静态顶空GC/MS测定卷烟滤嘴截留的烟气中苯系物
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- 英文论文题名：Determination of benzene series in mainstream cigarette smoke entrapped by filter by static headspace gas chromatograph-mass spectrometry
- 论文作者：姬厚伟 ; 满杰 ; 刘剑 ; 刘纳纳 ; 王芳 ; 韩伟
- 英文论文作者：JI Houwei ; MAN Jie ; LIU Jian ; LIU Nana ; WANG Fang ; HAN Wei ; Technology Center of China Tobacco Guizhou Industrial Co.Ltd
- 年：2016
- 作者机构：贵州中烟工业有限责任公司技术中心;
- 论文关键词：静态顶空 ; 气相色谱-质谱 ; 苯系物 ; 卷烟 ; 滤嘴
- 英文论文关键词：static headspace ; gas chromatograph-mass spectrometry ; benzene Series ; cigarette ; filter
- 会议召开时间：2016-12-01
- 会议录名称：中国烟草学会2016年度优秀论文汇编——烟草工业主题
- 语种：中文
- 分类号：TS411
- 学会代码：ZGYG
- 学会名称：中国烟草学会
- 页数：11
- 文件大小：1171k
- 原文格式：D
摘要
为测定卷烟滤嘴截留烟气中的苯系物,建立了静态顶空-气相色谱质谱选择离子定量的测定方法。样品经120℃、30 min静态顶空后,采用HP-INNOWAX柱分离和质谱检测,外标法定量。在优化条件下,该方法线性回归较好,相关系数r>0.999,线性范围为0.08～4μg/m L,定量检测限为0.003～0.005μg/支;回收率在86.2%～102.8%之间;RSD小于5%。该方法具有简单快速、准确灵敏等特点,适用于实际样品检测。
In order to determine benzene series in mainstream cigarette smoke entrapped by filter, a static headspace gas chromatography-mass spectrometry(SHS-GC/MS) under selected ion monitoring mode was developed. Under the optimized experimental conditions, cigarette filters were treated at 120 ℃for 30 min, and then the evolved products were separated on a HP-INNOWAX column, determined by MS and quantified by external standard method. The results showed that: the linear range was from 0.08 to 4 μg/ml with a good linear correlation coefficient(r>0.999) and the limits of quantification(LOQs) were 0.003~0.005 μg/cig; the recoveries were from 86.2 to 102.8% and the relative standard deviations(RSDs) were less than 5%.The method is accurate, simple, rapid, and is suitable for the analysis of seven benzene series in cigarette smoke removed by filter.
In order to determine benzene series in mainstream cigarette smoke entrapped by filter, a static headspace gas chromatography-mass spectrometry(SHS-GC/MS) under selected ion monitoring mode was developed. Under the optimized experimental conditions, cigarette filters were treated at 120 ℃for 30 min, and then the evolved products were separated on a HP-INNOWAX column, determined by MS and quantified by external standard method. The results showed that: the linear range was from 0.08 to 4 μg/ml with a good linear correlation coefficient(r>0.999) and the limits of quantification(LOQs) were 0.003~0.005 μg/cig; the recoveries were from 86.2 to 102.8% and the relative standard deviations(RSDs) were less than 5%.The method is accurate, simple, rapid, and is suitable for the analysis of seven benzene series in cigarette smoke removed by filter.
引文
[1]Schramm S,CarréV,Scheffler J,et al.Analysis of Mainstream and Sidestream Cigarette Smoke Particulate Matter by Laser Desorption Mass Spectrometry[J].Analytical Chemistry,2011,83(1):133-142.
[2]Adam T,Mitschke S,Streibel T,et al.Quantitative Puff-by-Puff-Resolved Characterization of Selected Toxic Compounds in Cigarette Mainstream Smoke[J].Chemical Research in Toxicology 2006,19(4):511-520.
[3]喻昕,刘建福,刘德华.卷烟滤嘴过滤效率研究概述[J].烟草科技,2003(1):9-14.
[4]庹苏行,胡念念,戴云辉.LC-MS/MS法检测卷烟滤嘴截留的烟气TSNAs[J].烟草科技,2008(12):42-46.
[5]王丽苹,任凤莲,吴名剑,等.不同材料滤嘴对卷烟主流烟气中挥发性羰基化合物截滤性能的研究[J].化学研究与应用,2008,20(6):796-798.
[6]于涛,张杰,曹建华,等.醋酸纤维滤嘴对卷烟主流烟气中主要酚类物质的选择性过滤研究[J].中国烟草学报,2009,15(3):25-28.
[7]刘跃华,何超,阮淑呈,等.卷烟滤嘴上菌核净农药的残留分析[J].分析试验室,2009,10:72-74.
[8]吴娜,李雪梅,黄海涛,等.气相色谱法测定烟气中拟除虫菊酯杀虫剂在卷烟滤嘴中的残留量[J].理化检验-化学分册,2012,(02):2 04-206.
[9]谢山岭,朱瑞芝,倪朝敏,等.固相萃取/高效液相色谱法对卷烟主流烟气中丙烯酰胺及其滤咀截留的测定[J].分析测试学报,2009,(10):1225-1228.
[10]宋金勇,马宇平,王文领,等.吸附热脱附-气相色谱/质谱联用分析卷烟主流烟气气相成分[J].衡阳师范学院学报,2006,(03):63-65.
[11]侯宏卫,熊巍,姜兴益,等.气相色谱-质谱联用法测定卷烟主流烟气气相物中挥发性有机化合物[J].中国烟草科学,2011,(05):81-86.
[12]Ye Q.Development of solid-phase microextraction followed by gas chromatography-mass spectrometry for rapid analysis of volatile organic chemicals in mainstream cigarette smoke[J].Journal of Chromatography A,2008,1213(2):239-244.
[13]Gregory M Polzin,Rachel E Kosa-Maines,David L Ashley,et al.Analysis of Volatile Organic Compounds in Mainstream Cigarette Smoke[J].Environmental Science&Technology,2007,41(4):1297-1302.
[14]Markus S Eschner,Ismailhaki Selmani,Thomas M Gro ger,et al.Online Comprehensive Two-Dimensional Characterization of Puff-by-Puff Resolved Cigarette Smoke by Hyphenation of Fast Gas Chromatography to Single-Photon Ionization Time-of-Flight Mass Spectrometry:Quantification of Hazardous Volatile Organic Compounds[J].Analytical Chemistry,2011,83(17):6619-6627.
[15]Stefan Mitschke,Thomas Adam,Thorsten Streibel,et al.Application of Time-of-Flight Mass Spectrometry with Laser-Based Photoionization Methods for Time-Resolved On-Line Analysis of Mainstream Cigarette Smoke[J].Analytical Chemistry,2005,77(8):2288-2296.
[16]柴欣生,付时雨,莫淑欢,等.静态顶空气相色谱技术[J].化学进展,2008,20(5):762-766.
[17]姬厚伟,刘剑,叶冲,等.静态顶空-气相色谱质谱选择性测定烟用白乳胶中7种苯系物[J].中国烟草学报,2012,18(06):5-9,22.
[18]刘玉敏,路庆华,庄明珠,等.静态顶空/气相色谱-质谱联用快速测定茶粉中残留溶剂[J].分析测试学报,2007(01):122-124.
[19]廖远熹,王昊阳,郭寅龙,等.中药柴胡挥发性成分的静态顶空-气相色谱-质谱分析[J].质谱学报,2005(03):187-192.
[20]许瑛华,朱炳辉,钟秀华,等.顶空气相色谱法测定化妆品中15种挥发性有机溶剂残留[J].色谱,2010,28(1):73-77.
[2]Adam T,Mitschke S,Streibel T,et al.Quantitative Puff-by-Puff-Resolved Characterization of Selected Toxic Compounds in Cigarette Mainstream Smoke[J].Chemical Research in Toxicology 2006,19(4):511-520.
[3]喻昕,刘建福,刘德华.卷烟滤嘴过滤效率研究概述[J].烟草科技,2003(1):9-14.
[4]庹苏行,胡念念,戴云辉.LC-MS/MS法检测卷烟滤嘴截留的烟气TSNAs[J].烟草科技,2008(12):42-46.
[5]王丽苹,任凤莲,吴名剑,等.不同材料滤嘴对卷烟主流烟气中挥发性羰基化合物截滤性能的研究[J].化学研究与应用,2008,20(6):796-798.
[6]于涛,张杰,曹建华,等.醋酸纤维滤嘴对卷烟主流烟气中主要酚类物质的选择性过滤研究[J].中国烟草学报,2009,15(3):25-28.
[7]刘跃华,何超,阮淑呈,等.卷烟滤嘴上菌核净农药的残留分析[J].分析试验室,2009,10:72-74.
[8]吴娜,李雪梅,黄海涛,等.气相色谱法测定烟气中拟除虫菊酯杀虫剂在卷烟滤嘴中的残留量[J].理化检验-化学分册,2012,(02):2 04-206.
[9]谢山岭,朱瑞芝,倪朝敏,等.固相萃取/高效液相色谱法对卷烟主流烟气中丙烯酰胺及其滤咀截留的测定[J].分析测试学报,2009,(10):1225-1228.
[10]宋金勇,马宇平,王文领,等.吸附热脱附-气相色谱/质谱联用分析卷烟主流烟气气相成分[J].衡阳师范学院学报,2006,(03):63-65.
[11]侯宏卫,熊巍,姜兴益,等.气相色谱-质谱联用法测定卷烟主流烟气气相物中挥发性有机化合物[J].中国烟草科学,2011,(05):81-86.
[12]Ye Q.Development of solid-phase microextraction followed by gas chromatography-mass spectrometry for rapid analysis of volatile organic chemicals in mainstream cigarette smoke[J].Journal of Chromatography A,2008,1213(2):239-244.
[13]Gregory M Polzin,Rachel E Kosa-Maines,David L Ashley,et al.Analysis of Volatile Organic Compounds in Mainstream Cigarette Smoke[J].Environmental Science&Technology,2007,41(4):1297-1302.
[14]Markus S Eschner,Ismailhaki Selmani,Thomas M Gro ger,et al.Online Comprehensive Two-Dimensional Characterization of Puff-by-Puff Resolved Cigarette Smoke by Hyphenation of Fast Gas Chromatography to Single-Photon Ionization Time-of-Flight Mass Spectrometry:Quantification of Hazardous Volatile Organic Compounds[J].Analytical Chemistry,2011,83(17):6619-6627.
[15]Stefan Mitschke,Thomas Adam,Thorsten Streibel,et al.Application of Time-of-Flight Mass Spectrometry with Laser-Based Photoionization Methods for Time-Resolved On-Line Analysis of Mainstream Cigarette Smoke[J].Analytical Chemistry,2005,77(8):2288-2296.
[16]柴欣生,付时雨,莫淑欢,等.静态顶空气相色谱技术[J].化学进展,2008,20(5):762-766.
[17]姬厚伟,刘剑,叶冲,等.静态顶空-气相色谱质谱选择性测定烟用白乳胶中7种苯系物[J].中国烟草学报,2012,18(06):5-9,22.
[18]刘玉敏,路庆华,庄明珠,等.静态顶空/气相色谱-质谱联用快速测定茶粉中残留溶剂[J].分析测试学报,2007(01):122-124.
[19]廖远熹,王昊阳,郭寅龙,等.中药柴胡挥发性成分的静态顶空-气相色谱-质谱分析[J].质谱学报,2005(03):187-192.
[20]许瑛华,朱炳辉,钟秀华,等.顶空气相色谱法测定化妆品中15种挥发性有机溶剂残留[J].色谱,2010,28(1):73-77.
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