Rock of China.Beijing:Science and Technology Press.
Lu Yaoru,Zhang Feng,Yan Baorui,Guo Xiuhong.2002&.Mechanism of karst development in sulphate rocks and its main geoenvironmental impacts.Acta Geoscientica Sinica,23(1):1～6.
Machel H G.2001.Bacterial and thermochemical sulfate reduction in diagenetic settings——old and new insights.Sedimentary Geology,140(1～2):143～175.
McArthur J M,Howarth R J,Bailey T R.2001.Strontium isotope stratigraphy:Lowess Version 3:Best～fit to the marine Sr～isotope curve for 0 to 509 Ma and accompanying look～up table for deriving numerical age.Journal of Geology,109:1555～170.
Mongenot T,Desprairies A,Lallierverges E,Laggoundefarge F,Tribovillard N.1996.Trace elements palaeoenvironmental markers in strongly mature hydrocarbon source rocks:the Cretaceous La Luna Formation of Venezuela.Sedimentary Geology,103(103):23～37.
National Energy Administration.2010#.The people’s Republic of China Petroleum and Natural Gas Industry Standards SY/T 6168-2009—— The Classification of Gas Poor.Beijing:Petroleum Industry Press,5.
Qiu Nansheng,Gu Xianjue.2000&.Tectono-thermal evolution of western qaidam basin,Northwest china.Scientia geologica sinica,35(4):456～464.
Raab M,Spiro B.1991.Sulfur isotopic variations during seawater evaporation with fractional crystallization.Chem.Geol.,86(4):323～333.
Sakai H.1968.Isotopic properties of sulfur compounds in hydrothermal processes.Geochem J.,2(1):2.
Shi Zhongsheng,Chen Kaiyuan,He Sheng.2005&.Strontium,sulfur and oxygen isotopic compositions and significance of paleoenvironment of Paleogene of Dongpu Depression.Earth Science,6(30):430～436.
Strauss H.1999.Geological evolution from isotope proxy signals——sulfur.Chemical Geology,161(1):89～101.
Sun Zhencheng.1997&.Sedimentary Environment and Hydrocarbon Generation of Cenozoic Brackish Lake in China.Beijing:Petroleum Industry Press.
Tabakh M E,Schreiber B C,Utha A C.1998.Diagenetic origin of basal anhydrite in Cretaceous Maha Sarakham salt,Khorat Plateau,NE Thailand.Sedimentology,45(3):579～594.
Tabakh M E,Utha A C,Schreiber B C.1999.Sedimentology of the Cretaceous Maha Sarakham evaporites in the Khorat Plateau of Northeastern Thailand.Sedimentary Geology,123(1):31～62.
Thode H G,Monster J,Dunford H B.1961.Sulphur isotope geochemistry.Geochimica et Cosmochimica Acta,25(3):159～174.
Thode H G,Monster J.1965.Sulfur isotope geochemistry of petroleum,evaporites and ancient seas.AAPG Mem.,4:367～377.
Wang Chunlian,Liu Chenglin,Xu Haiming,Wang Licheng,Shen Lijian.2013&.Sulfur isotopic composition of sulphate and its geological significance of member 4 of palaeocene shashi formation in JiangLing Depression of Hubei Province.Journal of Jilin University (Earthscience Edition),43 (3):691～703.
Yan Kai,Liu Chenlin,Wang Jiuyi,Wang Chunlian,Xu Haiming,Wang Chunlin,Yu Xiaocan,Meng Lingyang.2018.Sulfur isotopic characteristics of Eocene Series in the Yanjing—Shenjindu Sub-depression in the southern Jiangling Depression and its implication for paleoclimate and provenance.Acta Geologica Sinica,92(8):1647～1660.
Yuan Guanghui,Cao Yingchang,Yang Tian,Wang Yanzhong,Li Xiaoyan,Xi Kelai Jia Zhenzhen.2013&.Porosity enhancement potential through mineral dissolution by organic acids in the diagenetic process of clastic reservoir.Earth Science Frontiers,20(5):207～219.
Yuan Jianying,Huang Chenggang,Xia Qingsong,Cao Zhenglin,Zhao Fan,Wan Chuanzhi,Panxin.2016&.The characteristics of carbonate reservoir,and formation mechanism of pores in the saline lacustrine basin:A case study of the lower Eocene ganchaigou formation in western Qaidam Basin.Geological Review,62(1):111～126.
Zhang Hao,Chen Gang,Zhu Yushuang,Huang Chenggang,Yang Shuang,Si Yang,Li Xue,Xue Zhao.2017&.The discovery and significance of dolomites altered by hydrothermal fluid in Oligocene Series of the Yingxi area,Qaidam.Geological Science and Technology Information,36(1):87～97.
Zhang Hua,Liu Chenglin,Cao Yang Tong,Sun Hongwei,Wang Licheng.2013&.A tentative discussion on the time and the way of marine regression from Tarim Bay during the Cenozoic.Acta Geoscientica Sinica,34(5):577～584.
Zhao Haitong,Zhang Yongsheng,Xing Enyuan,Wang Linlin,Yu Dongdong,Shang Wenjun,Gui Baoling,Li Kai.2018.Sulfur isotopic characteristics of evaporite in the Middle Ordovician Mawu Member in the Salt Basin of northern Shaanxi and its paleoenvironment significance.Acta Geologica Sinica,92(8):1680～1692.
Zhao Jiafan,Chen Xiaohong,Jin Long.2005&.Analysis on sedimentary environment of the third stage saline lake in Qaidam Basin.Journal of Northwestern University(Natural Science Edition),35(3):342～346.
Zheng Xiyu,Tang Yuan,Xu Chang.1988&.Tibet Saline Lake.Beijing:Science and Technology Press.
Zhou Bin,Guan Ping,Wei Hengfei,Zhang Yongshu,Fu Ling,Yu Chuanqi.2017&.A new type of tight-oil and its feature in Zhahaquan area of Qaidam Basin.Acta Scientiarum Naturalium Universitatis Pekinensis,53(1):37～49.
Zhu Guangyou,Fei Anguo,Zhao Jie,Liu Che.2014&.Sulfur isotopic fractionation and mechanism for thermochemical sulfate reduction genetic H2S.Acta Petrologica Sinica,30(12):3772～3786.
Zhu Guangyou,Zhang Shuichang,Liang Yingbo,Dai Jinxing,Li Jian.2006&.Isotopic evidence of TSR origin for natural gas bearing high H2S contents within the Feixianguan Formation of the northeastern Sichuan Basin,southwestern China.Acta Petrologica Sinica,22(8):2182～2194.
陈启林.2007.大型咸化湖盆地层岩性油气藏有利条件与勘探方向-以柴达木盆地柴西南古近纪为例.岩性油气藏,19(1):46～51.
丁悌平,黎红,张国柄,李延河,李金城.1987.六氟化硫法测量33S/32S,34S/32S和36S/32S的方法研究.矿床地质,6(4):83～95.
方少仙,侯方浩.2013.碳酸盐岩成岩作用.北京:地质出版社:136.
国家能源局.2010.中华人民共和国石油天然气行业标准SY/T6168-2009——气藏分类.北京:石油工业出版社:5.
黄成刚,黄思静,吴素娟,陈启林.2006.100Ma来海水的锶同位素组成演化及主要控制因素.地球科学与环境学报,28(2):19～25.
黄成刚,袁剑英,曹正林,张世铭,王莹,佘敏.2015.咸化湖盆储层中咸水流体与岩石矿物相互作用实验模拟研究.矿物岩石地球化学通报,34(2):345～350.
黄成刚,袁剑英,吴梁宇,张小军,吴丽荣,潘星.2016.湖相白云岩成因模式及研究方法探讨.岩性油气藏,38(2):7～15.
黄成刚,倪祥龙,马新民,高妍芳,张昭,杨森,崔俊,赵权.2017a.致密湖相碳酸盐岩油气富集模式及稳产、高产主控因素.西北大学学报(自然科学版),47(5):724～738.
黄成刚,王建功,吴丽荣,倪祥龙,杨森,吴梁宇.2017b.古近系湖相碳酸盐岩储集特征与含油性分析——以柴达木盆地英西地区为例.中国矿业大学学报,46(5):909～922.
黄成刚,常海燕,崔俊,李亚锋,路艳平,李翔,马新民,吴梁宇.2017c.柴达木盆地西部地区渐新世沉积特征与油气成藏模式.石油学报,38(11):1230～1243.
黄成刚,李智勇,倪祥龙,马新民,张世铭,高妍芳,杨森,崔俊,伍坤宇.2017d.柴达木盆地英西地区E盐类矿物成因及油气地质意义.现代地质,31(4):779～790.
黄思静,石和,张萌,沈立成.2001.锶同位素地层学研究进展.地球科学进展.16(2):194～200.
李乐,姚光庆.2016.讨论:青藏高原北缘酒泉盆地青西凹陷白垩系湖相热水沉积原生白云岩.中国科学:地球科学,46(3):406～410.
李任伟,辛茂安.1989.东濮盆地蒸发岩的成因.沉积学报,7(4):141～147.
李兴远,周永章,安燕飞,吕文超,白明亮.2015.钦—杭成矿带南段丰村铅锌矿区下园垌矿段围岩微量元素的地球化学特征及其意义.地学前缘,22(2):131～143.
林耀庭.2003.四川盆地三叠纪海相沉积石膏和卤水的硫同位素研究.盐湖研究,11(2):1～7.
刘成林,王弭力,焦鹏程.1999.新疆罗布泊盐湖氢氧锶硫同位素地球化学及钾矿成矿物质来源.矿床地质,18(3):268～275.
刘群,陈郁华,李银彩.1987.中国中、新生代陆源碎屑—化学岩型盐类沉积.北京:科学技术出社.
卢耀如,张凤娥,阎葆瑞,郭秀红.2002.硫酸盐岩岩溶发育机理与有关地质环境效应.地球学报,23(1):1～6.
邱楠生,顾先觉.2000.柴达木盆地西部新生代的构造—热演化研究.地质科学,35(4):456～464.
史忠生,陈开远,何生.2005.东濮盐湖古近系锶、硫、氧同位素组成及古环境意义.地球科学(中国地质大学学报),30(6):430～436.
孙镇城.1997.中国新生代咸化湖泊沉积环境与油气生成.北京:石油工出版社.
王春连,刘成林,徐海明,王立成,沈立建.2013.湖北江陵凹陷古新统沙市组四段硫酸盐硫同位素组成及其地质意义.吉林大学学报(地球科学版),43(3):691～703.
颜开,刘成林,王九一,王春连,徐海明,王春林,余小灿,孟令阳.2018.江陵凹陷南缘盐井—申津渡凹地始新统硫同位素特征及古气候和物质来源探讨.地质学报,92(8):1647～1660.
远光辉,操应长,张林晔,王艳忠,李晓艳,葸克来,贾珍臻.2013.论碎屑岩储层成岩过程中有机酸的溶蚀增孔能力.地学前缘,20(5):207～219.
袁剑英,黄成刚,夏青松,曹正林,赵凡,万传治,潘星.2016.咸化湖盆碳酸盐岩储层特征及孔隙形成机理——以柴西地区始新统下干柴沟组为例.地质论评,62(1):111～126.
张浩,陈刚,朱玉双,黄成刚,杨爽,斯扬,李雪,薛钊.2017.柴达木盆地英西地区渐新统热液改造型白云岩的发现及意义.地质科技情报,36(1):87～97.
张华,刘成林,曹养同,孙宏伟,王立成.2013.塔里木古海湾新生代海退时限及方式的初步探讨.地球学报,34(5):577～584.
赵海彤,张永生,邢恩袁,王琳霖,于冬冬,商雯君,桂宝玲,李凯.2018.陕北盐盆中奥陶统马五段蒸发岩硫同位素特征及其古环境意义.地质学报,92(8):1680～1692.
赵加凡,陈小宏,金龙.2005.柴达木盆地第三纪盐湖沉积环境分析.西北大学学报(自然科学版),35(3):342～346.
郑喜玉,唐渊,徐昶.1988.西藏盐湖.北京:科学技术出版社.
周宾,关平,魏恒飞,张永庶,付玲,于川淇.2017.柴达木盆地扎哈泉地区致密油新类型的发现及其特征.北京大学学报(自然科学版),53(1):37～49.
朱光有,张水昌,梁英波,马永生,戴金星,周国源.2006.TSR对深部碳酸盐岩储层的溶蚀改造——四川盆地深部碳酸盐岩优质储层形成的重要方式.岩石学报,22(8):2182～2194.
朱光有,费安国,赵杰,刘策.2014.TSR成因H2S的硫同位素分馏特征与机制.岩石学报,30(12):3772～3786.
Ault W U,Kulp J L.1959.Isotopic geochemistry of sulphur.Geochim.Cosmochim.Acta,16(4):201～235.
Bouch J E,Milodowski A E,Ambrose K.2004.Contrasting patterns of pore-system modification due to dolomitization and fracturing in Dinantian basin-margin carbonates from the UK.In:Braithwaite C J R,Rizzi G,Darke G.eds.The Geometry and Petrogenesis of Dolomite Hydrocarbon Reservoirs.London:Geological Society Special Publication,235:325～348.
Cai Chunfang,Zhao Long.2016&.Thermochemical sulfate reduction and its effects on petroleum composition and reservoir quality:advances and problems.Bulletin of Mineralogy Petrology and Geochemistry,35(5):851～859.
Chambers L A,Trudinger P A.1979.Microbiological fractionation of stable sulfur isotopes:a review and critique.Geomicrobiology Journal,(3):249～293.
Chen Qilin.2007.Favorable condition and exploration prospecting of lithologic hydrocarbon reservoir in large-scale saline basin——Case study on the Eogene in the southwest of Qaidam basin.Lithologic Reservoirs,19(1):46～51.
Claypool G E,Holser W T,Kaplan I R,Sakai H,Zak I.1980.The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation.Chemical Geology,28(80):199～260.
Ding Tiping,Li Hong,Zhang Guobing,Li Yanhe,Li Jincheng.1987&.A study on determining 33S/32S,34S/32S and 36S/32S by SF6 method.Mineral Deposits,6(4):83～95.
Fang Shaoxian,Hou Fanghao.2013#.Diagenesis of Carbonate Rocks.Beijing:Geological Publishing House:1～136.
Fry B,Cox J,Gest H,Hayes J M.1986.Discrimination between 34S and 32S during bacterial metabolism of inorganic sulfur compounds.Journal of Bacteriology,165(1):328～330.
Hatch J R,Leventhal J S.1992.Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian(Missourian) Stark Shale Member of the Dennis Limestone,Wabaunsee County,Kansas,U S A.Chemical Geology,99(1～3):65～82.
Holser W T,Kaplan I R.1966.Isotope geochemistry of sedimentary sulfates.Chem.Geol.,1:93～135.
Huang Chenggang,Ni Xianglong,Ma Xinming,Gao Yanfang,Zhang Zhao,Yang Sen,Cui Jun,Zhao Quan.2017a&.Sedimentary characteristics and hydrocarbon accumulation model of Oligocene Series in the Western Qaidam Basin,China.Acta Petrolei Sinica,38(11):1230～1243.
Huang Chenggang,Huang Sijing,Wu Sujuan,Chen Qilin.2006&.Sr-isotope composition and evolvement in sea water over past 100 Ma and control factors.Journal of Earth Sciences and Environment,28(2):19～25.
Huang Chenggang,Wang Jiangong,Wu Lirong,Ni Xianglong,Yang Sen,Wu Liangyu.2017b&.Origin of salt minerals and oil—gas geological significance of E reservoirs in saline lacustrine basin of the Yingxi area,Qaidam Basin.Geoscience,31(4):779～790.
Huang Chenggang,Chang Haiyan,Cui Jun,Li Yafeng,Lu Yanping,Li Xiang,Ma Xinmin,Wu Liangyu.2017c&.Petroleum and gas enrichment pattern and major controlling factors of stable and high production of tight lacustrine carbonate rock reservoirs:A case study of the Yingxi area in Qaidam Basin.Journal of Northwest University(Natural Science Edition),47(5):724～738.
Huang Chenggang,Li Zhiyong,Ni Xianglong,Ma Xinmin,Zhang Shiming,Gao Yanfang,Yang Sen,Cui Jun,Wu Kunyu.2017d&.Characteristics of lacustrine carbonate reservoirs in Paleogene and oil-bearing property analysis:A case study of the Yingxi area from the Western Qaidam Basin.Journal of China University of Mining & Technology,46(5):909～922.
Huang Chenggang,Yuan Jianying,Cao Zhenglin,Zhang Shiming,Wang Ying,Se Min.2015&.The study of simulate experiment about the saline fluid—rock interaction in clastic reservoir in saline lacustrine basin.Bulletin of Mineralogy,Petrology and Geochemist,34(2):345～350.
Huang Chenggang,Yuan Jianying,Wu Liangyu,Zhang Xiaojun,Wu Lirong,Pan Xing.2016&.Origin of continental facies dolomite and research methods in lacustrine basin.Lithologic Reservoirs,38(1):7～15.
Huang Chenggang,Yuan,Xiaoyu Song Chunhui,Yuan Jianying,Ni Xianglong,Ma Xinming,Zhang Shiming.2018.Characteristics,origin,and role of salt minerals in the process of hydrocarbon accumulation in the saline lacustrine basin of the Yingxi Area,Qaidam,China.Carbonates Evaporites,33(3):431～446.DOI 10.1007/s13146-017-0350-9
Huang Sijing,Shi He,Zhang Meng,Shen Licheng.2001&.Progress in strontium isotope stratigraphy.Advance In Earth Sciences,16(2):194～200.
Jones B,Manning D A C.1994.Comparison of geological indices used for the interpretation of palaeoredox conditions in ancient mud-stones.Chemical Geology,111:111～129.
Kampschulte A,Strauss H.2004.The sulfur isotopic evolution of Phanerozoic seawater based on the analysis of structurally substituted sulfate in carbonates.Chemical Geology,204:255～286.
Kaplan I R,Rittenberg S C.1964.Microbiological fractionation of sulfur isotopes.J.Gen.Microbiol.,34(2):195～212.
Li Le,Yao Guangqing.2016&.Primary dolostone related to the Cretaceous lacustrine hydrothermal sedimentation in Qingxi sag,Jiuquan Basin on the northern Tibetan Plateau:Discussion.Science China Earth Sciences,46(3):406～410.
Li Renwei,Xin Mao’an.1989&.Origin of evaporates of Dongpu Basin.Acta Sedimentologica Sinica,7(4):141～147.
Li Xingyuan,Zhou Yongzhang,An Yanfei,L Wenchao,Bai Mingliang.2015&.Geochemical characteristics of trace elements and their implications for the Xiayuandong ore section of Fengcun lead—zinc deposits in Qingzhou—Hangzhou metallogenic belt.Earth Science Fontiers,22(2):131～143.
Lin Yaoting.2003&.Sulfur isotope study of Triassic marine sedimentary gypsum and brine in the Sichuan basin.Journal Of Salt Lake Research,11(2):1～7.
Liu Chenglin,Wang Mili,Jiao Pengcheng.1999&.Hydrogen,oxygen,strontium and sulfur isotopic geochemistry and potash-forming material sources of Lop Salt Lake,Xinjiang.Mineral Deposits,18(3):268～275.
Liu Qun,Chen Yuhua,Li Yincai.1987&.Mesozoic and Cenozoic Salt Deposition of Terrigenous Clastic Chemical Rock of China.Beijing:Science and Technology Press.
Lu Yaoru,Zhang Feng,Yan Baorui,Guo Xiuhong.2002&.Mechanism of karst development in sulphate rocks and its main geoenvironmental impacts.Acta Geoscientica Sinica,23(1):1～6.
Machel H G.2001.Bacterial and thermochemical sulfate reduction in diagenetic settings——old and new insights.Sedimentary Geology,140(1～2):143～175.
McArthur J M,Howarth R J,Bailey T R.2001.Strontium isotope stratigraphy:Lowess Version 3:Best～fit to the marine Sr～isotope curve for 0 to 509 Ma and accompanying look～up table for deriving numerical age.Journal of Geology,109:1555～170.
Mongenot T,Desprairies A,Lallierverges E,Laggoundefarge F,Tribovillard N.1996.Trace elements palaeoenvironmental markers in strongly mature hydrocarbon source rocks:the Cretaceous La Luna Formation of Venezuela.Sedimentary Geology,103(103):23～37.
National Energy Administration.2010#.The people’s Republic of China Petroleum and Natural Gas Industry Standards SY/T 6168-2009—— The Classification of Gas Poor.Beijing:Petroleum Industry Press,5.
Qiu Nansheng,Gu Xianjue.2000&.Tectono-thermal evolution of western qaidam basin,Northwest china.Scientia geologica sinica,35(4):456～464.
Raab M,Spiro B.1991.Sulfur isotopic variations during seawater evaporation with fractional crystallization.Chem.Geol.,86(4):323～333.
Sakai H.1968.Isotopic properties of sulfur compounds in hydrothermal processes.Geochem J.,2(1):2.
Shi Zhongsheng,Chen Kaiyuan,He Sheng.2005&.Strontium,sulfur and oxygen isotopic compositions and significance of paleoenvironment of Paleogene of Dongpu Depression.Earth Science,6(30):430～436.
Strauss H.1999.Geological evolution from isotope proxy signals——sulfur.Chemical Geology,161(1):89～101.
Sun Zhencheng.1997&.Sedimentary Environment and Hydrocarbon Generation of Cenozoic Brackish Lake in China.Beijing:Petroleum Industry Press.
Tabakh M E,Schreiber B C,Utha A C.1998.Diagenetic origin of basal anhydrite in Cretaceous Maha Sarakham salt,Khorat Plateau,NE Thailand.Sedimentology,45(3):579～594.
Tabakh M E,Utha A C,Schreiber B C.1999.Sedimentology of the Cretaceous Maha Sarakham evaporites in the Khorat Plateau of Northeastern Thailand.Sedimentary Geology,123(1):31～62.
Thode H G,Monster J,Dunford H B.1961.Sulphur isotope geochemistry.Geochimica et Cosmochimica Acta,25(3):159～174.
Thode H G,Monster J.1965.Sulfur isotope geochemistry of petroleum,evaporites and ancient seas.AAPG Mem.,4:367～377.
Wang Chunlian,Liu Chenglin,Xu Haiming,Wang Licheng,Shen Lijian.2013&.Sulfur isotopic composition of sulphate and its geological significance of member 4 of palaeocene shashi formation in JiangLing Depression of Hubei Province.Journal of Jilin University (Earthscience Edition),43 (3):691～703.
Yan Kai,Liu Chenlin,Wang Jiuyi,Wang Chunlian,Xu Haiming,Wang Chunlin,Yu Xiaocan,Meng Lingyang.2018.Sulfur isotopic characteristics of Eocene Series in the Yanjing—Shenjindu Sub-depression in the southern Jiangling Depression and its implication for paleoclimate and provenance.Acta Geologica Sinica,92(8):1647～1660.
Yuan Guanghui,Cao Yingchang,Yang Tian,Wang Yanzhong,Li Xiaoyan,Xi Kelai Jia Zhenzhen.2013&.Porosity enhancement potential through mineral dissolution by organic acids in the diagenetic process of clastic reservoir.Earth Science Frontiers,20(5):207～219.
Yuan Jianying,Huang Chenggang,Xia Qingsong,Cao Zhenglin,Zhao Fan,Wan Chuanzhi,Panxin.2016&.The characteristics of carbonate reservoir,and formation mechanism of pores in the saline lacustrine basin:A case study of the lower Eocene ganchaigou formation in western Qaidam Basin.Geological Review,62(1):111～126.
Zhang Hao,Chen Gang,Zhu Yushuang,Huang Chenggang,Yang Shuang,Si Yang,Li Xue,Xue Zhao.2017&.The discovery and significance of dolomites altered by hydrothermal fluid in Oligocene Series of the Yingxi area,Qaidam.Geological Science and Technology Information,36(1):87～97.
Zhang Hua,Liu Chenglin,Cao Yang Tong,Sun Hongwei,Wang Licheng.2013&.A tentative discussion on the time and the way of marine regression from Tarim Bay during the Cenozoic.Acta Geoscientica Sinica,34(5):577～584.
Zhao Haitong,Zhang Yongsheng,Xing Enyuan,Wang Linlin,Yu Dongdong,Shang Wenjun,Gui Baoling,Li Kai.2018.Sulfur isotopic characteristics of evaporite in the Middle Ordovician Mawu Member in the Salt Basin of northern Shaanxi and its paleoenvironment significance.Acta Geologica Sinica,92(8):1680～1692.
Zhao Jiafan,Chen Xiaohong,Jin Long.2005&.Analysis on sedimentary environment of the third stage saline lake in Qaidam Basin.Journal of Northwestern University(Natural Science Edition),35(3):342～346.
Zheng Xiyu,Tang Yuan,Xu Chang.1988&.Tibet Saline Lake.Beijing:Science and Technology Press.
Zhou Bin,Guan Ping,Wei Hengfei,Zhang Yongshu,Fu Ling,Yu Chuanqi.2017&.A new type of tight-oil and its feature in Zhahaquan area of Qaidam Basin.Acta Scientiarum Naturalium Universitatis Pekinensis,53(1):37～49.
Zhu Guangyou,Fei Anguo,Zhao Jie,Liu Che.2014&.Sulfur isotopic fractionation and mechanism for thermochemical sulfate reduction genetic H2S.Acta Petrologica Sinica,30(12):3772～3786.
Zhu Guangyou,Zhang Shuichang,Liang Yingbo,Dai Jinxing,Li Jian.2006&.Isotopic evidence of TSR origin for natural gas bearing high H2S contents within the Feixianguan Formation of the northeastern Sichuan Basin,southwestern China.Acta Petrologica Sinica,22(8):2182～2194.