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水文地球化学组分求异模型在吉林氟中毒区域规律研究中的应用
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摘要
氟元素是人体中重要的组成物质,人体可以通过饮食等环节从环境中摄取氟元素,环境中氟元素的含量及形态也对人体内氟的含量起到决定性作用,直接影响人的健康。人体内氟含量升高或降低都会对人体将康产生一定影响。根据饮用水水质标准,当地下水中氟含量高于l.0mg/L即为高氟水。人民长期饮用高氟水,容易产生氟中毒。地下水中总氟含量与地方病发病率有直接关系,通常地下水氟含量高的地区容易形成氟病区,然而并不是所有的高氟病区地下水中氟含量均较高,低氟病区的地下水中有时氟的浓度也会较高。出现这种现象的原因与所在地地下水动力条件、氟在地下水中的化学形态有关。不同的地下水动力条件可能影响氟元素的补给、排泄或富集速度,氟的不同化学形态可能影响了人体对氟的吸收性。本文通过对吉林西部氟病区自然地理情况、水文地质条件进行调查,同时收集了病区的发病情况,建立了地下水多组分求异模型对地下水中氟元素与其他各元素之间的存在关系进行计算,与发病率进行对比分析,得到一些规律性的结论。
     ⑴总氟含量与氟病发病率关系并不完全一致。
     通常人们认为地下水中总氟含量高的地区一定会引发较高的地氟病发病率,但从调查结果看出,部分低氟含量地下水区域也会产生高发病率,部分高氟含量的地下水反而是低氟病区。因此,不能一概而论的认为总氟含量和氟发病率之间有唯一的相关关系。
     ⑵可吸收氟化物含量的高低和病情轻重有直接关系。
     地下水中的氟存在于多种化学形态,以游离形态存在的氟容易被人体吸收,与其他元素结合存在的氟不易被人体吸收。根据调查,吉林西部地区的病区与地下水氟元素之间存在这种关系。而氟在地下水中到底以何种状态存在则与地下水中的水文地球化学条件及地下水化学类型存在直接关系。
     ⑶氟中毒病情与地下水更新的速度具有正相关关系。
     根据吉林西部的氟中毒病情与水文地质条件调查结果可以基本看出,地下水更新速度较快的地区容易形成轻病区,地下水更新缓慢的地区容易形成中或重病区。
     ⑷研究饮用地下水中的氟与氟中毒的关系时,除考虑元素氟和离子态含量之外,必须结合各该水文地球化学场中各元素含量和它们的化学形态进行系统的全面的综合研究和评价。
Fluorine is the important element for human health, human can absorb fluorinefrom environment through all kinds of methods just like fooding and drinking,andthe content and the chemical form can play an importmant role in the fluorinecontent in human bodys and effect on the human health.The increasing anddesending of the fluorine content in body can effect on the human health. Accordingto the Standards for Drinking Water Quality,when the fluorine concentration ingroundwater is lower than1mg/L,the groundwater is look at the high fluorinewater.Human drinking the high fluorine content water frequently can causefluorosis.The content of fluorine in groundwater is relationship with the rate offluorosis,high content fluorine can cause high rate of fluorosis normally, but not allof the content flurine in groundwater in serious fluorosis areas is higher than lightfluorosis areas.This pHenomenon has a relationship with the hydrogeololgycondition and the hydro-geochemistry of groundwater.The rate of fluorinesupplying,draining and concentrating is different in all kinds of groundwaterhydrogeololgy condition,and different fluorine chemical forms can effect on theabsorbability in body.This article builds on a Hydro-Geochemistry CombinationDifferent Model to calculate the relationship between the fluorine and the otherelements in groundwater through investigating the pHysical geograpHycircumstances and the hydrogeololgy conditions in the west of Jilin Province andcontrasting the rate of fluorosis, then explores the regular conclusion.
     ⑴The whole fluorine content is not accord to the rate of fluorosis actually.
     Normally, we consisder that the high fluorine content can cause the high rate offluorosis, but from the investigating result,some lower fluorine content area canappear serious flourosis area,and the higher fluorine content area is the light flourosisarea.We can not consider that the whole fluorine content has only relationship withthe fluorosis rate.
     ⑵The fluorine content can be absorbed by body has direct relationship with the fluorosis rate.
     The fluoride has lots of chemical form in groundwater, and free state fluorinecan be absorbed easily, combined-state fluorine can be absorbeddifficultly.According to the investigation, the fluorosis rate in the west of jilinprovince area exist the appearance between the fluoride in groundwater. The fluorinecan be existed in what form is related to the groundwater dynamics condition and thehydro-geochemistry.
     ⑶The fluorosis rate has relationship with the cycling rate of groundwater.
     From the investigation result of the fluorosis and hydrogeololgy conditions inthe west of Jilin Province,we can know that the high speed cycling groundwater areacan easily form light fluorosis regions and the low speed cycling groundwater areacan form middle or serious fluorosis regions normally.
     ⑷When we study the relationship between fluoride and fluorosis,we mustconsider the other elemens and the chemical form in addition to the fluorine,and dowhole assessment to the relationship between the fluorine and the other element indifferent hydro-geochemistry conditions.
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