迎春花叶提取物在H_2SO_4中对锌的缓蚀作用
详细信息 查看官网全文
- 英文论文题名：Inhibition by Jasminum nudiflorum Lindl Leaves Extract of the Corrosion of Zinc in H_2SO_4 Solution
- 论文作者：李向红 ; 邓书端 ; 张小红
- 英文论文作者：LI Xiang-hong ; DENG Shu-duan ; ZHANG Xiao-hong ; Faculty of Science ; Southwest Forestry University ; Faculty of Materials Engineering ; Southwest Forestry University
- 年：2012
- 作者机构：西南林业大学理学院;西南林业大学材料工程学院;
- 论文关键词：迎春花 ; 提取物 ; 硫酸 ; 锌 ; 缓蚀 ; 吸附
- 英文论文关键词：jasminum nudiflorum lindl ; extract ; sulfuric acid ; zinc ; inhibition ; adsorption
- 会议召开时间：2012-07-25
- 会议录名称：第十七届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TG174.42
- 学会代码：ZGHA
- 会议名称：第十七届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国重庆
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：4
- 文件大小：1934k
- 原文格式：O
- 会议级别：全国
摘要
采用失重法和动电位极化曲线法研究了迎春花(Jasminum nudiflorum Lindl.)叶提取物(JNLLE)在0.01 mol·L~(-1)H_2SO_4介质中对锌的缓蚀作用。结果表明:JNLLE在0.01 mol·L~(-1)H_2SO_4溶液中对锌具有良好的缓蚀作用。缓蚀率随缓蚀剂浓度的增加而增大,但随温度的升高而降低。JNLLE在锌表面的吸附符合Langmuir吸附等温式。极化曲线表明,JNLLE为混合抑制型缓蚀剂。
The inhibition effect of Jasminum nudiflorum Lindl.leaves extract(JNLLE) on the corrosion of zinc in 0.01 mol · L~(-1) H_2SO_4 was investigated by weight loss and potentiodynaniic polarization curves methods.The results show that JNLLE acts as a good inhibitor in 0.01 mol · L~(-1) H_2SO_4.Inhibition efficiency increases with the concentration of JNLLE,while decreases with the temperature.The adsorption of JNLLE obeys Langniuir adsorption isotherm.Polarization curves show that JNLLE acts as a mixed-type inhibitor.
The inhibition effect of Jasminum nudiflorum Lindl.leaves extract(JNLLE) on the corrosion of zinc in 0.01 mol · L~(-1) H_2SO_4 was investigated by weight loss and potentiodynaniic polarization curves methods.The results show that JNLLE acts as a good inhibitor in 0.01 mol · L~(-1) H_2SO_4.Inhibition efficiency increases with the concentration of JNLLE,while decreases with the temperature.The adsorption of JNLLE obeys Langniuir adsorption isotherm.Polarization curves show that JNLLE acts as a mixed-type inhibitor.
引文
[1]蒋金芝,孟凡桂,唐有根.金属有机缓蚀剂研究进展[J].有色金属,2003,55(1):22-24.
[2]Jinturkar P,Guan Y C,Han K N,et al.Dissolution and corrosion inhibition of copper,zinc and their alloys[J].Corrosion,1998,54(2):106-114.
[3]Fiaud C,Bensarsa S,Demesy Des Aulnois I,et al.Inhibiting properties of phosphines against zinc corrosion in acidic media[J].British Corrosion Journal,1987,22(2):109-112.
[4]木冠南,李琳,赵天培.硫酸介质中各类表面活性剂在锌表面上的吸附及其缓蚀作用[J].化学清洗,1999,15(1):1-3.
[5]Abiola O K,James A O.The effects of Aloe vera extract on corrosion and kinetics of corrosion process of zinc in HCl solution[J].Corrosion Science,2010,52:661-664.
[6]李向红,付惠,王毕辉,等.紫竹竹叶提取物作为盐酸中锌的缓蚀剂的研究[J].云南化工,2010,37(3):9-12.
[7]李向红,付惠,陆胤旭,等.麻竹竹叶提取物在NaOH中对锌的缓蚀作用[J].腐蚀与防护,2011,32(3):163-165.
[8]Li Xianghong,Deng Shuduan,Fu Hui.Inhibition by Jasminum nudiflorum Lindl.leaves extract of the corrosion of cold rolled steel in hydrochloric acid solution[J].Journal of Applied Electrochemistry,2010,40:1641-1649.
[9]杨伟波,卢成瑛,陈功锡,等.迎春花研究进展[J].食品科学,2008,29(4):474-477.
[10]木冠南,李向红,屈庆,等.稀土铈(Ⅳ)离子和钼酸钠在盐酸溶液中对冷轧钢的缓蚀协同作用[J].化学学报,2004,62(24):2386-2390.
[11]Fuchs Godec R,Dolecek V.A effect of sodium dodecylsufate on the corrosion of copper in sulphuric acid media[J].Colloids Surf.A 244(2004):73-76.
[12]曹楚南.腐蚀电化学原理(第二版)[M].北京:化学工业出版社,2004:235-238.
[2]Jinturkar P,Guan Y C,Han K N,et al.Dissolution and corrosion inhibition of copper,zinc and their alloys[J].Corrosion,1998,54(2):106-114.
[3]Fiaud C,Bensarsa S,Demesy Des Aulnois I,et al.Inhibiting properties of phosphines against zinc corrosion in acidic media[J].British Corrosion Journal,1987,22(2):109-112.
[4]木冠南,李琳,赵天培.硫酸介质中各类表面活性剂在锌表面上的吸附及其缓蚀作用[J].化学清洗,1999,15(1):1-3.
[5]Abiola O K,James A O.The effects of Aloe vera extract on corrosion and kinetics of corrosion process of zinc in HCl solution[J].Corrosion Science,2010,52:661-664.
[6]李向红,付惠,王毕辉,等.紫竹竹叶提取物作为盐酸中锌的缓蚀剂的研究[J].云南化工,2010,37(3):9-12.
[7]李向红,付惠,陆胤旭,等.麻竹竹叶提取物在NaOH中对锌的缓蚀作用[J].腐蚀与防护,2011,32(3):163-165.
[8]Li Xianghong,Deng Shuduan,Fu Hui.Inhibition by Jasminum nudiflorum Lindl.leaves extract of the corrosion of cold rolled steel in hydrochloric acid solution[J].Journal of Applied Electrochemistry,2010,40:1641-1649.
[9]杨伟波,卢成瑛,陈功锡,等.迎春花研究进展[J].食品科学,2008,29(4):474-477.
[10]木冠南,李向红,屈庆,等.稀土铈(Ⅳ)离子和钼酸钠在盐酸溶液中对冷轧钢的缓蚀协同作用[J].化学学报,2004,62(24):2386-2390.
[11]Fuchs Godec R,Dolecek V.A effect of sodium dodecylsufate on the corrosion of copper in sulphuric acid media[J].Colloids Surf.A 244(2004):73-76.
[12]曹楚南.腐蚀电化学原理(第二版)[M].北京:化学工业出版社,2004:235-238.