黄兴镇硫酸锰行业地下水污染及其治理研究
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摘要
地下水是水环境不可分割且十分重要的一部分。在我国，随着经济建设的发展，片面追求经济利益最大化而忽视对环境的负面影响导致了地下水污染有逐年加重的趋势，这种现象在农村等不发达地区尤其严重。
目前，我国有关地下水污染治理的研究、实践和管理工作大大滞后于其污染的速度。具体表现在地下水和地质环境监测系统不健全；污染物在地下水中的迁移转化机理研究匮乏；地下水的修复技术理论研究多，工程实践少；地下水开发利用和监督管理工作薄弱：缺乏统一的地下水资源管理体系条例等。而这种滞后，不仅直接导致了环境的恶化，更是引发了许多社会问题，严重的甚至危及到了社会安定。
基于以上的诸多问题，本文以黄兴镇硫酸锰制造企业引起地下水严重污染这一事件为切入点，对地下水环境污染的监测、治理、防治等方面进行了探讨。黄兴镇问题曾经一度是各大媒体有关环境污染的关注焦点，其严重性甚至引起了国务院总理的关注。时至今日，各污染源企业已全部关停，但主要污染源——生产废渣依然处于放任状态，污染仍在继续。因此，对此地区的废渣处置和污水治理刻不容缓。
本文从黄兴镇污染区域的水文地质环境调查和水质监测入手，在水质评价的基础上查清了污染源并首次对其进行了污染特性和综合利用研究，并根据污染物的迁移规律对污染进行了模拟预测。在污染的治理方面，通过计算将水利截获技术应用到地下水层的净化当中去，并设计了废水抽出地面后的一系列净化处理装置设施。本文对污染区域包括污染源、污染受体这一有机整体进行了较为全面地分析研究，并充分考虑了当地的实际情况，研究结果真实可靠。
将地下水污染治理的理论研究充分准确地应用到实践中去是本文的指导思想，这一思想也在全文中得到了很好的体现。鉴于我国地下水的污染现象普遍而治理缺乏的现状，本文研究方法和结果具有一定的指导价值，可作为相似问题地下水污染治理的参考和借鉴。
Groundwater is an important and indiscerptible part of the whole water environment. In China, with the development of economic construction many people, organization and even government sometimes pursue the partial maximum profit only but ignore the negative influence on the environment. So the contamination of groundwater becomes more and more serious with the passing of year. What's more, this phenomenon is especially severe in many rural areas and undeveloped areas.
Now in our country many work concerning research, practice and management of groundwater contamination lag behind the speed of groundwater pollution greatly. Concretely speaking the delay include: groundwater and geologic Monitoring system are not perfect; research work on mechanisms of pollutants transporting and transforming is rare; theory about groundwater remediation is rich while engineering practice is poor; exploration and monitoring of groundwater is weakness. All of these not only lead to deterioration of environment but also arouse many social problems and even endanger social stability.
Based on these problems the paper carried out investigations on groundwater monitoring and treatment and take groundwater contamination in the town of huangxing as the real example. The huangxing town problem at one time is the focus of many media and even attracts the attention of government prime minister. Today all the pollution factories have been closed but the main pollutant-waste residue is still abandoned outdoor without any safety measures. So there is no time to delay to treat these waste residue and contaminated groundwater.
The paper started from the hydrological investigation and the contaminated water quality monitoring of the contaminated area. With the help of water quality evaluation the main pollutant was found and its pollution features and utilization were also studied in the third part of the paper. Furthermore in light of the pollutant migration rules a prediction was made w hich can display the pollution extent in the coming 20 years. As far as the wastewater treatment is concerned, hydraulic capture technique can be used in the aquifer purification. After that a series of equipments that contained aeration, filtration and coagulation was designed to treat the water pumped from the aquifer through the designed wells. The paper analyzed the contaminated area that includes contaminant source and victim comprehensively. At the same time the local condition were taken into sufficient account, so the investigation results are genuine and credible.
Taking use of groundwater treatment theory in practice sufficiently and accurately is the purpose of the paper and it has been carried out perfectly. Because groundwater contamination problems are popular in our country while its treatment is lacking, the methods and results of the paper have some guide effects and can be used as reference when similar problems occur.
目前，我国有关地下水污染治理的研究、实践和管理工作大大滞后于其污染的速度。具体表现在地下水和地质环境监测系统不健全；污染物在地下水中的迁移转化机理研究匮乏；地下水的修复技术理论研究多，工程实践少；地下水开发利用和监督管理工作薄弱：缺乏统一的地下水资源管理体系条例等。而这种滞后，不仅直接导致了环境的恶化，更是引发了许多社会问题，严重的甚至危及到了社会安定。
基于以上的诸多问题，本文以黄兴镇硫酸锰制造企业引起地下水严重污染这一事件为切入点，对地下水环境污染的监测、治理、防治等方面进行了探讨。黄兴镇问题曾经一度是各大媒体有关环境污染的关注焦点，其严重性甚至引起了国务院总理的关注。时至今日，各污染源企业已全部关停，但主要污染源——生产废渣依然处于放任状态，污染仍在继续。因此，对此地区的废渣处置和污水治理刻不容缓。
本文从黄兴镇污染区域的水文地质环境调查和水质监测入手，在水质评价的基础上查清了污染源并首次对其进行了污染特性和综合利用研究，并根据污染物的迁移规律对污染进行了模拟预测。在污染的治理方面，通过计算将水利截获技术应用到地下水层的净化当中去，并设计了废水抽出地面后的一系列净化处理装置设施。本文对污染区域包括污染源、污染受体这一有机整体进行了较为全面地分析研究，并充分考虑了当地的实际情况，研究结果真实可靠。
将地下水污染治理的理论研究充分准确地应用到实践中去是本文的指导思想，这一思想也在全文中得到了很好的体现。鉴于我国地下水的污染现象普遍而治理缺乏的现状，本文研究方法和结果具有一定的指导价值，可作为相似问题地下水污染治理的参考和借鉴。
Groundwater is an important and indiscerptible part of the whole water environment. In China, with the development of economic construction many people, organization and even government sometimes pursue the partial maximum profit only but ignore the negative influence on the environment. So the contamination of groundwater becomes more and more serious with the passing of year. What's more, this phenomenon is especially severe in many rural areas and undeveloped areas.
Now in our country many work concerning research, practice and management of groundwater contamination lag behind the speed of groundwater pollution greatly. Concretely speaking the delay include: groundwater and geologic Monitoring system are not perfect; research work on mechanisms of pollutants transporting and transforming is rare; theory about groundwater remediation is rich while engineering practice is poor; exploration and monitoring of groundwater is weakness. All of these not only lead to deterioration of environment but also arouse many social problems and even endanger social stability.
Based on these problems the paper carried out investigations on groundwater monitoring and treatment and take groundwater contamination in the town of huangxing as the real example. The huangxing town problem at one time is the focus of many media and even attracts the attention of government prime minister. Today all the pollution factories have been closed but the main pollutant-waste residue is still abandoned outdoor without any safety measures. So there is no time to delay to treat these waste residue and contaminated groundwater.
The paper started from the hydrological investigation and the contaminated water quality monitoring of the contaminated area. With the help of water quality evaluation the main pollutant was found and its pollution features and utilization were also studied in the third part of the paper. Furthermore in light of the pollutant migration rules a prediction was made w hich can display the pollution extent in the coming 20 years. As far as the wastewater treatment is concerned, hydraulic capture technique can be used in the aquifer purification. After that a series of equipments that contained aeration, filtration and coagulation was designed to treat the water pumped from the aquifer through the designed wells. The paper analyzed the contaminated area that includes contaminant source and victim comprehensively. At the same time the local condition were taken into sufficient account, so the investigation results are genuine and credible.
Taking use of groundwater treatment theory in practice sufficiently and accurately is the purpose of the paper and it has been carried out perfectly. Because groundwater contamination problems are popular in our country while its treatment is lacking, the methods and results of the paper have some guide effects and can be used as reference when similar problems occur.
引文
[1] 李广贺，刘兆昌，张旭．水资源利用工程与管理．北京：清华大学出版社，1998，303-304
[2] 明金．地下水污染调查与预测计算．王蔼玲，常连贵，廖进德译．北京：中国建筑工业出版社，1978，65-67
[3] 李昌静，卫钟鼎．地下水水质及其污染．北京：中国建筑工业出版社，1983，103-104
[4] Beck M B, Finney B A. Operational water quality management: Problem context and evaluation of a model for water quality. Water resource research, 1987,23(11): 2030-2042
[5] 王景华．区域环境与影响评价．北京：中国环境科学出版社，1990，14-16
[6] 邱汉学，黄巧珍．地下水环境背景值及其确定方法．青岛海洋大学学报，1994，12：16-19
[7] 谢明武．第二江流域地下水环境背景值研究的实验室方法．见：孙昌仁主编．中国环境地质研究．北京：科学技术出版社，1998，232-236
[8] 汪海．趋势面分析用于污染起始值计算初试．见：孙昌仁主编，中国环境地质研究．北京：科学技术出版社，1998，241-242
[9] Bond R G, Straub C P, Prober R, et al. Handbook of experimental control. Vol. 1 : Air Pollution. Cleveland: The Chemical Rubber Co., 1972,76-79
[10] Christensen H E, Fairchild E J. Registry of toxic effects of chemical substances: 1976 Edition. Prepared by Tracor Jitco Inc., Rockville, MD for National Institute for Occupational Safety and Health. HEW Publication, 1076, No. (NIOSH) 76-191
[11] Shepard T H. Catalog of reratogenic agents. Baltimore: Johns Hopkins University Press, 1973,128-129
[12] Environmental Protection Agency. Quality criteria for water. EPA: 1976, 440/9-76-023
[13] National Academy of Sciences, National Academy of Engineering. Water quality criteria 1972. In: A Report. National Academy of Sciences. Washington. D. C., 1973,EPA-R3-73-033
[14] American Conference of Governmental Industrial Hygienists. Documentation of the threshold limit values for substances in workroom air with supplement. Third Edition. Cincinnati: American Conference of Governmental Industrial Hygienists, 1974,93-98
[15] World Health Organization (WHO). Evaluation of certain food additives and the contaminants mercury, lead and cadmium: 16th Report of the Joint FAO-WHO expert committee on food additives. Geneva: WHO Tech, 1972, Report No. 505
[16] International Agency for Research on Cancer. IARC monographs on the evaluation of carcinogenic risk of chemicals to man. Lyon France: A World Health Organization Publication, 1976, 11 : 354-356
[17] 汪晶，和德科，汪尧衢．环境评价数据手册——有毒物质鉴定值．北京：化学工业出版社，1988，329
[18] Federal Water Pollution Control Administration. National Technical Advisory Committee Report. Water Quality Criteria (1968)
[19] U. S. Public health service. Drinking water standard: 1972. Title 42 Code Federal Regulations Part 72
[20] Roach S A. A More rational basis for air sampling programs. Am. Ind. Hyg. Assoc., 1966,27:10-12
[21] Patty F A. Arsenic, phosphorus, selenium, sulfur and tellurium. In: Patty. F. A. Industrial Hygiene and Toxicology, Second Revised Edition. New York: Interscience Publishers, 1963,2
[22] 李昌静，卫钟鼎．地下水水质及其污染．北京：中国建筑工业出版社，1983，106-109
[23] U.S. Environmental Protection Agency, Office of Research and Development. Scientific and technical assessments report on manganese. Available from National Technical Information Service. U. S. Department of Commerce Springfield, 1975,242-291
[24] Sullivan R J. Preliminary air pollution survey of manganese and its compounds: A literature review. Prepared by Litton system under contract No. PH 22-68-23 for National Air Pollution Control Administration. Available from Clearinghouse for Federal Scientific and Technical Information. U. S. Department of Commerce Springfield, 1969,39-69
[25] National Academy of Sciences, National Research Concil. Manganese: Medical and biological effects of environmental pollutants. Washington D. C. :National Academy of Sciences, 1973,89-92
[26] Sax N I. Dangerous properties of industrial materials, Fourth Edition. New York: Van Nostrand Reinhold Co., 1975,123-128
[27] 钱家忠．地下水资源评价与管理数学模型的研究进展．科学通报，2001，46(2)：99-102
[28] Yeh W WG. A proposed algorithm for the solution of the large-scale inverse problem in groundwater. Water resource research, 1976,12(3): 365-374
[29] 薛禹群．面临21世纪的中国地下水模拟问题．水文地质工程地质．1999，26(5)：1-3
[30] 李昌静，卫钟鼎．地下水水质及其污染．北京：中国建筑工业出版社，1983，289-291
[31] 朱利中．土壤及地下水有机污染的化学与生物修复．环境科学进展，1999，7(2)：65-71
[32] Borden R C, Carlos A G, Mark T B. Geochemical indicators of intrinsic bioremediation. Groundwater, 1995,33 (2): 180-189
[33] Haddad B I, Geoffrey B P. A successful integrated multicomponent remediation approach implemented at a petroleum-contaminated site. In: Marinos et al eds. Engineering Geology and the Environment. Balkema: Rotterdam, 1997,1877-1882
[34] Lang M M, Paul V R, Lewis S. Model simulations in support of field scale design and operation of bioremediation based on co metabolic degradation. Groundwater, 1997,35(4): 565-572
[35] Porta A. A review of European bioremediation practice. In: Hinchee R. E, Olfenbuffel R F eds. On-site bioremediation. Massachusetts U S A: Butterworth-Neinemann, 1991,1-13
[36] Taylor S W, Cliford R L, Elizabth A L. Biofouling of contaminated ground-water recovery wells: characterization of microorganisms. Groundwater, 1997,35(6): 973-980
[37] Mayotte T J, Michael J D, Craig S C. Bench-scale evaluation of bioaugmentation to remediate carbon tetrachloride-contaminated aquifer materials. Groundwater, 1997,34(2): 358-367
[38] Li Zhonghui, Robert S B. Sorption of perchloroethylene by surfactant-modified as controlled by surfactant loading. Environmental Science and Technology, 1989,32(15): 2278-2282
[39] 朱立中，陈宝梁．有机膨润土在废水处理中的应用及其发展．环境科学进展，1998，6(3)：53-61
[40] 张锡辉．水环境修复工程学．北京：化学工业出版社，2002，184-200
[41] Agell K G. In site remedial methods: air sparging. The National Environmental Journal, 1992,2(1): 20-23
[42] Brow R A, Jasiulewicz F. Air sparging: a new model for remediation. Pollution
Engineering, 1992,24(7): 52-55
[43] McCray J E, Ronald W F. Numerical simulation of air sparging for remediation of NAPL contamination. Groundwater, 1997,35 (1): 99-110
[44] Kuroda D R. Progress using bioremediation for site restoration by the US Army Corps of Engineers. Stud Environ Sci, 1997,66:393-404
[45] 张甲耀，李静，夏威林等．生物修复技术研究进展．应用与环境生物学报，1996，2(2)：193-199
[46] 陆光华，刘颖洁．地下水有机污染物的生物修复技术及应用．水资源保护，2003，(4)：15-18
[47] Hadely P W, Armstrong R. "Where is the benzene?" Examing California ground-water quality surveys. Ground Water, 1991,29(1): 35-40
[48] Borden R C, Gomez C A, Becker M T. Geochemical indicators of intrinsic bioremediation. Ground Water, 1995,33(2): 180-189
[49] 金棵，顾宗濂，谢思琴等．石油污染土壤及地下水的生物修复进展．应用与环境生物学报，1999，5(Suppl)：130-135
[50] 马文漪，杨柳燕．环境微生物工程．南京：南京大学出版社，1998，250-267
[51] 湖南省革命委员会地质局．区域水文地质调查报告(浏阳幅)．1976，20-22
[52] 长沙市环境科学研究所，长沙市环境监测中心站，长沙县环境监测站．长沙县黄兴镇硫酸锰行业环境污染现状调查报告．2002，15-18
[53] 李广贺，刘兆昌，张旭．水资源利用工程与管理．北京：清华大学出版社，1998，334-336
[54] 湖南省地质矿产局水文二队，长沙市环境保护研究所．长沙市浅层地下水环境质量评价报告．1984，22-28
[55] 汪晶，和德科，汪尧衢．环境评价数据手册——有毒物质鉴定值．北京：化学工业出版社，1988，350-360
[56] 蔡固平，葛晓霞，曾光明．黄兴镇硫酸锰企业污染调查与评价．中国环境监测，2003，19(4)：56-59
[57] 孙讷正．地下水污染：数学模型和数值方法．北京：地质出版社，1989，124-126
[58] 朱学愚，谢春红．地下水运移模型．北京：中国建筑工业出版社．1990，134-135
[59] 戴嘉尊，邱建贤．微分方程数值解法．南京：东南大学出版社．2002，95-98
[60] 宁平，陈亚雄，孙佩石，等．含锰废渣吸收低浓度SO_2生产MnSO_4·H_2O研究．环境科学，1997，18(6)：58-60
[61] 徐根良，谭智，吉晏辉，等．含重金属中和废渣固化处置实验研究[J]．环境工
程，1994，12(3)：40-44
[62] 王槐安，李德军．用电解金属锰废渣制作蜂窝型煤及燃烧技术研究．中国锰业，1994，12(5)：42-44
[63] 马铭杰，董坚，张化．海盐工业废渣的综合利用．化工环保，2001，21(5)：282-285
[64] 李万春．皮蛋白生产废渣中铬的回收利用．化工环保，1994，14(3)：182-184
[65] M J Sanchez-Martin, L F Lorenzo, M Sanchez-Camazano. Leaching of Cd, Zn, Pb, and Cu in packed and undisturbed columns of soils affected by the spill from a pyrite mine in the south of Spain. Soil and Sediment Contamination, 2001,10(4): 369-373
[66] 赵万有，郑玉兰，关连．铬渣对地下水、土壤、蔬菜污染机制的研究．环境保护科学，1994，20(1)：15-19
[67] Avelino Nunez-Delgado, Eugenio Lopez-Periago, Francisco Diaz-Fierros-Viqueira. Vertical leaching of contaminants present in cattle slurry: column trails with uncultivated and cultivated soils..Intern. J. Environmental studies, 1996,50:27-39
[68] 陈德放．火力发电厂电厂灰对土壤及浅层地下水的影响研究．能源研究与信息，2001，17(2)：106-112
[69] Vasileios Antoniadis, Brian John Alloway. Leaching of Cadmium, nickel, and zinc down the profile of sewage sludge-treated soil. Commun. Soil Sci. Plant anal., 2002,33(1&2):273-286
[70] 钱云平．Pb(Ⅱ)在地下水环境中迁移的机理及模型研究．水环境保护，1997，(4)：16-17
[71] Allen P. Washing of Zinc(Ⅱ) from contaminated soil column. Journal of Environmental Engineering, 1995,12(2): 174-184
[72] McGregor R G, Blowes D W, Jambor J L, et al. The solid-phase controls on the mobility of heavy metals at the copper cliff tailings area, Sudbury, Ontario, Canada. Journal of Contamination Hydrology, 1998, 33: 247-271
[73] 王代长，蒋新，卞永容，等．模拟酸雨对不同土层酸度和K~+淋失规律的影响．环境科学，2003，24(2)：30-34
[74] 丁国安，徐晓斌，房秀梅，等．中国酸雨现状及发展趋势．科学通报，1997，42(2)：169-173
[75] 国家环境保护总局编．水和废水监测分析方法(第四版)．北京：中国环境科学出版社，2002，247-250
[76] 魏复盛，齐文启．原字吸收光谱在环境分析中的应用．北京：中国环境科学
出版社，1988，156-222
[77] 张汉波，段昌群，胡斌，等．不同年代废弃的铅锌矿渣堆中重金属的动态变化．农业环境科学学报，2003，22(1)：67-69
[78] 吴攀，刘丛强，张元根，等．土法炼锌废渣堆中的重金属及其释放规律．中国环境科学，2002，22(2)：109-113
[79] 孙庆业，蓝崇钰．铅锌尾矿废弃地的化学性质研究．农业生态环境，2000，16(4)：36-39
[80] Chlopecka A, Bacon J R, Wilson M J, et al. Forms of cadmium, lead, and zinc in contaminated soils from southwest Poland. Journal of Environmental Quality, 1996,25:69-79
[81] 尹秀英，许文良，冯君．我国固体废物处理处置现状及对策．世界地质，1998，17(3)：100-104
[82] 王伟，袁光钰．我国的固体废物处理处置与发展．环境科学，1997，18(2)：97-91
[83] 徐根良，谭智，吉晏辉．含重金属中和废渣固化处置实验研究．环境工程，1994，12(3)：40-44
[84] 王九思，陈学民，肖举强，等．水处理化学[M]．化学工业出版社，2002，271
[85] 徐风广．含锰废渣用于公路回填土的实验研究．中国锰业，2001，19(4)：1-3
[86] 刘西德，姜力夫，高灿柱，等．从锰矿废渣制取硫酸锰的研究．山东化工，1994，(2)：12-14
[87] 朱晓帆，苏仕军，任志凌，等．软锰矿烟气脱硫研究．四川大学学报(工程科学版)，2000，32(5)：36-39
[88] 黄妍，王治军，童志权．软锰矿浆脱除烟气中的SO_2的研究．环境工程，1998，16(4)：43-46
[89] 粱仁杰，姚树森，唐昌敏，等．软锰矿浆烟气脱硫及副产硫酸锰的研究．重庆大学学报，1994，17(5)：88-93
[90] 陈秀成，曹瑞钰．低下水污染治理技术的进展．中国给水排水，2001，17(4)：23-26
[91] 贺玉晓，尹国勋，谭利敏．某电厂堆灰场附近浅层地下水中Cr~(6+)的成因及治理措施．环境污染治理技术与设备，2003，4(9)：74-76
[92] 刘新华，沈照理，钟佐燊，等．淄博市地下水水源地石油化工型油类污染及治理方案研究．现代地质——中国地质大学研究生院学报，1995，25(1)：17-18
[93] Stiver Enos L. Coproduced groundwater treatment and disposal potions during hyercarbon operations. GWMR, winter, 1989,131-339
[94] Schrader EDL. Remediation of floating, open oil spills: comparative efficiency of commercially available polypropylene sorbentbooms. Environ. Geo. And Wat. Resour, 1997,17(2): 1025-1039
[95] Robert E H, Reisinger H J. A practical application of multiphase transport theory to groundwater contamination problems. GWMR, winter, 1987,320-332
[96] 徐绍辉，朱学愚．地下水石油污染治理的水力截获技术及数值模拟．水力学报，1999，(1)：71-76
[97] Linda M, Abriola, Pinder G F. A multiphase approach to the modeling of porous media contamination by organic compounds,. 1.equation development. Water resource,1985,21 (1): 1-18
[98] Linda M. A multiphase approach to the modeling of porous media contamination by organic compounds,. 2. numerical simulation. Water resource, 1985,21(1): 18-28
[99] Fetter C W. Contamination hydrogeology. New York: Mac millam Publishing Company, 1993,202-231
[100] Tumm W, Morgan J J. Aquatic chemistry. New York: Wiley-Interscience Publishing Company, 1972,85-89
[101] 薛罡，赵洪宾．地下水除铁除锰技术新进展．给水排水，2002，28(7)：26-29
[102] 李圭白，刘超．地下水除铁除锰．第二版．北京：中国建筑工业出版社，1989，35-37
[103] 王九思，陈学民，肖举强等．水处理化学．北京：化学工业出版社，2002，274
[104] 张杰．生物固锰除锰技术的确立．给水排水，1996，22(11)：5-10
[105] 张杰，戴镇生．地下水除铁除锰现代观．给水排水，1996，22(10)：13-16
[106] 刘德明，徐爱军．地下水除锰机理研究．给水与废水国际会议论文集．北京：中国建筑工业出版社，1994，142-150
[107] 吴正淮．地下水除铁除锰机理的革新与应用．给水排水，1994，20(1)：3-14
[108] 刘灿生，黄毅轩．关于地下水除铁除锰机理的讨论．给水排水，1996，22(10)：17-20
[109] 许建华，杨人隽，王嘉宝．水的特种处理．上海：同济大学出版社，1989，65-75
[110] 同济大学主编．给水工程．北京：中国建筑工业出版社，1980，90-95
[111] 毛大庆．生物法除铁除锰的实验研究：[哈尔滨建筑大学学位论文]．哈尔滨：
哈尔滨建筑大学，1998，20-22
[112] 许京骐，陈培康．给水排水新技术．北京：中国建筑工业出版社，1988，30-35
[113] 薛罡，赵洪宾．地下水除铁除锰生物处理工艺实验研究．给水排水，2000，26(12)：8-11
[114] Moucher P. From conventional to biological removal of iron and manganese in France. AWWA, 1992,84(4): 158-166
[115] 王长平，李武．曝气．两级过滤工艺用于地下水除铁除锰．工业安全与环保，2002，28(12)：19-20
[116] 余健，郭照光，付国楷．两级过滤除铁除锰水厂的设计与运行．中国农村水利水电，2002，(1)：4-5
[2] 明金．地下水污染调查与预测计算．王蔼玲，常连贵，廖进德译．北京：中国建筑工业出版社，1978，65-67
[3] 李昌静，卫钟鼎．地下水水质及其污染．北京：中国建筑工业出版社，1983，103-104
[4] Beck M B, Finney B A. Operational water quality management: Problem context and evaluation of a model for water quality. Water resource research, 1987,23(11): 2030-2042
[5] 王景华．区域环境与影响评价．北京：中国环境科学出版社，1990，14-16
[6] 邱汉学，黄巧珍．地下水环境背景值及其确定方法．青岛海洋大学学报，1994，12：16-19
[7] 谢明武．第二江流域地下水环境背景值研究的实验室方法．见：孙昌仁主编．中国环境地质研究．北京：科学技术出版社，1998，232-236
[8] 汪海．趋势面分析用于污染起始值计算初试．见：孙昌仁主编，中国环境地质研究．北京：科学技术出版社，1998，241-242
[9] Bond R G, Straub C P, Prober R, et al. Handbook of experimental control. Vol. 1 : Air Pollution. Cleveland: The Chemical Rubber Co., 1972,76-79
[10] Christensen H E, Fairchild E J. Registry of toxic effects of chemical substances: 1976 Edition. Prepared by Tracor Jitco Inc., Rockville, MD for National Institute for Occupational Safety and Health. HEW Publication, 1076, No. (NIOSH) 76-191
[11] Shepard T H. Catalog of reratogenic agents. Baltimore: Johns Hopkins University Press, 1973,128-129
[12] Environmental Protection Agency. Quality criteria for water. EPA: 1976, 440/9-76-023
[13] National Academy of Sciences, National Academy of Engineering. Water quality criteria 1972. In: A Report. National Academy of Sciences. Washington. D. C., 1973,EPA-R3-73-033
[14] American Conference of Governmental Industrial Hygienists. Documentation of the threshold limit values for substances in workroom air with supplement. Third Edition. Cincinnati: American Conference of Governmental Industrial Hygienists, 1974,93-98
[15] World Health Organization (WHO). Evaluation of certain food additives and the contaminants mercury, lead and cadmium: 16th Report of the Joint FAO-WHO expert committee on food additives. Geneva: WHO Tech, 1972, Report No. 505
[16] International Agency for Research on Cancer. IARC monographs on the evaluation of carcinogenic risk of chemicals to man. Lyon France: A World Health Organization Publication, 1976, 11 : 354-356
[17] 汪晶，和德科，汪尧衢．环境评价数据手册——有毒物质鉴定值．北京：化学工业出版社，1988，329
[18] Federal Water Pollution Control Administration. National Technical Advisory Committee Report. Water Quality Criteria (1968)
[19] U. S. Public health service. Drinking water standard: 1972. Title 42 Code Federal Regulations Part 72
[20] Roach S A. A More rational basis for air sampling programs. Am. Ind. Hyg. Assoc., 1966,27:10-12
[21] Patty F A. Arsenic, phosphorus, selenium, sulfur and tellurium. In: Patty. F. A. Industrial Hygiene and Toxicology, Second Revised Edition. New York: Interscience Publishers, 1963,2
[22] 李昌静，卫钟鼎．地下水水质及其污染．北京：中国建筑工业出版社，1983，106-109
[23] U.S. Environmental Protection Agency, Office of Research and Development. Scientific and technical assessments report on manganese. Available from National Technical Information Service. U. S. Department of Commerce Springfield, 1975,242-291
[24] Sullivan R J. Preliminary air pollution survey of manganese and its compounds: A literature review. Prepared by Litton system under contract No. PH 22-68-23 for National Air Pollution Control Administration. Available from Clearinghouse for Federal Scientific and Technical Information. U. S. Department of Commerce Springfield, 1969,39-69
[25] National Academy of Sciences, National Research Concil. Manganese: Medical and biological effects of environmental pollutants. Washington D. C. :National Academy of Sciences, 1973,89-92
[26] Sax N I. Dangerous properties of industrial materials, Fourth Edition. New York: Van Nostrand Reinhold Co., 1975,123-128
[27] 钱家忠．地下水资源评价与管理数学模型的研究进展．科学通报，2001，46(2)：99-102
[28] Yeh W WG. A proposed algorithm for the solution of the large-scale inverse problem in groundwater. Water resource research, 1976,12(3): 365-374
[29] 薛禹群．面临21世纪的中国地下水模拟问题．水文地质工程地质．1999，26(5)：1-3
[30] 李昌静，卫钟鼎．地下水水质及其污染．北京：中国建筑工业出版社，1983，289-291
[31] 朱利中．土壤及地下水有机污染的化学与生物修复．环境科学进展，1999，7(2)：65-71
[32] Borden R C, Carlos A G, Mark T B. Geochemical indicators of intrinsic bioremediation. Groundwater, 1995,33 (2): 180-189
[33] Haddad B I, Geoffrey B P. A successful integrated multicomponent remediation approach implemented at a petroleum-contaminated site. In: Marinos et al eds. Engineering Geology and the Environment. Balkema: Rotterdam, 1997,1877-1882
[34] Lang M M, Paul V R, Lewis S. Model simulations in support of field scale design and operation of bioremediation based on co metabolic degradation. Groundwater, 1997,35(4): 565-572
[35] Porta A. A review of European bioremediation practice. In: Hinchee R. E, Olfenbuffel R F eds. On-site bioremediation. Massachusetts U S A: Butterworth-Neinemann, 1991,1-13
[36] Taylor S W, Cliford R L, Elizabth A L. Biofouling of contaminated ground-water recovery wells: characterization of microorganisms. Groundwater, 1997,35(6): 973-980
[37] Mayotte T J, Michael J D, Craig S C. Bench-scale evaluation of bioaugmentation to remediate carbon tetrachloride-contaminated aquifer materials. Groundwater, 1997,34(2): 358-367
[38] Li Zhonghui, Robert S B. Sorption of perchloroethylene by surfactant-modified as controlled by surfactant loading. Environmental Science and Technology, 1989,32(15): 2278-2282
[39] 朱立中，陈宝梁．有机膨润土在废水处理中的应用及其发展．环境科学进展，1998，6(3)：53-61
[40] 张锡辉．水环境修复工程学．北京：化学工业出版社，2002，184-200
[41] Agell K G. In site remedial methods: air sparging. The National Environmental Journal, 1992,2(1): 20-23
[42] Brow R A, Jasiulewicz F. Air sparging: a new model for remediation. Pollution
Engineering, 1992,24(7): 52-55
[43] McCray J E, Ronald W F. Numerical simulation of air sparging for remediation of NAPL contamination. Groundwater, 1997,35 (1): 99-110
[44] Kuroda D R. Progress using bioremediation for site restoration by the US Army Corps of Engineers. Stud Environ Sci, 1997,66:393-404
[45] 张甲耀，李静，夏威林等．生物修复技术研究进展．应用与环境生物学报，1996，2(2)：193-199
[46] 陆光华，刘颖洁．地下水有机污染物的生物修复技术及应用．水资源保护，2003，(4)：15-18
[47] Hadely P W, Armstrong R. "Where is the benzene?" Examing California ground-water quality surveys. Ground Water, 1991,29(1): 35-40
[48] Borden R C, Gomez C A, Becker M T. Geochemical indicators of intrinsic bioremediation. Ground Water, 1995,33(2): 180-189
[49] 金棵，顾宗濂，谢思琴等．石油污染土壤及地下水的生物修复进展．应用与环境生物学报，1999，5(Suppl)：130-135
[50] 马文漪，杨柳燕．环境微生物工程．南京：南京大学出版社，1998，250-267
[51] 湖南省革命委员会地质局．区域水文地质调查报告(浏阳幅)．1976，20-22
[52] 长沙市环境科学研究所，长沙市环境监测中心站，长沙县环境监测站．长沙县黄兴镇硫酸锰行业环境污染现状调查报告．2002，15-18
[53] 李广贺，刘兆昌，张旭．水资源利用工程与管理．北京：清华大学出版社，1998，334-336
[54] 湖南省地质矿产局水文二队，长沙市环境保护研究所．长沙市浅层地下水环境质量评价报告．1984，22-28
[55] 汪晶，和德科，汪尧衢．环境评价数据手册——有毒物质鉴定值．北京：化学工业出版社，1988，350-360
[56] 蔡固平，葛晓霞，曾光明．黄兴镇硫酸锰企业污染调查与评价．中国环境监测，2003，19(4)：56-59
[57] 孙讷正．地下水污染：数学模型和数值方法．北京：地质出版社，1989，124-126
[58] 朱学愚，谢春红．地下水运移模型．北京：中国建筑工业出版社．1990，134-135
[59] 戴嘉尊，邱建贤．微分方程数值解法．南京：东南大学出版社．2002，95-98
[60] 宁平，陈亚雄，孙佩石，等．含锰废渣吸收低浓度SO_2生产MnSO_4·H_2O研究．环境科学，1997，18(6)：58-60
[61] 徐根良，谭智，吉晏辉，等．含重金属中和废渣固化处置实验研究[J]．环境工
程，1994，12(3)：40-44
[62] 王槐安，李德军．用电解金属锰废渣制作蜂窝型煤及燃烧技术研究．中国锰业，1994，12(5)：42-44
[63] 马铭杰，董坚，张化．海盐工业废渣的综合利用．化工环保，2001，21(5)：282-285
[64] 李万春．皮蛋白生产废渣中铬的回收利用．化工环保，1994，14(3)：182-184
[65] M J Sanchez-Martin, L F Lorenzo, M Sanchez-Camazano. Leaching of Cd, Zn, Pb, and Cu in packed and undisturbed columns of soils affected by the spill from a pyrite mine in the south of Spain. Soil and Sediment Contamination, 2001,10(4): 369-373
[66] 赵万有，郑玉兰，关连．铬渣对地下水、土壤、蔬菜污染机制的研究．环境保护科学，1994，20(1)：15-19
[67] Avelino Nunez-Delgado, Eugenio Lopez-Periago, Francisco Diaz-Fierros-Viqueira. Vertical leaching of contaminants present in cattle slurry: column trails with uncultivated and cultivated soils..Intern. J. Environmental studies, 1996,50:27-39
[68] 陈德放．火力发电厂电厂灰对土壤及浅层地下水的影响研究．能源研究与信息，2001，17(2)：106-112
[69] Vasileios Antoniadis, Brian John Alloway. Leaching of Cadmium, nickel, and zinc down the profile of sewage sludge-treated soil. Commun. Soil Sci. Plant anal., 2002,33(1&2):273-286
[70] 钱云平．Pb(Ⅱ)在地下水环境中迁移的机理及模型研究．水环境保护，1997，(4)：16-17
[71] Allen P. Washing of Zinc(Ⅱ) from contaminated soil column. Journal of Environmental Engineering, 1995,12(2): 174-184
[72] McGregor R G, Blowes D W, Jambor J L, et al. The solid-phase controls on the mobility of heavy metals at the copper cliff tailings area, Sudbury, Ontario, Canada. Journal of Contamination Hydrology, 1998, 33: 247-271
[73] 王代长，蒋新，卞永容，等．模拟酸雨对不同土层酸度和K~+淋失规律的影响．环境科学，2003，24(2)：30-34
[74] 丁国安，徐晓斌，房秀梅，等．中国酸雨现状及发展趋势．科学通报，1997，42(2)：169-173
[75] 国家环境保护总局编．水和废水监测分析方法(第四版)．北京：中国环境科学出版社，2002，247-250
[76] 魏复盛，齐文启．原字吸收光谱在环境分析中的应用．北京：中国环境科学
出版社，1988，156-222
[77] 张汉波，段昌群，胡斌，等．不同年代废弃的铅锌矿渣堆中重金属的动态变化．农业环境科学学报，2003，22(1)：67-69
[78] 吴攀，刘丛强，张元根，等．土法炼锌废渣堆中的重金属及其释放规律．中国环境科学，2002，22(2)：109-113
[79] 孙庆业，蓝崇钰．铅锌尾矿废弃地的化学性质研究．农业生态环境，2000，16(4)：36-39
[80] Chlopecka A, Bacon J R, Wilson M J, et al. Forms of cadmium, lead, and zinc in contaminated soils from southwest Poland. Journal of Environmental Quality, 1996,25:69-79
[81] 尹秀英，许文良，冯君．我国固体废物处理处置现状及对策．世界地质，1998，17(3)：100-104
[82] 王伟，袁光钰．我国的固体废物处理处置与发展．环境科学，1997，18(2)：97-91
[83] 徐根良，谭智，吉晏辉．含重金属中和废渣固化处置实验研究．环境工程，1994，12(3)：40-44
[84] 王九思，陈学民，肖举强，等．水处理化学[M]．化学工业出版社，2002，271
[85] 徐风广．含锰废渣用于公路回填土的实验研究．中国锰业，2001，19(4)：1-3
[86] 刘西德，姜力夫，高灿柱，等．从锰矿废渣制取硫酸锰的研究．山东化工，1994，(2)：12-14
[87] 朱晓帆，苏仕军，任志凌，等．软锰矿烟气脱硫研究．四川大学学报(工程科学版)，2000，32(5)：36-39
[88] 黄妍，王治军，童志权．软锰矿浆脱除烟气中的SO_2的研究．环境工程，1998，16(4)：43-46
[89] 粱仁杰，姚树森，唐昌敏，等．软锰矿浆烟气脱硫及副产硫酸锰的研究．重庆大学学报，1994，17(5)：88-93
[90] 陈秀成，曹瑞钰．低下水污染治理技术的进展．中国给水排水，2001，17(4)：23-26
[91] 贺玉晓，尹国勋，谭利敏．某电厂堆灰场附近浅层地下水中Cr~(6+)的成因及治理措施．环境污染治理技术与设备，2003，4(9)：74-76
[92] 刘新华，沈照理，钟佐燊，等．淄博市地下水水源地石油化工型油类污染及治理方案研究．现代地质——中国地质大学研究生院学报，1995，25(1)：17-18
[93] Stiver Enos L. Coproduced groundwater treatment and disposal potions during hyercarbon operations. GWMR, winter, 1989,131-339
[94] Schrader EDL. Remediation of floating, open oil spills: comparative efficiency of commercially available polypropylene sorbentbooms. Environ. Geo. And Wat. Resour, 1997,17(2): 1025-1039
[95] Robert E H, Reisinger H J. A practical application of multiphase transport theory to groundwater contamination problems. GWMR, winter, 1987,320-332
[96] 徐绍辉，朱学愚．地下水石油污染治理的水力截获技术及数值模拟．水力学报，1999，(1)：71-76
[97] Linda M, Abriola, Pinder G F. A multiphase approach to the modeling of porous media contamination by organic compounds,. 1.equation development. Water resource,1985,21 (1): 1-18
[98] Linda M. A multiphase approach to the modeling of porous media contamination by organic compounds,. 2. numerical simulation. Water resource, 1985,21(1): 18-28
[99] Fetter C W. Contamination hydrogeology. New York: Mac millam Publishing Company, 1993,202-231
[100] Tumm W, Morgan J J. Aquatic chemistry. New York: Wiley-Interscience Publishing Company, 1972,85-89
[101] 薛罡，赵洪宾．地下水除铁除锰技术新进展．给水排水，2002，28(7)：26-29
[102] 李圭白，刘超．地下水除铁除锰．第二版．北京：中国建筑工业出版社，1989，35-37
[103] 王九思，陈学民，肖举强等．水处理化学．北京：化学工业出版社，2002，274
[104] 张杰．生物固锰除锰技术的确立．给水排水，1996，22(11)：5-10
[105] 张杰，戴镇生．地下水除铁除锰现代观．给水排水，1996，22(10)：13-16
[106] 刘德明，徐爱军．地下水除锰机理研究．给水与废水国际会议论文集．北京：中国建筑工业出版社，1994，142-150
[107] 吴正淮．地下水除铁除锰机理的革新与应用．给水排水，1994，20(1)：3-14
[108] 刘灿生，黄毅轩．关于地下水除铁除锰机理的讨论．给水排水，1996，22(10)：17-20
[109] 许建华，杨人隽，王嘉宝．水的特种处理．上海：同济大学出版社，1989，65-75
[110] 同济大学主编．给水工程．北京：中国建筑工业出版社，1980，90-95
[111] 毛大庆．生物法除铁除锰的实验研究：[哈尔滨建筑大学学位论文]．哈尔滨：
哈尔滨建筑大学，1998，20-22
[112] 许京骐，陈培康．给水排水新技术．北京：中国建筑工业出版社，1988，30-35
[113] 薛罡，赵洪宾．地下水除铁除锰生物处理工艺实验研究．给水排水，2000，26(12)：8-11
[114] Moucher P. From conventional to biological removal of iron and manganese in France. AWWA, 1992,84(4): 158-166
[115] 王长平，李武．曝气．两级过滤工艺用于地下水除铁除锰．工业安全与环保，2002，28(12)：19-20
[116] 余健，郭照光，付国楷．两级过滤除铁除锰水厂的设计与运行．中国农村水利水电，2002，(1)：4-5