Synthesis of ZSM-5 with controlled SiO_2/Al_2O_3 ratio and their applications in butene catalytic cracking
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- 英文论文题名：Synthesis of ZSM-5 with controlled SiO_2/Al_2O_3 ratio and their applications in butene catalytic cracking
- 论文作者：郭成玉 ; 李兆飞 ; Xing Xin ; Liu Qiwu ; Pang Xinmei ; Li Fayong ; Yan Lijun ; Hu Yunfeng
- 英文论文作者：Guo Chengyu ; Li Zhaofei ; Xing Xin ; Liu Qiwu ; Pang Xinmei ; Li Fayong ; Yan Lijun ; Hu Yunfeng ; Petrochemical Research Institute of Petrochina ; Department of Chemistry & Chemical Engineering ; Northeast Petroleum University
- 年：2016
- 作者机构：Petrochemical Research Institute of Petrochina;Department of Chemistry & Chemical Engineering,Northeast Petroleum University;
- 英文论文关键词：ZSM-5 zeolite ; SiO_2/Al_2O_3 ratio ; 1-butene ; cracking
- 会议召开时间：2016-11-12
- 会议录名称：第十三届全国工业催化技术及应用年会论文集
- 语种：英文
- 分类号：TQ221.212;O643.36
- 学会代码：GYCH
- 会议名称：第十三届全国工业催化技术及应用年会
- 会议地点：中国广东广州
- 主办单位：全国工业催化信息站、工业催化杂志社
- 学会名称：工业催化杂志社
- 页数：6
- 文件大小：189k
- 原文格式：O
- 会议级别：全国
摘要
Cracking of C_4 hydrocarbons is an attractive technology for enhancing the production of propylene.ZSM-5 zeolite is mainly used as the active component in this process.The performance and the properties of the zeolite materials need to be studied in detail.In this presentation,ZSM-5 zeolites with controlled SiO_2/Al_2O_3 ratio varied in a fairly high span were prepared and characterized.Following that,the fixed bed catalysts were fabricated and evaluated in the catalytic cracking reaction of 1-butene.Their cracking performances were studied.A possible mechanism was proposed based on the data of reaction.Detailed studies will be presented in the conference.
Cracking of C_4 hydrocarbons is an attractive technology for enhancing the production of propylene.ZSM-5 zeolite is mainly used as the active component in this process.The performance and the properties of the zeolite materials need to be studied in detail.In this presentation,ZSM-5 zeolites with controlled SiO_2/Al_2O_3 ratio varied in a fairly high span were prepared and characterized.Following that,the fixed bed catalysts were fabricated and evaluated in the catalytic cracking reaction of 1-butene.Their cracking performances were studied.A possible mechanism was proposed based on the data of reaction.Detailed studies will be presented in the conference.
Cracking of C_4 hydrocarbons is an attractive technology for enhancing the production of propylene.ZSM-5 zeolite is mainly used as the active component in this process.The performance and the properties of the zeolite materials need to be studied in detail.In this presentation,ZSM-5 zeolites with controlled SiO_2/Al_2O_3 ratio varied in a fairly high span were prepared and characterized.Following that,the fixed bed catalysts were fabricated and evaluated in the catalytic cracking reaction of 1-butene.Their cracking performances were studied.A possible mechanism was proposed based on the data of reaction.Detailed studies will be presented in the conference.
引文
[1]David L Johnson,Glen Mills,Khushrav E Nariman,et al.Catalytic production of light olefins rich in propylene:US,6222087[P].2001-04-24.
[2]Cosyns J,Chodorge J,Commereuc D,et al.Maximize propylene production[J].Hydrocarbon Process,1998,77(3):61-66.
[3]Teng Jiawei,Zhao Guoliang,Xie Zaiku,et al.Effect of ZSM-5 zeolite crystal size on propylene production from catalytic cracking of C_4 olefins[J].Chinese Journal of Catalysis,2004,25(8):602-606.
[4]Zhu Genquan,Zhang Jiushun,Wang Xieqing.Study on the production of propylene and ethylene by catalytic cracking of butylenes[J].Petroleum Processing and Petrochemicals,2005,36(2):33-37.
[5]Zhang Huiming.Advances in catalytic conversion of C_4 olefin to propylene[J].Petrochemical Technology,2008,37(6):637-642.
[6]Liu Juntao,Zhong Siqing,Xu Chunming,et al.Study on production of propylene and ethylene from C_4 olefins by catalytic cracking[J].Petrochemical Technology,2005,34(1):9-13.
[7]Lin L F,Qin C F,Zhou Z X.Acid strength controlled reaction pathways for the catalytic cracking of 1-butene to propene over ZSM-5[J].J Catal,2014,309:136-145.
[8]Teng X,Wang Y,He M.Synthesis of ultra-high-silica ZSM-5 zeolites with tunable crystal sizes[J].Solid State Sci,2012,14:409-418.
[9]Bai Erzuo.Advances in catalytic process of olefin metathesis[J].Edvanced in Fine Petrochemicals,2001,2(2):24-27.
[10]Li Fufeng,Jia Wenhao,Chen Lixing,et al.Catalytic cracking of butene over nano-sized H-ZSM-5 catalyst[J].Chinese Journal of Catalysis,2007,28(6):567-571.
[2]Cosyns J,Chodorge J,Commereuc D,et al.Maximize propylene production[J].Hydrocarbon Process,1998,77(3):61-66.
[3]Teng Jiawei,Zhao Guoliang,Xie Zaiku,et al.Effect of ZSM-5 zeolite crystal size on propylene production from catalytic cracking of C_4 olefins[J].Chinese Journal of Catalysis,2004,25(8):602-606.
[4]Zhu Genquan,Zhang Jiushun,Wang Xieqing.Study on the production of propylene and ethylene by catalytic cracking of butylenes[J].Petroleum Processing and Petrochemicals,2005,36(2):33-37.
[5]Zhang Huiming.Advances in catalytic conversion of C_4 olefin to propylene[J].Petrochemical Technology,2008,37(6):637-642.
[6]Liu Juntao,Zhong Siqing,Xu Chunming,et al.Study on production of propylene and ethylene from C_4 olefins by catalytic cracking[J].Petrochemical Technology,2005,34(1):9-13.
[7]Lin L F,Qin C F,Zhou Z X.Acid strength controlled reaction pathways for the catalytic cracking of 1-butene to propene over ZSM-5[J].J Catal,2014,309:136-145.
[8]Teng X,Wang Y,He M.Synthesis of ultra-high-silica ZSM-5 zeolites with tunable crystal sizes[J].Solid State Sci,2012,14:409-418.
[9]Bai Erzuo.Advances in catalytic process of olefin metathesis[J].Edvanced in Fine Petrochemicals,2001,2(2):24-27.
[10]Li Fufeng,Jia Wenhao,Chen Lixing,et al.Catalytic cracking of butene over nano-sized H-ZSM-5 catalyst[J].Chinese Journal of Catalysis,2007,28(6):567-571.