基于响应性聚合物的超分子组装及功能材料制备
|
摘要
通过非共价键相互作用自发进行的大分子超分子自组装体系以及基于聚合的杂化纳米材料和传感器对材料科学、生命科学、信息科学以及纳米科学与技术等众多的科学领域的发展都产生了重大的影响,已经成为21世纪最重要的科学问题之一。本论文集中研究环境响应性聚合物的控制合成、组装体的构筑和结构调控和无机/合物杂化纳米材料。在论文的前半部分,基于环境敏感水溶性高分子设计合成了一系列三杂臂星型聚合物。在水溶液中,研究了多种环境响应性三杂臂星型聚合物聚合物的超分子组装以及不同环境条件对超分子组装体的影响。论文的后半部分,主要研究无机/合物杂化纳米材料的制备。具体来说,本论文的工作包括以下几个方面：
1.结合原子转移自由基聚合(ATRP)、开环聚合(ROP)和点击化学(Click Chemistry)技术制备了结构规整的两亲性温度敏感ABC三杂臂星型聚合物聚苯乙烯-聚(ε-己内酯)-了、聚(N-异丙基丙烯酰胺)(PS(-b-PNIPAM)-b-PCL)。这种聚合物可以在水溶液中形成以PS/PCL为核、以PNIPAM为壳的胶束,并且这种胶束具有温度敏感性。我们还利用ATRP、ROP和点击化学相结合采用一步法制备了ABC三杂臂星型聚合物,聚苯乙烯(或聚环氧乙烷)-聚(ε-己内酯)-聚(N,N-二甲基胺乙基甲基丙烯酸酯)(PS(-b-PCL)-b-PDMA和PEO(-b-PCL)-b-PDMA)。结合ATRP和点击化学合成了一种新型的具有‘"schizophrenic"聚集性质的ABC三杂臂星型聚环氧乙烷-聚(N,N-二乙基胺乙基甲基丙烯酸酯)-聚(N-异丙基丙烯酰胺)(PEG(-b-PDEA)-b-PNIPAM)。该三杂臂星型聚合物可在酸性和高温的水溶液中自组装形成以PNIPAM为核的胶束,也可在碱性和室温的条件下得到以PDEA为核的反转胶束。还结合ATRP、ROP和点击化学合成了全生物相容性的ABC三杂臂星型聚合物聚环氧乙烷-聚(L-赖氨酸)-聚(ε-己内酯)(PEO(-b-PLL)-b-PCL),这种聚合物在水溶液中自组装形成以PCL为核和以PEO/PLL为壳的胶束。
2.合成了包含有三甲氧基硅烷基的嵌段共聚物聚(N-异丙基丙烯酰胺)-b-聚(γ-甲基丙烯酰氧基-丙基三甲氧基硅烷)(PNIPAM-b-PMPS),该聚合物在水溶液中自发形成以PNIPAM为壳层的胶束,在三乙胺催化下硅氧烷水解交联形成氧化硅粒子,从而形成温敏性的二氧化硅/合物杂化纳米粒子。利用嵌段聚合物PDMA-b-PMPS的自组装和自催化凝胶化过程制备了pH和温度敏感的杂化纳米粒子。还合成了端基为多巴胺分子的温度敏感性聚合物PNIPAM,利用配体交换的形式非常简单的制备了温度敏感性的Fe3O4/聚合物杂化纳米粒子。利用ATRP和点击化学合成含有多巴胺衍生物的两亲性三杂臂聚合物聚环氧乙烷-聚(甲基丙烯酸多巴酰胺)-聚苯乙烯(PEO(-b-PDOPA)-b-PS),利用这种聚合物功能化氧化铁纳米粒子,得到了两亲性的氧化铁/合物杂化纳米粒子,发现该粒子在水溶液中能自组装成含有氧化铁纳米粒子的杂化囊泡,这是一种简单的制备杂化纳米囊泡的方式。
The supramolecular self-assembly of polymeric building blocks via noncovalent interactions has exhibited important roles in developing novel biomaterials, smart devices, information science, and nanotechnology, which renders this interdisciplinary research subject as one of the key scientific issues in the 21st century. This dissertation mainly focuses on the controlled synthesis, fabrication, and structural tuning of stimuli-responsive supramolecular polymeric assemblies, inorganic/polymer hybrid nanoparticles. A series of amphiphilic and double hydrophilic miktoarm star terpolymers were synthesized. In aqueous solution, chain architectural effects on thier self-assembling properties under varying solution conditions were investigated. Moreover, inorganic/polymer hybrid nanoparticles were investigated. This dissertation can be further categorized into seven main parts as described below:
1. Amphiphilic ABC miktoarm star terpolymer consisting of polystyrene, poly(ε-caprolactone), and poly(N-isopropylacrylamide) arms, PS(-b-PNIPAM)-b-PCL, was synthesized via a combination. of atom transfer radical polymerization (ATRP), ring-opening polymerization (ROP), and consecutive click reactions. In aqueous solution, the obtained amphiphilic miktoarm star terpolymer self-assembles into micelles possessing mixed PS/PCL cores and thermo-responsive coronas. We also report on the one-pot synthesis of well-defined ABC miktoarm star terpolymers consisting of poly(2-(dimethylamino)ethyl methacrylate), poly(ε-caprolactone), and polystyrene or poly(ethylene oxide) arms, PS(-b-PCL)-b-PDMA and PEO(-b-PCL)-b-PDMA, taking advantage of the compatibility and mutual tolerability of reaction conditions (catalysts and monomers) employed for ATRP, ROP, and click reactions. We report the first example of synthesis and "schizophrenic" micellization behavior of multi-responsive double hydrophilic ABC miktoarm star terpolymer. A well-defined miktoarm star terpolymer consisting of poly(ethylene glycol), poly(2-(diethylamino)ethyl methacrylate), and poly(N-isopropylacryl-amide) arms, PEG(-b-PDEA)-b-PNIPAM, was synthesized via the combination of ATRP and click reaction. This novel type of miktoarm star terpolymer molecularly dissolves in aqueous solution at acidic pH and room temperature, but supramolecularly self-assembles into PDEA-core micelles at alkaline pH and room temperature, and PNIPAM-core micelles at acidic pH and elevated temperatures. Most importantly, both types of micellar aggregates possess well-solvated hybrid coronas. A well-defined ABC miktoarm star terpolymer consisting of biocompatible poly(ethylene oxide), poly(e-benzyloxycarbonyl-L-lysine), and poly(e-caprolactone) arms, PEO(-b-PZLL)-b-PCL, was synthesized via the combination of consecutive click reactions and ROP. In aqueous solution, the obtained amphiphilic miktoarm star terpolymer self-assembles into micelles possessing PCL cores and mixed PEO/PLL coronas.
2. Poly(N-isopropylacrylamide)-b-poly(γ-methacryloxypropyltrimethoxysilane) (PNIPAM-b-PMPS) was prepared by successive reversible addition-fragmentation transfer (RAFT) polymerizations. Thermo-responsive polymer-encapsulated silica hybrid nanoparticles were fabricated via self-assembling of block copolymer in aqueous solution into micelles and subsequent sol-gel process inside the micellar core. And we also report the facile preparation of hybrid nanoparticles starting from a amphiphilic block copolymer, poly(2-(dimethylamino)ethylmethacrylate)-b-poly(γ-methacryloxypropyltrimethoxysilane)(PDMA-b-PMPS), block copoly-mer. Micellization of the obtained amphiphilic diblock polymer in aqueous solution leads to the formation of nanoparticles consisting of PMPS cores and PDMA shells. The PDMA block can spontaneously catalyze the sol-gel reactions of trimethoxysilyl groups within PMPS cores, leading to the formation of hybrid nanoparticles coated with PDMA brushes. PDMA brushes exhibit pH and thermo-responsiveness, the swelling/collapse of them can be finely tuned with solution pH and temperatures. The thermo-responsive dopamine-terminated PNIPAM was synthesized by ATRP, the thermo-responsive Fe3O4/polymer hybrid nanoparticles was obtained through the ligand exchange reaction with dopamine-terminated PNIPAM and Fe3O4 nanoparticles. An amphiphilic ABC miktoarm star terpolymer consisting of poly(ethylene oxide), poly(dopamine methacrylamide) and polystyrene, PEO(-b-PDOPA)-b-PS, was synthesized via a combination of ATRP and click reactions. The amphiphilic Fe3O4 polymer hybrid nanoparticles was obtained through the ligand exchange reaction with PEO(-b-PDOPA)-b-PS and Fe3O4 nanoparticles. In aqueous solution, the amphiphilic hybrid nanoparticles can self-assembles into hybrid vesicles.
1.结合原子转移自由基聚合(ATRP)、开环聚合(ROP)和点击化学(Click Chemistry)技术制备了结构规整的两亲性温度敏感ABC三杂臂星型聚合物聚苯乙烯-聚(ε-己内酯)-了、聚(N-异丙基丙烯酰胺)(PS(-b-PNIPAM)-b-PCL)。这种聚合物可以在水溶液中形成以PS/PCL为核、以PNIPAM为壳的胶束,并且这种胶束具有温度敏感性。我们还利用ATRP、ROP和点击化学相结合采用一步法制备了ABC三杂臂星型聚合物,聚苯乙烯(或聚环氧乙烷)-聚(ε-己内酯)-聚(N,N-二甲基胺乙基甲基丙烯酸酯)(PS(-b-PCL)-b-PDMA和PEO(-b-PCL)-b-PDMA)。结合ATRP和点击化学合成了一种新型的具有‘"schizophrenic"聚集性质的ABC三杂臂星型聚环氧乙烷-聚(N,N-二乙基胺乙基甲基丙烯酸酯)-聚(N-异丙基丙烯酰胺)(PEG(-b-PDEA)-b-PNIPAM)。该三杂臂星型聚合物可在酸性和高温的水溶液中自组装形成以PNIPAM为核的胶束,也可在碱性和室温的条件下得到以PDEA为核的反转胶束。还结合ATRP、ROP和点击化学合成了全生物相容性的ABC三杂臂星型聚合物聚环氧乙烷-聚(L-赖氨酸)-聚(ε-己内酯)(PEO(-b-PLL)-b-PCL),这种聚合物在水溶液中自组装形成以PCL为核和以PEO/PLL为壳的胶束。
2.合成了包含有三甲氧基硅烷基的嵌段共聚物聚(N-异丙基丙烯酰胺)-b-聚(γ-甲基丙烯酰氧基-丙基三甲氧基硅烷)(PNIPAM-b-PMPS),该聚合物在水溶液中自发形成以PNIPAM为壳层的胶束,在三乙胺催化下硅氧烷水解交联形成氧化硅粒子,从而形成温敏性的二氧化硅/合物杂化纳米粒子。利用嵌段聚合物PDMA-b-PMPS的自组装和自催化凝胶化过程制备了pH和温度敏感的杂化纳米粒子。还合成了端基为多巴胺分子的温度敏感性聚合物PNIPAM,利用配体交换的形式非常简单的制备了温度敏感性的Fe3O4/聚合物杂化纳米粒子。利用ATRP和点击化学合成含有多巴胺衍生物的两亲性三杂臂聚合物聚环氧乙烷-聚(甲基丙烯酸多巴酰胺)-聚苯乙烯(PEO(-b-PDOPA)-b-PS),利用这种聚合物功能化氧化铁纳米粒子,得到了两亲性的氧化铁/合物杂化纳米粒子,发现该粒子在水溶液中能自组装成含有氧化铁纳米粒子的杂化囊泡,这是一种简单的制备杂化纳米囊泡的方式。
The supramolecular self-assembly of polymeric building blocks via noncovalent interactions has exhibited important roles in developing novel biomaterials, smart devices, information science, and nanotechnology, which renders this interdisciplinary research subject as one of the key scientific issues in the 21st century. This dissertation mainly focuses on the controlled synthesis, fabrication, and structural tuning of stimuli-responsive supramolecular polymeric assemblies, inorganic/polymer hybrid nanoparticles. A series of amphiphilic and double hydrophilic miktoarm star terpolymers were synthesized. In aqueous solution, chain architectural effects on thier self-assembling properties under varying solution conditions were investigated. Moreover, inorganic/polymer hybrid nanoparticles were investigated. This dissertation can be further categorized into seven main parts as described below:
1. Amphiphilic ABC miktoarm star terpolymer consisting of polystyrene, poly(ε-caprolactone), and poly(N-isopropylacrylamide) arms, PS(-b-PNIPAM)-b-PCL, was synthesized via a combination. of atom transfer radical polymerization (ATRP), ring-opening polymerization (ROP), and consecutive click reactions. In aqueous solution, the obtained amphiphilic miktoarm star terpolymer self-assembles into micelles possessing mixed PS/PCL cores and thermo-responsive coronas. We also report on the one-pot synthesis of well-defined ABC miktoarm star terpolymers consisting of poly(2-(dimethylamino)ethyl methacrylate), poly(ε-caprolactone), and polystyrene or poly(ethylene oxide) arms, PS(-b-PCL)-b-PDMA and PEO(-b-PCL)-b-PDMA, taking advantage of the compatibility and mutual tolerability of reaction conditions (catalysts and monomers) employed for ATRP, ROP, and click reactions. We report the first example of synthesis and "schizophrenic" micellization behavior of multi-responsive double hydrophilic ABC miktoarm star terpolymer. A well-defined miktoarm star terpolymer consisting of poly(ethylene glycol), poly(2-(diethylamino)ethyl methacrylate), and poly(N-isopropylacryl-amide) arms, PEG(-b-PDEA)-b-PNIPAM, was synthesized via the combination of ATRP and click reaction. This novel type of miktoarm star terpolymer molecularly dissolves in aqueous solution at acidic pH and room temperature, but supramolecularly self-assembles into PDEA-core micelles at alkaline pH and room temperature, and PNIPAM-core micelles at acidic pH and elevated temperatures. Most importantly, both types of micellar aggregates possess well-solvated hybrid coronas. A well-defined ABC miktoarm star terpolymer consisting of biocompatible poly(ethylene oxide), poly(e-benzyloxycarbonyl-L-lysine), and poly(e-caprolactone) arms, PEO(-b-PZLL)-b-PCL, was synthesized via the combination of consecutive click reactions and ROP. In aqueous solution, the obtained amphiphilic miktoarm star terpolymer self-assembles into micelles possessing PCL cores and mixed PEO/PLL coronas.
2. Poly(N-isopropylacrylamide)-b-poly(γ-methacryloxypropyltrimethoxysilane) (PNIPAM-b-PMPS) was prepared by successive reversible addition-fragmentation transfer (RAFT) polymerizations. Thermo-responsive polymer-encapsulated silica hybrid nanoparticles were fabricated via self-assembling of block copolymer in aqueous solution into micelles and subsequent sol-gel process inside the micellar core. And we also report the facile preparation of hybrid nanoparticles starting from a amphiphilic block copolymer, poly(2-(dimethylamino)ethylmethacrylate)-b-poly(γ-methacryloxypropyltrimethoxysilane)(PDMA-b-PMPS), block copoly-mer. Micellization of the obtained amphiphilic diblock polymer in aqueous solution leads to the formation of nanoparticles consisting of PMPS cores and PDMA shells. The PDMA block can spontaneously catalyze the sol-gel reactions of trimethoxysilyl groups within PMPS cores, leading to the formation of hybrid nanoparticles coated with PDMA brushes. PDMA brushes exhibit pH and thermo-responsiveness, the swelling/collapse of them can be finely tuned with solution pH and temperatures. The thermo-responsive dopamine-terminated PNIPAM was synthesized by ATRP, the thermo-responsive Fe3O4/polymer hybrid nanoparticles was obtained through the ligand exchange reaction with dopamine-terminated PNIPAM and Fe3O4 nanoparticles. An amphiphilic ABC miktoarm star terpolymer consisting of poly(ethylene oxide), poly(dopamine methacrylamide) and polystyrene, PEO(-b-PDOPA)-b-PS, was synthesized via a combination of ATRP and click reactions. The amphiphilic Fe3O4 polymer hybrid nanoparticles was obtained through the ligand exchange reaction with PEO(-b-PDOPA)-b-PS and Fe3O4 nanoparticles. In aqueous solution, the amphiphilic hybrid nanoparticles can self-assembles into hybrid vesicles.
引文
(1)Hadjichristidis N., Pitsikalis M., Pispas S., et al.2001. Polymers with complex architecture by living anionic polymerization [J]. Chemical Reviews,101:3747-3792.
(2)Hadjichristidis N., latrou H., Pitsikalis M., et al.2006. Macromolecular architectures by living and controlled/living polymerizations [J]. Progress in Polymer Science,31:1068-1132.
(3)Hadjichristidis N., latrou H., Pitsikalis M., et al.2005. Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk [J]. Progress in Polymer Science,30:725-782.
(4)Hawker C. J., Bosman A. W. and Harth E.2001. New polymer synthesis by nitroxide mediated living radical polymerizations [J]. Chemical Reviews,101:3661-3688.
(5)Matyjaszewski K. and Xia J. H.2001. Atom transfer radical polymerization [J]. Chemical Reviews,101:2921-2990.
(6)Tsarevsky N. V. and Matyjaszewski K.2007. "Green" atom transfer radical polymerization: From process design to preparation of well-defined environmentally friendly polymeric materials [J]. Chemical Reviews,107:2270-2299.
(7)Kato M., Kamigaito M., Sawamoto M., et al.1995. Polymerization of Methyl-Methacrylate with the Carbon-Tetrachloride Dichlorotris(Triphenylphosphine)Ruthenium(Ii) Methylaluminum Bis(2,6-Di-Tert-Butylphenoxide) Initiating System-Possibility of Living Radical Polymerization [J]. Macromolecules,28:1721-1723.
(8)Wang J. S. and Matyjaszewski K.1995. Controlled Living Radical Polymerization-Halogen Atom-Transfer Radical Polymerization Promoted by a Cu(I)Cu(Ii) Redox Process [J]. Macromolecules,28:7901-7910.
(9)Wang J. S. and Matyjaszewski K.1995. Controlled Living Radical Polymerization Atom-Transfer Radical Polymerization in the Presence of Transition-Metal Complexes [J]. Journal of the American Chemical Society,117:5614-5615.
(10)Teodorescu M. and Matyjaszewski K.1999. Atom transfer radical polymerization of (meth)acrylamides [J]. Macromolecules,32:4826-4831.
(11)Rademacher J., Baum R., Pallack M., et al.2000. Atom transfer radical polymerization of N,N-dimethylacrylamide [J]. Macromolecules,33:284-288.
(12)Gao H. F. and Matyjaszewski K.2008. Synthesis of low-polydispersity miktoarm star copolymers via a simple "Arm-First" method:Macromonomers as arm precursors [J]. Macromolecules,41:4250-4257.
(13)Jiang S., Chen Q., Tripathy M., et al.2010. Janus Particle Synthesis and Assembly [J]. Advanced Materials,22:1060-1071.
(14)Liu H., Jiang X. Z., Fan J., et al.2007. Aldehyde surface-functionalized shell cross-linked micelles with pH-tunable core swellability and their bioconjugation with lysozyme [J]. Macromolecules,40:9074-9083.
(15)Xu J., Ge Z. S., Zhu Z. Y., et al.2006. Synthesis and micellization properties of double hydrophilic A(2)BA(2) and A(4)BA(4) non-linear block copolymers [J]. Macromolecules,39: 8178-8185.
(16)Matyjaszewski K., Miller P. J., Pyun J., et al.1999. Synthesis and characterization of star polymers with varying arm number, length, and composition from organic and hybrid inorganic/organic multifunctional initiators [J]. Macromolecules,32:6526-6535.
(17)Aniansson E., Wall S. N. and Almgren M.1976. Theory of Kinetics of Micellar Equilibria and Quantitative Interpretation of Chemical Relaxation Studies of Micellar Solutions of Ionic Surfactants [J]. Journal of Physical Chemistry,80:905-922.
(18)Gong F. H., Tang H. L., Liu C. L., et al.2006. Preparation of hyperbranched polymers through ATRP of in situ formed AB* monomer [J]. Journal of Applied Polymer Science,101: 850-856.
(19)Jho J. Y., Yoo S. H. and Yoon T. H.1999. Controlling the degree of branching in ATRP of hyperbranched polyacrylates. [J]. Abstracts of Papers of the American Chemical Society,218: U545-U545.
(20)Chiefari J., Chong Y. K., Ercole F., et al.1998. Living free-radical polymerization by reversible addition-fragmentation chain transfer:The RAFT process [J]. Macromolecules,31: 5559-5562.
(21)Moad G., Chiefari J., Chong Y. K., et al.2000. Living free radical polymerization with reversible addition-fragmentation chain transfer (the life of RAFT) [J]. Polymer International,49: 993-1001.
(22)Convertine A. J., Lokitz B. S., Vasileva Y, et al.2006. Direct synthesis of thermally responsive DMA/NIPAM diblock and DMA/NIPAM/DMA triblock copolymers via aqueous, room temperature RAFT polymerization [J]. Macromolecules,39:1724-1730.
(23)Chong Y. K., Le T. P. T., Moad G, et al.1999. A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization:The RAFT process [J]. Macromolecules,32:2071-2074.
(24)Lowe A. B., Wang R., Tiriveedhi V., et al.2007. RAFT synthesis and solution properties of pH-responsive styrenic-based AB diblock copolymers of 4-vinylbenzyltrimethylphosphonium chloride with N,N-dimethylbenzylvinylamine [J]. Macromolecular Chemistry and Physics,208: 2339-2347.
(25)Convertine A. J. and McCormick C. L.2005. Synthesis of temperature responsive block copolymers via aqueous room temperature RAFT polymerization [J]. Abstracts of Papers of the American Chemical Society,230:U4124-U4125.
(26)Donovan M. S., Sumerlin B. S., Lowe A. B., et al.2002. Controlled/"living" polymerization of sulfobetaine monomers directly in aqueous media via RAFT [J]. Macromolecules,35: 8663-8666.
(27)Zhang Y. F., Luo S. Z. and Liu S. Y.2005. Fabrication of hybrid nanoparticles with thermoresponsive coronas via a self-assembling approach [J]. Macromolecules,38:9813-9820.
(28)Yusa S., Shimada Y., Mitsukami Y., et al.2004. Heat-induced association and dissociation behavior of amphiphilic diblock copolymers synthesized via reversible addition-fragmentation chain transfer radical polymerization [J]. Macromolecules,37:7507-7513.
(29)Schilli C. M., Zhang M. F., Rizzardo E., et al.2004. A new double-responsive block copolymer synthesized via RAFT polymerization: Poly(N-isopropylacrylamide)-block-poly(acrylic acid) [J]. Macromolecules,37:7861-7866.
(30)Veregin R. P. N., Georges M. K.; Kazmaier P. M., et al.1993. Free-Radical Polymerizations for Narrow Polydispersity Resins-Electron-Spin-Resonance Studies of the Kinetics and Mechanism [J]. Macromolecules,26:5316-5320.
(31)Debuigne A., Chan-Seng D., Li L. C., et al.2007. Synthesis and evaluation of sterically hindered 1,1-diadamantyl nitroxide as a low-temperature mediator for the stable free radical polymerization process [J]. Macromolecules,40:6224-6232.
(32)Debuigne A., Radhakrishnan T. and Georges M. K.2006. Stable free radical polymerization of acrylates promoted by alpha-hydroxycarbonyl compounds [J]. Macromolecules,39:5359-5363.
(33)Flakus S., Mandel K., Bartsch M., et al.2005. A new acyclic alpha-hydrogen bearing nitroxide and its corresponding alkoxyamine for stable free radical polymerization [J]. Macromolecular Rapid Communications,26:1698-1703.
(34)Gopalan P. and Ober C. K.2001. Highly reactive 2,5-disubstituted styrene-based monomer polymerized via stable free radical polymerization:Effect of substitution and liquid crystallinity on polymerization [J]. Macromolecules,34:5120-5124.
(35)Zou Y. S., Lin J., Zhuang R. C., et al.2000. Synthesis of block copolymer from dissimilar vinyl monomer by stable free radical polymerization [J]. Macromolecules,33:4745-4749.
(36)Pasquale A. J. and Long T. E.1999. Real-time monitoring of the stable free radical polymerization of styrene via in-situ mid-infrared spectroscopy [J]. Macromolecules,32: 7954-7957.
(37)Moffat K. A., Hamer G. K. and Georges M. K.1999. Stable free radical polymerization process:Kinetic and mechanistic study of the thermal decomposition of MB-TMP monitored by NMR and ESR spectroscopy [J]. Macromolecules,32:1004-1012.
(38)Listigovers N. A., Georges M. K., Odell P. G, et al.1996. Narrow-polydispersity diblock and triblock copolymers of alkyl acrylates by a "living" stable free radical polymerization [J]. Macromolecules,29:8992-8993.
(39)Ropson N., Dubois P., Jerome R., et al.1995. Macromolecular Engineering of Polylactones and Polylactides.20. Effect of Monomer, Solvent, and Initiator on the Ring-Opening Polymerization as Initiated with Aluminum Alkoxides [J]. Macromolecules,28:7589-7598.
(40)Ropson N., Dubois P., Jerome R., et al.1994. Macromolecular Engineering of Polylactones and Polylactides.17. Cryometric and Viscosimetric Analysis of the Species Active in the Ring-Opening Polymerization of Lactones, Lactides, and Cyclic Anhydrides as Initiated by Aluminum Triisopropoxide [J]. Macromolecules,27:5950-5956.
(41)Ropson N., Dubois P., Jerome R., et al.1993. Macromolecular Engineering of Polylactones and Polylactides.14. A C-13 and Al-27 Nmr-Study of the Effect of Gamma-Butyrolactone on the Structure of Aluminum Isopropoxide in Toluene [J]. Macromolecules,26:6378-6385.
(42)Dubois P., Ropson N., Jerome R., et al.1996. Macromolecular engineering of polylactones and polylactides.19. Kinetics of ring-opening polymerization of epsilon-caprolactone initiated with functional aluminum alkoxides [J]. Macromolecules,29:1965-1975.
(43)Habraken G. J. M., Koning C. E. and Heise A.2009. Peptide Block Copolymers by N-Carboxyanhydride Ring-Opening Polymerization and Atom Transfer Radical Polymerization: The Effect of Amide Macroinitiators [J]. Journal of Polymer Science Part a-Polymer Chemistry, 47:6883-6893.
(44)Lu H., Wang J., Lin Y, et al.2009. One-Pot Synthesis of Brush-Like Polymers via Integrated Ring-Opening Metathesis Polymerization and Polymerization of Amino Acid N-Carboxyanhydrides [J]. Journal of the American Chemical Society,131:13582-+.
(45)Rao J. Y., Zhu Z. Y and Liu S. Y 2009. Synthesis and micellization behavior of stimuli-responsive polypeptide hybrid triblock copolymer [J]. Chinese Science Bulletin,54: 1912-1917.
(46)Rao J. Y, Zhang Y F., Zhang J. Y, et al.2008. Facile Preparation of Well-Defined AB(2) Y-Shaped Miktoarm Star Polypeptide Copolymer via the Combination of Ring-Opening Polymerization and Click Chemistry [J]. Biomacromolecules,9:2586-2593.
(47)Rao J. Y., Luo Z. E, Ge Z. S., et al.2007. "Schizophrenic" micellization associated with coil-to-helix transitions based on polypeptide hybrid double hydrophilic rod-coil diblock copolymer [J]. Biomacromolecules,8:3871-3878.
(48)Yu H. J., Chen X. S., Lu T. C., et al.2007. Poly(L-lysine)-graft-chitosan copolymers: Synthesis, characterization, and gene transfection effect [J]. Biomacromolecules,8:1425-1435.
(49)Wieringa R. H., Siesling E. A., Geurts P. F. M., et al.2001. Surface grafting of poly (L-glutamates).1. Synthesis and characterization [J]. Langmuir,17:6477-6484. (50) Yu M. E. and Deming T. J.1998. Synthetic polypeptide mimics of marine adhesives [J]. Macromolecules,31:4739-4745.
(51)Trnka T. M., Day M. W. and Grubbs R. H.2001. Olefin metathesis with 1,1-difluoroethylene [J]. Angewandte Chemie-International Edition,40:3441-+.
(52)Trnka T. M. and Grubbs R. H.2001. The development of L2X2Ru= CHR olefin metathesis catalysts:An organometallic success story [J]. Accounts of Chemical Research,34:18-29.
(53)Singh R., Czekelius C. and Schrock R. R.2006. Living ring-opening metathesis polymerization of cyclopropenes [J]. Macromolecules,39:1316-1317.
(54)Buchmeiser M. and Schrock R. R.1995. Synthesis of Polyenes That Contain Metallocenes Via the Living Polymerization of Ethynylferrocene and Ethynylruthenocene [J]. Macromolecules, 28:6642-6649.
(55)Schrock R. R., Lee J. K., Odell R., et al.1995. Exploring Factors That Determine Cis/Trans Structure and Tacticity in Polymers Prepared by Ring-Opening Metathesis Polymerization with Initiators of the Type Syn-Mo(Nar)(Chcme(2)Ph)(or)(2) and Anti-Mo(Nar)(Chcme(2)Ph)(or)(2)-Observation of a Temperature-Dependent Cis/Trans Ratio [J]. Macromolecules,28:5933-5940.
(56)Howard T. R., Lee J. B. and Grubbs R. H.1980. Titanium metallacarbene-metallacyclobutane reactions:stepwise metathesis [J]. Journal of the American Chemical Society 102:6876-6878
(57)Yokoyama A. and Yokozawa T.2007. Converting step-growth to chain-growth condensation polymerization [J]. Macromolecules,40:4093-4101.
(58)Yokozawa T. and Yokoyama A.2009. Chain-Growth Condensation Polymerization for the Synthesis of Well-Defined Condensation Polymers and pi-Conjugated Polymers [J]. Chemical Reviews,109:5595-5619.
(59)Masukawa T., Yokoyama A. and Yokozawa T.2009. Synthesis of Well-Defined Polybenzamide-block-Polystyrene by Combination of Chain-Growth Condensation Polymerization and RAFT Polymerization [J]. Macromolecular Rapid Communications,30: 1413-1418.
(60)Ohta Y, Fujii S., Yokoyama A., et al.2009. Synthesis of Well-Defined Hyperbranched Polyamides by Condensation Polymerization of AB(2) Monomer through Changed Substituent Effects [J]. Angewandte Chemie-International Edition,48:5942-5945.
(61)Yokoyama A., Masukawa T., Yamazaki Y., et al.2009. Successive Chain-Growth Condensation Polymerization for the Synthesis of Well-Defined Diblock Copolymers of Aromatic Polyamide and Aromatic Polyether [J]. Macromolecular Rapid Communications,30:24-28.
(62)Ohishi T., Sugi R., Yokoyama A., et al.2008. Synthesis via Chain-Growth Condensation Polymerization and Gelating Properties of a Variety of Block Copolymers-of Meta-and Para-Substituted Aromatic Polyamides [J]. Macromolecules,41:9683-9691.
(63)Ajioka N., Yokoyama A. and Yokozawa T.2008. Synthesis of well-defined rod-coil diblock copolymer of aromatic polyether and polyacrylonitrile by chain-growth condensation polymerization and atom transfer radical polymerization [J]. Macromolecular Rapid Communications,29:665-671.
(64)Yokozawa T., Adachi I., Miyakoshi R., et al.2007. Catalyst-transfer condensation polymerization for the synthesis of well-defined polythiophene with hydrophilic side chain and of diblock copolythiophene with hydrophilic and hydrophobic side chains [J]. High Performance Polymers,19:684-699.
(65)Ajioka N., Suzuki Y., Yokoyama A., et al.2007. Synthesis of well-defined polystyrene-b-aromatic polyether using an orthogonal initiator for atom transfer radical polymerization and chain-growth condensation polymerization [J]. Macromolecules,40: 5294-5300.
(66)Finn M. G, Kolb H. C., Fokin V. V., et al.2008. Click chemistry-Definition and aims [J]. Progress in Chemistry,20:1-4.
(67)Kolb H. C., Finn M. G. and Sharpless K. B.2001. Click chemistry:Diverse chemical function from a few good reactions [J]. Angewandte Chemie-International Edition,40:2004-+.
(68)Ossipov D. A. and Hilborn J.2006. Poly(vinyl alcohol)-based hydrogels formed by "click chemistry" [J]. Macromolecules,39:1709-1718.
(69)Xu J. and Liu S. Y.2009. Synthesis of Well-Defined 7-Arm and 21-Arm Poly (N-isopropylacrylamide) Star Polymers with beta-Cyclodextrin Cores via Click Chemistry and Their Thermal Phase Transition Behavior in Aqueous Solution [J]. Journal of Polymer Science Part a-Polymer Chemistry,47:404-419.
(70)Gao H. F. and Matyjaszewski K.2006. Synthesis of star polymers by a combination of ATRP and the "click" coupling method [J]. Macromolecules,39:4960-4965.
(71)Shi G. Y, Tang X. Z. and Pan C. Y.2008. Tadpole-shaped amphiphilic copolymers prepared via RAFT polymerization and click reaction [J]. Journal of Polymer Science Part a-Polymer Chemistry,46:2390-2401.
(72)Piirma I., polymeric Surfactants:Sufanctant Science 42.1992, New York:Marcel Dekker.
(73)Alexandridis P. and lindman B., Amphiphilic Block Copolymers:Self-assembly and Application.2000, Amsterdam:Elsevier.
(74)何天白 and 胡汉杰,海外高分子科学的新进展.1997,北京：化学工业出版社.
(75)Gan Z. H., Jim T. F., Li M., et al.1999. Enzymatic biodegradation of poly(ethylene oxide-b-epsilon-caprolactone) diblock copolymer and its potential biomedical applications [J]. Macromolecules,32:590-594.
(76)Kataoka K., Harada A. and Nagasaki Y.2001. Block copolymer micelles for drug delivery: design, characterization and biological significance [J]. Advanced Drug Delivery Reviews,47: 113-131.
(77)Antonietti M., Forster S., Hartmann J., et al.1996. Novel amphiphilic block copolymers by polymer reactions and their use for solubilization of metal salts and metal colloids [J]. Macromolecules,29:3800-3806.
(78)Moffitt M. and Eisenberg A.1997. Scaling relations and size control of block ionomer microreactors containing different metal ions [J]. Macromolecules,30:4363-4373.
(79)Halperin A., Tirrell M. and Lodge T. P.1992. Tethered Chains in Polymer Microstructures [J]. Advances in Polymer Science,100:31-71.
(80)Zhang L. F., Yu K. and Eisenberg A.1996. Ion-induced morphological changes in "crew-cut" aggregates of amphiphilic block copolymers [J]. Science,272:1777-1779.
(81)Zhang L. F. and Eisenberg A.1995. Multiple Morphologies of Crew-Cut Aggregates of Polystyrene-B-Poly(Acrylic Acid) Block-Copolymers [J]. Science,268:1728-1731.
(82)Zhang L. F. and Eisenberg A.1999. Crew-cut aggregates from self-assembly of blends of polystyrene-b-poly(acrylic acid) block copolymers and homopolystyrene in solution [J]. Journal of Polymer Science Part B-Polymer Physics,37:1469-1484.
(83)Zhang L. F. and Eisenberg A.1998. Formation of crew-cut aggregates of various morphologies from amphiphilic block copolymers in solution [J]. Polymers for Advanced Technologies,9:677-699.
(84)Zhang L. F. and Eisenberg A.1996. Morphogenic effect of added ions on crew-cut aggregates of polystyrene-b-poly(acrylic acid) block copolymers in solutions [J]. Macromolecules,29: 8805-8815.
(85)Thurmond K. B., Kowalewski T. and Wooley K. L.1996. Water-soluble knedel-like structures: The preparation of shell-cross-linked small particles [J]. Journal of the American Chemical Society,118:7239-7240.
(86)Colfen H.2001. Double-hydrophilic block copolymers:Synthesis and application as novel surfactants and crystal growth modifiers [J]. Macromolecular Rapid Communications,22: 219-252.
(87)Gil E. S. and Hudson S. A.2004. Stimuli-reponsive polymers and their bioconjugates [J]. Progress in Polymer Science,29:1173-1222.
(88)Wang D., Wu T., Wan X. J., et al.2007. Purely salt-responsive micelle formation and inversion based on a novel schizophrenic sulfobetaine block copolymer:Structure and kinetics of micellization [J]. Langmuir,23:11866-11874.
(89)Butun V., Billingham N. C. and Armes S. P.1998. Unusual aggregation behavior of a novel tertiary amine methacrylate-based diblock copolymer:Formation of micelles and reverse micelles in aqueous solution [J]. Journal of the American Chemical Society,120:11818-11819.
(90)Wu C. and Zhou S. Q.1995. Thermodynamically Stable Globule State of a Single Poly(N-Isopropylacrylamide) Chain in Water [J]. Macromolecules,28:5388-5390.
(91)徐建，基于聚(N-异丙基烯酰胺)的多种拓扑缝构水溶性高分子制备及其溶液性爱研
究.2008,中国科学技术大学：合肥.
(92)Schild H. G.1992. Poly (N-Isopropylacrylamide)-Experiment, Theory and Application [J]. Progress in Polymer Science,17:163-249.
(93)Lutz J. F.2008. Polymerization of oligo(ethylene glycol) (meth)acrylates:Toward new generations of smart biocompatible materials [J]. Journal of Polymer Science Part a-Polymer Chemistry,46:3459-3470.
(94)Lutz J. E, Weichenhan K., Akdemir O., et al.2007. About the phase transitions in aqueous solutions of thermoresponsive copolymers and hydrogels based on 2-(2-methoxyethoxy)ethyl methacrylate and oligo(ethylene glycol) methacrylate [J]. Macromolecules,40:2503-2508.
(95)Lutz J. F., Akdemir O. and Hoth A.2006. Point by point comparison of two thermosensitive polymers exhibiting a similar LCST:Is the age of poly(NIPAM) over? [J]. Journal of the American Chemical Society,128:13046-13047.
(96)Arotcarena M., Heise B., Ishaya S., et al.2002. Switching the inside and the outside of aggregates of water-soluble block copolymers with double thermoresponsivity [J]. Journal of the American Chemical Society,124:3787-3793.
(97)Martin T. J., Prochazka K., Munk P., et al.1996. pH-dependent micellization of poly(2-vinylpyridine)-block-poly(ethylene oxide) [J]. Macromolecules,29:6071-6073.
(98)Liu S. Y. and Armes S. P.2003. Synthesis and aqueous solution behavior of a pH-responsive schizophrenic diblock copolymer [J]. Langmuir,19:4432-4438.
(99)Butun V., Armes S. P., Billingham N. C., et al.2001. The remarkable "flip-flop" self-assembly of a diblock copolymer in aqueous solution [J]. Macromolecules,34:1503-1511.
(100)Liu S. Y., Billingham N. C. and Armes S. P.2001. A schizophrenic water-soluble diblock copolymer [J]. Angewandte Chemie-International Edition,40:2328-+.
(101)Liu S. Y. and Armes S. P.2002. Polymeric surfactants for the new millennium:A pH-responsive, zwitterionic, schizophrenic diblock copolymer [J]. Angewandte Chemie-International Edition,41:1413-1416.
(102)Butun V., Vamvakaki M., Billingham N. C., et al.2000. Synthesis and aqueous solution properties of novel neutral/acidic block copolymers [J]. Polymer,41:3173-3182.
(103)Cai Y. L. and Armes S. P.2004. A Zwitterionic ABC triblock copolymer that forms a "Trinity" of micellar aggregates in aqueous solution [J]. Macromolecules,37:7116-7122.
(104)Gohy J. E, Creutz S., Garcia M., et al.2000. Aggregates formed by amphoteric diblock copolymers in water [J]. Macromolecules,33:6378-6387.
(105)Dai S., Ravi P., Tam K. C., et al.2003. Novel pH-responsive amphiphilic diblock copolymers with reversible micellization properties [J]. Langmuir,19:5175-5177.
(106)Virtanen J., Arotcarena M., Heise B., et al.2002. Dissolution and aggregation of a poly(NIPA-block-sulfobetaine) copolymer in water and saline aqueous solutions [J]. Langmuir,18: 5360-5365.
(107)Hu F. Q., Wei L., Zhou Z., et al.2006. Preparation of biocompatible magnetite nanocrystals for in vivo magnetic resonance detection of cancer [J]. Advanced Materials,18:2553-+.
(108)Haynes C. L. and Van Duyne R. P.2001. Nanosphere lithography:A versatile nanofabrication tool for studies of size-dependent nanoparticle optics [J]. Journal of Physical Chemistry B,105:5599-5611.
(109)Walter E. C., Penner R. M., Liu H., et al.2002. Sensors from electrodeposited metal nanowires [J]. Surface and Interface Analysis,34:409-412.
(110)Zhu M. Q., Wang L. Q., Exarhos G. J., et al.2004. Thermosensitive gold nanoparticles [J]. Journal of the American Chemical Society,126:2656-2657.
(111)Xie J., Xu C., Kohler N., et al.2007. Controlled PEGylation of monodisperse Fe3O4 nanoparticles for reduced non-specific uptake by macrophage cells [J]. Advanced Materials,19: 3163-+.
(1)Alexandridis P.1996. Amphiphilic copolymers and their applications [J]. Current Opinion in Colloid & Interface Science,1:490-501.
(2)Zhang L. F. and Eisenberg A.1995. Multiple Morphologies of Crew-Cut Aggregates of Polystyrene-B-Poly(Acrylic Acid) Block-Copolymers [J]. Science,268:1728-1731.
(3)Balogh L., Samuelson L., Alva K. S., et al.1998. Synthesis, homopolymerization, and block copolymerization of N-ethyl-2-ethynyl-pyridinium trifluoromethanesulfonate with styrene and butadiene [J]. Journal of Polymer Science Part a-Polymer Chemistry,36:703-712.
(4)Hong H. Y., Mai Y. Y., Zhou Y. F., et al.2008. Synthesis and supramolecular self-assembly of thermosensitive amphiphilic star copolymers based on a hyperbranched polyether core [J]. Journal of Polymer Science Part a-Polymer Chemistry,46:668-681.
(5)Ge Z. S., Chen D. Y., Zhang J. Y., et al.2007. Facile synthesis of dumbbell-shaped dendritic-linear-dendritic triblock copolymer via reversible addition-fragmentation chain transfer polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:1432-1445.
(6)Ge Z. S., Luo S. Z. and Liu S. Y.2006. Syntheses and self-assembly of poly(benzyl ether)-b-poly(N-isopropylacrylamide) dendritic-linear diblock copolymers [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:1357-1371.
(7)Babin J., Taton D., Brinkmann M., et al.2008. Synthesis and self-assembly in bulk of linear and Mikto-arm star block copolymers based on polystyrene and poly(glutamic acid) [J]. Macromolecules,41:1384-1392.
(8)Havrankova J., Limpouchova Z., Stepanek M., et al.2007. Self-assembly of heteroarm star copolymers-A Monte Carlo study [J]. Macromolecular Theory and Simulations,16:386-398.
(9)Hadjichristidis N., Iatrou H., Pitsikalis M., et al.2005. Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk [J]. Progress in Polymer Science,30:725-782.
(10)Li Z. B., Kesselman E., Talmon Y., et al.2004. Multicompartment micelles from ABC miktoarm stars in water [J]. Science,306:98-101.
(11)Li Z. B., Hillmyer M. A. and Lodge T. P.2006. Morphologies of multicompartment micelles formed by ABC miktoarm star terpolymers [J]. Langmuir,22:9409-9417.
(12)Li Z. B., Hillmyer M. A. and Lodge T. P.2006. Laterally nanostructured vesicles, polygonal bilayer sheets, and segmented wormlike micelles [J]. Nano Letters,6:1245-1249.
(13)Erdogan T., Gungor E., Durmaz H., et al.2006. Photoresponsive poly(methyl methacrylate)(2)-(polystyrene)(2) miktoarm star copolymer containing an azobenzene moiety at the core [J]. Journal of Polymer Science Part A-Polymer Chemistry,44:1396-1403.
(14)Saito N., Liu C., Lodge T. P., et al.2008. Multicompartment Micelles from Polyester-Containing ABC Miktoarm Star Terpolymers [J]. Macromolecules,41:8815-8822.
(15)Sioula S., Hadjichristidis N. and Thomas E. L.1998. Direct evidence for confinement of junctions to lines in an 3 miktoarm star terpolymer microdomain structure [J]. Macromolecules, 31:8429-8432.
(16)Van Butsele K., Stoffelbach F., Jerome R., et al.2006. Synthesis of novel amphiphilic and pH-sensitive ABC miktoarm star terpolymers [J]. Macromolecules,39:5652-5656.
(17)Yamauchi K., Takahashi K., Hasegawa H., et al.2003. Microdomain morphology in an ABC 3-miktoarm star terpolymer:A study by energy-filtering TEM and 3D electron tomography [J]. Macromolecules,36:6962-6966.
(18)Tunca U., Ozyurek Z., Erdogan T., et al.2004. Novel miktofunctional initiator for the preparation of an ABC-type miktoarm star polymer via a combination of controlled polymerization techniques [J]. Journal of Polymer Science Part A-Polymer Chemistry,42: 4228-4236.
(19)Lu T., He X. H. and Liang H. J.2004. Ordered microstructures by assembly of ABC 3-miktoarm star terpolymers and linear homopolymers [J]. Journal of Chemical Physics,121: 9702-9707.
(20)Hadjichristidis N. and Pispas S.2006. Designed block copolymers for ordered polymeric nanostructures [J]. Advances in Polymer Science,200:37-55.
(21)Huang R., Jiang Y. and Liang H. J.2006. Effect of architecture on the tensile properties of triblock copolymers in a lamellar phase [J]. Chemphyschem,7:1950-1956.
(22)Birshtein T. M., Polotsky A. A. and Abetz V.2004. Theory of the lamellar superstructure of an ABC 3-miktoarm star-terpolymer [J]. Macromolecular Theory and Simulations,13:512-519.
(23)Kou D. Z., Jiang Y. and Liang H. J.2006. Microstructures from a mixture of ABC 3-miktoarm star terpolymers and homopolymers in two-dimensional space [J]. Journal of Physical Chemistry B,110:23557-23563.
(24)Zhu Y. T., Li R. K. Y. and Jiang W.2006. A Monte Carlo simulation for the micellization of ABC 3-miktoarm star terpolymers in a selective solvent [J]. Chemical Physics,327:137-143.
(25)Zhulina E. B. and Borisov O. V.2008. Scaling theory of 3-miktoarm ABC copolymer micelles in selective solvent [J]. Macromolecules,41:5934-5944.
(26)M. Ciampolini a. N. N.1966. Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine [J]. Inorganic Chemistry,5:41-44.
(27)Mantovani G., Ladmiral V., Tao L., et al.2005. One-pot tandem living radical polymerisation-Huisgens cycloaddition process ("click") catalysed by N-alkyl-2-pyridylmethanimine/Cu(I)Br complexes [J]. Chemical Communications,2089-2091.
(28)Wu P., Feldman A. K., Nugent A. K., et al.2004. Efficiency and fidelity in a click-chemistry route to triazole dendrimers by the copper(Ⅰ)-catalyzed ligation of azides and alkynes [J]. Angewandte Chemie-International Edition,43:3928-3932.
(29)Pitsikalis M., Pispas S., Mays J. W., et al.1998. Nonlinear block copolymer architectures [J]. Advances in Polymer Science,135:1-137.
(30)Durmaz H., Karatas F., Tunca U., et al.2006. Preparation of ABC miktoarm star terpolymer containing poly(ethylene glycol), polystyrene, and poly(tert-butylacrylate) arms by combining Diels-Alder reaction, atom transfer radical, and stable free radical polymerization routes [J]. Journal of Polymer Science Part A-Polymer Chemistry,44:499-509.
(31)He T., Li D. J., Sheng X., et al.2004. Synthesis of ABC 3-miktoarm star terpolymers from a trifunctional initiator by combining ring-opening polymerization, atom transfer radical polymerization, and nitroxide-mediated radical polymerization [J]. Macromolecules,37: 3128-3135.
(32)Wang G. W. and Huang J. L.2007. Preparation of star-shaped ABC copolymers of polystyrene-poly(ethylene oxide)-polyglycidol using ethoxyethyl glycidyl ether as the cap molecule [J]. Macromolecular Rapid Communications,28:298-304.
(33)Wang G. W. and Huang J. L.2008. Synthesis and characterization of well-defined ABC 3-Miktoarm star-shaped terpolymers based on poly(styrene), poly(ethylene oxide), and poly(epsilon-caprolactone) by combination of the "Living" anionic polymerization with the ring-opening polymerization [J]. Journal of Polymer Science Part A-Polymer Chemistry,46: 1136-1150.
(34)Feng X. S. and Pan C. Y.2002. Synthesis of amphiphilic miktoarm ABC star copolymers by RAFT mechanism using maleic anhydride as linking agent [J]. Macromolecules,35:4888-4893.
(35)Feng X. S. and Pan C. Y.2002. Block and star block copolymers by mechanism transformation.7. Synthesis of polytetrahydrofuran/poly(1,3-dioxepane)/polystyrene ABC miktoarm star copolymers by combination of CROP and ATRP [J]. Macromolecules,35: 2084-2089.
(36)He X. H., Huang L., Liang H. J., et al.2003. Localizations of junction points of ABC 3-miktoarm star terpolymers [J]. Journal of Chemical Physics,118:9861-9863.
(37)Shi P. H., Li Y. G. and Pan C. Y.2004. Block and star block copolymers by mechanism transformation-X. Synthesis of poly(ethylene oxide) methyl ether/polystyrene/poly(L-lactide) ABC miktoarm star copolymers of by combination of RAFT and ROP [J]. European Polymer Journal,40:1283-1290.
(38)Li Y. G., Wang Y. M. and Pan C. Y.2003. Block and star block copolymers by mechanism transformation 9:Preparation and characterization of poly(methyl methacrylate)/poly(1,3-dioxepane)/polystyrene ABC miktoarm star copolymers by combination of reversible addition-fragmentation chain-transfer polymerization and cationic ring-opening polymerization [J]. Journal of Polymer Science Part A-Polymer Chemistry,41:1243-1250.
(39)Altintas 0., Hizal G. and Tunca U.2006. ABC-type hetero-arm star terpolymers through "click" chemistry [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:5699-5707.
(40)Yang L. P., Zhou H. X., Shi G. Y., et al.2008. Synthesis of ABCD 4-miktoarm star polymers by combination of RAFT, ROP, and "Click chemistry'" [J]. Journal of Polymer Science Part A-Polymer Chemistry,46:6641-6653.
(41)Deng G. H., Ma D. Y. and Xu Z. Z.2007. Synthesis of ABC-type miktoarm star polymers by "click" chemistry, ATRP and ROP [J]. European Polymer Journal,43:1179-1187.
(42)Yuan Y. Y., Wang Y. C., Du J. Z., et al.2008. Synthesis of Amphiphilic ABC 3-Miktoarm Star Terpolymer by Combination of Ring-Opening Polymerization and "Click" Chemistry [J]. Macromolecules,41:8620-8625.
(43)Altintas O., Yankul B., Hizal G., et al.2007. One-pot preparation of 3-miktoarm star terpolyrmers via click [3+2] reaction [J]. Journal of Polymer Science Part A-Polymer Chemistry, 45:3588-3598.
(44)Braunecker W. A. and Matyjaszewski K.2007. Controlled/living radical polymerization: Features, developments, and perspectives [J]. Progress in Polymer Science,32:93-146.
(45)Matyjaszewski K.2003. Controlled/living radical polymerization:State of the art in 2002 [J]. ACS Symposium Series,854:2-9.
(46)Qiu J., Charleux B. and Matyjaszewski K.2001. Progress in controlled/living polymerization (CLP) in aqueous media-Part Ⅲ. Controlled/living polymerization in aqueous media [J]. Polimery,46:663-672.
(47)Mecerreyes D., Moineau G., Dubois P., et al.1998. Simultaneous dual living polymerizations: A novel one-step approach to block and graft copolymers [J]. Angewandte Chemie-International Edition,37:1274-1276.
(48)Duxbury C. J., Wang W. X., de Geus M., et al.2005. Can block copolymers be synthesized by a single-step chemoenzymatic route in supercritical carbon dioxide? [J]. Journal of the American Chemical Society,127:2384-2385.
(49)Wang W. X., Howdle S. M. and Yan D. Y.2005. One-step seed dispersion polymerisation in supercritical carbon dioxide [J]. Chemical Communications,3939-3941.
(50)Zhou J. X., Villarroya S., Wang W. X., et al.2006. One-step chemoenzymatic synthesis of poly(epsilon-caprolactone-block-methyl methacrylate) in supercritical C02 [J]. Macromolecules, 39:5352-5358.
(51)Golas P. L. and Matyjaszewski K.2007. Click chemistry and ATRP:A beneficial union for the preparation of functional materials [J]. Qsar & Combinatorial Science,26:1116-1134.
(52)Lutz J. F., Borner H. G. and Weichenhan K.2006. Combining ATRP and "click" chemistry:a promising platform toward functional biocompatible polymers and polymer bioconjugates [J]. Macromolecules,39:6376-6383.
(53)Mespouille L., Vachaudez M., Suriano F., et al.2007. One-pot synthesis of well-defined amphiphilic and adaptative block copolymers via versatile combination of "Click" chemistry and ATRP [J]. Macromolecular Rapid Communications,28:2151-2158.
(54)Geng J., Lindqvist J., Mantovani G., et al.2008. Simultaneous copper(Ⅰ)-catalyzed azide-alkyne cycloaddition (CuAAC) and living radical polymerization [J]. Angewandte Chemie-International Edition,47:4180-4183.
(55)Perrier S., Jackson S. G., Haddleton D. M., et al.2002. Preparation of fluorinated methacrylic copolymers by copper mediated living radical polymerization [J]. Tetrahedron,58:4053-4059.
(56)Butun V., Liu S., Weaver J. V. M., et al.2006. A brief review of'schizophrenic'block copolymers [J]. Reactive & Functional Polymers,66:157-165.
(57)Xu Y. L., Shi L. Q., Ma R. J., et al.2007. Synthesis and micellization of thermo-and pH-responsive block copolymer of poly (N-isopropylacrylamide)-block-poly(4-vinylpyridine) [J]. Polymer,48:1711-1717.
(58)Agut W., Brulet A., Taton D., et al.2007. Thermoresponsive micelles from jeffamine-b-poly(L-glutamic acid) double hydrophilic block copolymers [J]. Langmuir,23: 11526-11533.
(59)Rao J. Y., Luo Z. F., Ge Z. S., et al.2007. "Schizophrenic" micellization associated with coil-to-helix transitions based on polypeptide hybrid double hydrophilic rod-coil diblock copolymer [J]. Biomacromolecules,8:3871-3878.
(60)Cai C. H., Zhang L. S., Lin J. P., et al.2008. Self-assembly behavior of pH-and thermosensitive amphiphilic triblock copolymers in solution:Experimental studies and self-consistent field theory simulations [J]. Journal of Physical Chemistry B,112:12666-12673.
(61)Li J. G., Wang T., Wu D. L., et al.2008. Stimuli-Responsive Zwitterionic Block Copolypeptides:Poly(N-isopropylacrylamide)-block-poly(lysine-co-glutamic acid) [J]. Biomacromolecules,9:2670-2676.
(62)Zhang X. Q., Li J. G., Li W., et al.2007. Synthesis and characterization of thermo-and pH-responsive double-hydrophilic diblock copolypeptides [J]. Biomacromolecules,8:3557-3567.
(63)Schilli C. M., Zhang M. F., Rizzardo E., et al.2004. A new double-responsive block copolymer synthesized via RAFT polymerization: Poly(N-isopropylacrylamide)-block-poly(acrylic acid) [J]. Macromolecules,37:7861-7866.
(64)Zhang Y. F., Wu T. and Liu S. Y.2007. Micellization kinetics of a novel multi-responsive double hydrophilic diblock copolymer studied by stopped-flow pH and temperature jump [J]. Macromolecular Chemistry and Physics,208:2492-2501.
(65)Andre X., Zhang M. F. and Muller A. H. E.2005. Thermo-and pH-responsive micelles of poly(acrylic acid)-block-poly(N,N-diethylacrylamide) [J]. Macromolecular Rapid Communications,26:558-563.
(66)Zeng J. G., Shi K. Y., Zhang Y. Y., et al.2008. Construction and micellization of a noncovalent double hydrophilic block copolymer [J]. Chemical Communications,3753-3755.
(67)Arotcarena M., Heise B., Ishaya S., et al.2002. Switching the inside and the outside of aggregates of water-soluble block copolymers with double thermoresponsivity [J]. Journal of the American Chemical Society,124:3787-3793.
(68)Cai Y. L., Burguiere C. and Armes S. P.2004. Direct synthesis and aqueous solution properties of Y-shaped, stimulus-responsive block copolymer surfactants [J]. Chemical Communications,802-803.
(69)Xu J., Ge Z. S., Zhu Z. Y., et al.2006. Synthesis and micellization properties of double hydrophilic A(2)BA(2) and A(4)BA(4) non-linear block copolymers [J]. Macromolecules,39: 8178-8185.
(70)Rao J. Y., Zhang Y. F., Zhang J. Y., et al.2008. Facile Preparation of Well-Defined AB(2) Y-Shaped Miktoarm Star Polypeptide Copolymer via the Combination of Ring-Opening Polymerization and Click Chemistry [J]. Biomacromolecules,9:2586-2593.
(71)Ge Z. S., Cai Y. L., Yin J., et al.2007. Synthesis and'Schizophrenic'micellization of double hydrophilic AB(4) miktoarm star and AB diblock copolymers:Structure and kinetics of micellization [J]. Langmuir,23:1114-1122.
(72)Wang X. F., Zhang Y. F., Zhu Z. Y., et al.2008. Fabrication of fullerene-containing hybrid vesicles via supramolecular self-assembly of a well-defined amphiphilic block copolymer incorporated with a Single C-60 moiety at the diblock junction point [J]. Macromolecular Rapid Communications,29:340-346.
(73)Schlaad H.2006. Solution properties of polypeptide-based copolymers [J]. Advances in Polymer Science,202:53-73.
(74)Dimitrov I., Kukula H., Colfen H., et al.2004. Advances in the synthesis and characterization of polypeptide-based hybrid block copolymers [J]. Macromolecular Symposia,215:383-393.
(75)Lowik D. W. P. M., Ayres L., Smeenk J. M., et al.2006. Synthesis of bio-inspired hybrid polymers using peptide synthesis and protein engineering [J]. Advances in Polymer Science,202: 19-52.
(76)Deming T. J.2006. Polypeptide and polypeptide hybrid copolymer synthesis via NCA polymerization [J]. Advances in Polymer Science,202:1-18.
(77)Deming T. J.2007. Synthetic polypeptides for biomedical applications [J]. Progress in Polymer Science,32:858-875.
(78)Gauthier M. A. and Klok H. A.2008. Peptide/protein-polymer conjugates:synthetic strategies and design concepts [J]. Chemical Communications,2591-2611.
(79)Abraham S., Ha C. S. and Kim I.2006. Self-assembly of star-shaped polystyrene-block-polypeptide copolymers synthesized by the combination of atom transfer radical polymerization and ring-opening living polymerization of alpha-amino acid-N-carboxyanhydrides [J]. Journal of Polymer Science Part A-Polymer Chemistry,44: 2774-2783.
(1)Hu F. Q., Wei L., Zhou Z., et al.2006. Preparation of biocompatible magnetite nanocrystals for in vivo magnetic resonance detection of cancer [J]. Advanced Materials,18:2553-+.
(2)Haynes C. L. and Van Duyne R. P.2001. Nanosphere lithography:A versatile nanofabrication tool for studies of size-dependent nanoparticle optics [J]. Journal of Physical Chemistry B,105: 5599-5611.
(3)Walter E. C., Penner R. M., Liu H., et al.2002. Sensors from electrodeposited metal nanowires [J]. Surface and Interface Analysis,34:409-412.
(4)Chen X. Y. and Armes S. P.2003. Surface polymerization of hydrophilic methacrylates from ultrafine silica sols in protic media at ambient temperature:A novel approach to surface functionalization using a polyelectrolytic macroinitiator [J]. Advanced Materials,15:1558-1562.
(5)Chen X. Y, Armes S. P., Greaves S. I, et al.2004. Synthesis of hydrophilic polymer-grafted ultrafine inorganic oxide particles in protic media at ambient temperature via atom transfer radical polymerization:use of an electrostatically adsorbed polyelectrolytic macroinitiator [J]. Langmuir, 20:587-595.
(6)Wu K. H., Shin M., Yang C. C., et al.2006. Preparation and ferromagnetic properties of Ni0.5Fe2O4/polyaniline core-shell nanocomposites [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:2657-2664.
(7)Golden J. H., Deng H. B., Disalvo F. J., et al.1995. Monodisperse Metal-Clusters 10-Angstroms in Diameter in a Polymeric Host-the Monomer-as-Solvent Approach [J]. Science, 268:1463-1466.
(8)Alivisatos A. P.1996. Semiconductor clusters, nanocrystals, and quantum dots [J]. Science, 271:933-937.
(9)Daniel M. C. and Astruc D.2004. Gold nanoparticles:Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J]. Chemical Reviews,104:293-346.
(10)Qiao X. G., Chen M., Zhou J., et al.2007. Synthesis of raspberry-like silica/polystyrene/silica multilayer hybrid particles via miniemulsion polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:1028-1037.
(11)Garcia I., Zafeiropoulos N. E., Janke A., et al.2007. Functional ization of iron oxide magnetic nanoparticles with poly(methyl methacrylate) brushes via grafting-from atom transfer radical polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:925-932.
(12)Gravano S. M., Dumas R., Liu K., et al.2005. Methods for the surface functionalization of gamma-Fe2O3 nanoparticles with initiators for atom transfer radical polymerization and the formation of core-shell inorganic-polymer structures [J]. Journal of Polymer Science Part a-Polymer Chemistry,43:3675-3688.
(13)Montagne F., Mondain-Monval O., Pichot C., et al.2006. Highly magnetic latexes from submicrometer oil in water ferrofluid emulsions [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:2642-2656.
(14)Pyun J. and Matyjaszewski K.2001. Synthesis of nanocomposite organic/inorganic hybrid materials using controlled/"living" radical polymerization [J]. Chemistry of Materials,13: 3436-3448.
(15)Zhang H., Wang C. L., Li M. J., et al.2005. Fluorescent nanocrystal-polymer complexes with flexible processability [J]. Advanced Materials,17:853-857.
(16)Brennan J. L., Hatzakis N. S., Tshikhudo T. R., et al.2006. Bionanoconjugation via click chemistry:The creation of functional hybrids of lipases and gold nanoparticles [J]. Bioconjugate Chemistry,17:1373-1375.
(17)Luo S. Z., Xu J., Zhang Y. F., et al.2005. Double hydrophilic block copolymer monolayer protected hybrid gold nanoparticles and their shell cross-linking [J]. Journal of Physical Chemistry B,109:22159-22166.
(18)Xu H. X.,-Xu J., Jiang X. Z., et al.2007. Thermosensitive unimolecular micelles surface-decorated with gold nanoparticles of tunable spatial distribution [J]. Chemistry of Materials,19:2489-2494.
(19.)Kotal A., Mandal T. K. and Walt D. R.2005. Synthesis of gold-poly(methyl methacrylate) core-shell nanoparticles by surface-confined atom transfer radical polymerization at elevated temperature [J]. Journal of Polymer Science Part a-Polymer Chemistry,43:3631-3642.
(20)Prucker O. and Ruhe J.1998. Synthesis of poly(styrene) monolayers attached to high surface area silica gels through self-assembled monolayers of azo initiators [J]. Macromolecules,31: 592-601.
(21)Prucker O. and Ruhe J.1998. Mechanism of radical chain polymerizations initiated by azo compounds covalently bound to the surface of spherical particles [J]. Macromolecules,31: 602-613.
(22)Pyun J., Kowalewski T. and Matyjaszewski K.2003. Synthesis of polymer brushes using atom transfer radical polymerization [J]. Macromolecular Rapid Communications,24:1043-1059.
(23)Ohno K., Morinaga T., Koh K., et al.2005. Synthesis of monodisperse silica particles coated with well-defined, high-density polymer brushes by surface-initiated atom transfer radical polymerization [J]. Macromolecules,38:2137-2142.
(24)von Werne T. and Patten T. E.1999. Preparation of structurally well-defined polymer-nanoparticle hybrids with controlled/living radical polymerizations [J]. Journal of the American Chemical Society,121:7409-7410.
(25)von Werne T. and Patten T. E.2001. Atom transfer radical polymerization from nanoparticles: A tool for the preparation of well-defined hybrid nanostructures and for understanding the chemistry of controlled/"living" radical polymerizations from surfaces [J]. Journal of the American Chemical Society,123:7497-7505.
(26)Kim K. M., Keum D. K. and Chujo Y.2003. Organic-inorganic polymer hybrids using polyoxazoline initiated by functionalized silsesquioxane [J]. Macromolecules,36:867-875.
(27)Mori H., Seng D. C., Zhang M. E, et al.2002. Hybrid nanoparticles with hyperbranched polymer shells via self-condensing atom transfer radical polymerization from silica surfaces [J], Langmuir,18:3682-3693.
(28)Carrot G, Rutot-Houze D., Pottier A., et al.2002. Surface-initiated ring-opening polymerization:A versatile method for nanoparticle ordering [J]. Macromolecules,35:8400-8404.
(29)Bartholome C., Beyou E., Bourgeat-Lami E., et al.2003. Nitroxide-mediated polymerizations from silica nanoparticle surfaces:"Graft from" polymerization of styrene using a triethoxysilyl-terminated alkoxyamine initiator [J]. Macromolecules,36:7946-7952.
(30)Perruchot C., Khan M. A., Kamitsi A., et al.2001. Synthesis of well-defined, polymer-grafted silica particles by aqueous ATRP [J]. Langmuir,17:4479-4481.
(31)Li C. Z. and Benicewicz B. C.2005. Synthesis of well-defined polymer brushes grafted onto silica nanoparticles via surface reversible addition-fragmentation chain transfer polymerization [J]. Macromolecules,38:5929-5936.
(32)Li D. J., Jones G. L., Dunlap J. R., et al.2006. Thermosensitive hairy hybrid nanoparticles synthesized by surface-initiated atom transfer radical polymerization [J]. Langmuir,22: 3344-3351.
(33)Parvole J., Laruelle G, Guimon C., et al.2003. Initiator-grafted silica particles for controlled free radical polymerization:Influence of the initiator structure on the grafting density [J]. Macromolecular Rapid Communications,24:1074-1078.
(34)Ueda J., Yamaguchi H., Yamauchi T., et al.2007. Radical graft polymerization of vinyl monomers onto nanoparticles in ionic liquid initiated by azo groups introduced onto the surface [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:1143-1149.
(35)Ramakrishnan A., Dhamodharan R. and Ruhe J.2006. Growth of poly(methyl methacrylate) brushes on silicon surfaces by atom transfer radical polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:1758-1769.
(36)Mansky P., Liu Y., Huang E., et al.1997. Controlling polymer-surface interactions with random copolymer brushes [J]. Science,275:1458-1460.
(37)Lindenblatt G, Schartl W., Pakula T., et al.2000. Synthesis of polystyrene-grafted polyorganosiloxane microgels and their compatibility with linear polystyrene chains [J]. Macromolecules,33:9340-9347.
(38)Ranjan R. and Brittain W. J.2007. Combination of Living Radical Polymerization and Click Chemistry for Surface Modification [J]. Macromolecules,40:6217-6223.
(39)Zhu M. Q., Wang L. Q., Exarhos G. J., et al.2004. Thermosensitive gold nanoparticles [J]. Journal of the American Chemical Society,126:2656-2657.
(40)Zhao B. and Brittain W. J.2000. Polymer brushes:surface-immobilized macromolecules [J]. Progress in Polymer Science,25:677-710.
(41)Koh K., Ohno K., Tsujii Y, et al.2003. Precision synthesis of organic/inorganic hybrid nanocapsules with a silanol-functionalized micelle template [J]. Angewandte Chemie-International Edition in English,42:4194-4197.
(42)Du J. Z. and Chen Y. M.2004. Organic-inorganic hybrid nanoparticles with a complex hollow structure [J]. Angewandte Chemie-International Edition in-English,43:5084-5087.
(43)Du J. Z. and Chen Y. M.2004. Atom-transfer radical polymerization of a reactive monomer: 3-(Trimethoxysilyl)propyl methacrylate [J]. Macromolecules,37:6322-6328.
(44)Du J. Z. and Chen Y. M.2004. Organic-inorganic hybrid nanoparticles with a complex hollow structure [J]. Angewandte Chemie-International Edition,43:5084-5087.
(45)Du J. Z. and Chen Y. M.2005. Hairy nanospheres by gelation of reactive block copolymer micelles [J]. Macromolecular Rapid Communications,26:491-494.
(46)Chen Y. M., Du J. Z., Xiong M., et al.2006. Gelation inside block copolymer aggregates and organic/inorganic nanohybrids [J]. Macromolecular Rapid Communications,27:741-750.
(47)Ionov L., Sapra S., Synytska A., et al.2006. Fast and spatially resolved environmental probing using stimuli-responsive polymer layers and fluorescent nanocrystals [J]. Advanced Materials,18:1453-1457.
(48)Willner I., Basnar B. and Willner B.2007. From molecular machines to microscale motility of objects:Application as "smart materials", sensors, and nanodevices [J]. Advanced Functional Materials,17:702-717.
(49)Barbosa P. C., Silva M. M., Smith M. J., et al.2007. Studies of solid-state electrochromic devices based on PEO/siliceous hybrids doped with lithium perchlorate [J]. Electrochimica Acta, 52:2938-2943.
(50)Lecommandoux S., Sandre O., Checot F., et al.2006. Smart hybrid magnetic self-assembled micelles and hollow capsules [J]. Progress in Solid State Chemistry,34:171-179.
(51)Li J., Liu B. and Li J. H.2006. Controllable self-assembly of CdTe/poly(N-isopropylacrylamide acrylic acid) microgels in response to pH stimuli [J]. Langmuir, 22:528-531.
(52)Sanchez C., Julian B., Belleville P., et al.2005. Applications of hybrid organic-inorganic nanocomposites [J]. Journal of Materials Chemistry,15:3559-3592.
(53)Zhu P. W. and Napper D. H.1994. Entanglement Knotting in Globule-to-Coil Transitions of Poly(N-Isopropyacrylamide) at Interfaces [J]. Journal of Colloid and Interface Science,168: 380-385.
(54)Zhu P. W. and Napper D. H.1994. Studies of Aggregation Kinetics of Polystyrene Latices Sterically Stabilized by Poly(N-Isopropylacrylamide) [J].Physical Review E,50:1360-1366.
(55)Zhu P. W. and Napper D. H.1994. Experimental-Observation of Coil-to-Globule Type Transitions at Interfaces [J]. Journal of Colloid and Interface Science,164:489-494.
(56)Zhao J., Shan J., Van Assche G., et al.2009. Demixing and Remixing Kinetics in Aqueous Dispersions of Poly(N-isopropylacrylamide) (PNIPAM) Brushes Bound to Gold Nanoparticles Studied by Means of Modulated Temperature Differential Scanning Calorimetry [J]. Macromolecules,42:5317-5327.
(57)Rezende C. A., Shan J., Lee L. T., et al.2009. Tuning the Structure of Thermosensitive Gold Nanoparticle Monolayers [J]. Journal of Physical Chemistry B,113:9786-9794.
(58)Shan J. and Tenhu H.2007. Recent advances in polymer protected gold nanoparticles: synthesis, properties and applications [J]. Chemical Communications,4580-4598.
(59)Raula J., Shan J., Nuopponen M., et al.2003. Synthesis of gold nanoparticles grafted with a thermoresponsive polymer by surface-induced reversible-addition-fragmentation chain-transfer polymerization [J]. Langmuir,19:3499-3504.
(60)Du J. Z. and Armes S. P.2005. pH-responsive vesicles based on a hydrolytically self-cross-linkable copolymer [J]. Journal of the American Chemical Society,127:12800-12801.
(61)Butun V., Billingham N. C. and Armes S. P.1997. Synthesis and aqueous solution properties of novel hydrophilic-hydrophilic block copolymers based on tertiary amine methacrylates [J]. Chemical Communications,671-672.
(62)Butun V., Billingham N. C. and Armes S. P.1998. Unusual aggregation behavior of a novel tertiary amine methacrylate-based diblock copolymer:Formation of micelles and reverse micelles in aqueous solution [J]. Journal of the American Chemical Society,120:11818-11819.
(63)Vamvakaki M., Billingham N. C. and Armes S. P.1999. Synthesis of controlled structure water-soluble diblock copolymers via oxyanionic polymerization [J]. Macromolecules,32: 2088-2090.
(64)Vamvakaki M:, Unali G. F., Butun V, et al.2001. Effect of partial quaternization on the aqueous solution properties of tertiary amine-based polymeric surfactants:Unexpected separation of surface activity and cloud point behavior [J]. Macromolecules,34:6839-6841.
(65)Butun V., Armes S. P. and Billingham N. C.2001. Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers [J]. Polymer,42:5993-6008.
(66)Xu J., Luo S. Z., Shi W. E, et al.2006. Two-stage collapse of unimolecular micelles with double thermoresponsive coronas [J]. Langmuir,22:989-997.
(67)Rungsardthong U., Deshpande M., Bailey L., et al.2001. Copolymers of amine methacrylate with poly(ethylene glycol) as vectors for gene therapy [J]. Journal of Controlled Release,73: 359-380.
(68)Licciardi M., Tang Y., Billingham N. C., et al.2005. Synthesis of novel folic acid-functionalized biocompatible block copolymers by atom transfer radical polymerization for gene delivery and encapsulation of hydrophobic drugs [J]. Biomacromolecules,6:1085-1096.
(69)Xie J.; Xu C., Kohler N., et al.2007. Controlled PEGylation of monodisperse Fe3O4 nanoparticles for reduced non-specific uptake by macrophage cells [J]. Advanced Materials,19: 3163-+.
(70)Wan S. R., Zheng Y., Liu Y. Q., et al.2005. Fe3O4 nanoparticles coated with homopolymers of glycerol mono(meth) acrylate and their block copolymers [J]. Journal of Materials Chemistry, 15:3424-3430.
(71)Guo M., Yan Y., Zhang H. K., et al.2008. Magnetic and pH-responsive nanocarriers with multilayer core-shell architecture for anticancer drug delivery [J]. Journal of Materials Chemistry, 18:5104-5112.
(72)Si S., Kotal A., Mandal T. K., et al.2004. Size-controlled synthesis of magnetite nanoparticles in the presence of polyelectrolytes [J]. Chemistry of Materials,16:3489-3496.
(73)Euliss L. E., Grancharov S. G., O'Brien S., et al.2003. Cooperative assembly of magnetic nanoparticles and block copolypeptides in aqueous media [J]. Nano Letters,3:1489-1493.
(74)Ai H., Flask C., Weinberg B., et al.2005. Magnetite-loaded polymeric micelles as ultrasensitive magnetic-resonance probes [J]. Advanced Materials,17:1949-+.
(75)Sanchez-Gaytan B. L., Cui W. H., Kim Y. J., et al.2007. Interfacial assembly of nanoparticles in discrete block-copolymer aggregates [J]. Angewandte Chemie-International Edition,46: 9235-9238.
(76)Wang X. E, Zhang Y F.; Zhu Z. Y, et al.2008. Fabrication of fullerene-containing hybrid vesicles via supramolecular self-assembly of a well-defined amphiphilic block copolymer incorporated with a Single C-60 moiety at the diblock junction point [J]. Macromolecular Rapid Communications,29:340-346.
(77)Lee H., Lee B. P. and Messersmith P. B.2007. A reversible wet/dry adhesive inspired by mussels and geckos [J]. Nature,448:338-U334.
(78)Xu J., Ye J. and Liu S. Y.2007. Synthesis of well-defined cyclic poly(N-isopropylacrylamide) via click chemistry and its unique thermal phase transition behavior [J]. Macromolecules,40: 9103-9110.
(2)Hadjichristidis N., latrou H., Pitsikalis M., et al.2006. Macromolecular architectures by living and controlled/living polymerizations [J]. Progress in Polymer Science,31:1068-1132.
(3)Hadjichristidis N., latrou H., Pitsikalis M., et al.2005. Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk [J]. Progress in Polymer Science,30:725-782.
(4)Hawker C. J., Bosman A. W. and Harth E.2001. New polymer synthesis by nitroxide mediated living radical polymerizations [J]. Chemical Reviews,101:3661-3688.
(5)Matyjaszewski K. and Xia J. H.2001. Atom transfer radical polymerization [J]. Chemical Reviews,101:2921-2990.
(6)Tsarevsky N. V. and Matyjaszewski K.2007. "Green" atom transfer radical polymerization: From process design to preparation of well-defined environmentally friendly polymeric materials [J]. Chemical Reviews,107:2270-2299.
(7)Kato M., Kamigaito M., Sawamoto M., et al.1995. Polymerization of Methyl-Methacrylate with the Carbon-Tetrachloride Dichlorotris(Triphenylphosphine)Ruthenium(Ii) Methylaluminum Bis(2,6-Di-Tert-Butylphenoxide) Initiating System-Possibility of Living Radical Polymerization [J]. Macromolecules,28:1721-1723.
(8)Wang J. S. and Matyjaszewski K.1995. Controlled Living Radical Polymerization-Halogen Atom-Transfer Radical Polymerization Promoted by a Cu(I)Cu(Ii) Redox Process [J]. Macromolecules,28:7901-7910.
(9)Wang J. S. and Matyjaszewski K.1995. Controlled Living Radical Polymerization Atom-Transfer Radical Polymerization in the Presence of Transition-Metal Complexes [J]. Journal of the American Chemical Society,117:5614-5615.
(10)Teodorescu M. and Matyjaszewski K.1999. Atom transfer radical polymerization of (meth)acrylamides [J]. Macromolecules,32:4826-4831.
(11)Rademacher J., Baum R., Pallack M., et al.2000. Atom transfer radical polymerization of N,N-dimethylacrylamide [J]. Macromolecules,33:284-288.
(12)Gao H. F. and Matyjaszewski K.2008. Synthesis of low-polydispersity miktoarm star copolymers via a simple "Arm-First" method:Macromonomers as arm precursors [J]. Macromolecules,41:4250-4257.
(13)Jiang S., Chen Q., Tripathy M., et al.2010. Janus Particle Synthesis and Assembly [J]. Advanced Materials,22:1060-1071.
(14)Liu H., Jiang X. Z., Fan J., et al.2007. Aldehyde surface-functionalized shell cross-linked micelles with pH-tunable core swellability and their bioconjugation with lysozyme [J]. Macromolecules,40:9074-9083.
(15)Xu J., Ge Z. S., Zhu Z. Y., et al.2006. Synthesis and micellization properties of double hydrophilic A(2)BA(2) and A(4)BA(4) non-linear block copolymers [J]. Macromolecules,39: 8178-8185.
(16)Matyjaszewski K., Miller P. J., Pyun J., et al.1999. Synthesis and characterization of star polymers with varying arm number, length, and composition from organic and hybrid inorganic/organic multifunctional initiators [J]. Macromolecules,32:6526-6535.
(17)Aniansson E., Wall S. N. and Almgren M.1976. Theory of Kinetics of Micellar Equilibria and Quantitative Interpretation of Chemical Relaxation Studies of Micellar Solutions of Ionic Surfactants [J]. Journal of Physical Chemistry,80:905-922.
(18)Gong F. H., Tang H. L., Liu C. L., et al.2006. Preparation of hyperbranched polymers through ATRP of in situ formed AB* monomer [J]. Journal of Applied Polymer Science,101: 850-856.
(19)Jho J. Y., Yoo S. H. and Yoon T. H.1999. Controlling the degree of branching in ATRP of hyperbranched polyacrylates. [J]. Abstracts of Papers of the American Chemical Society,218: U545-U545.
(20)Chiefari J., Chong Y. K., Ercole F., et al.1998. Living free-radical polymerization by reversible addition-fragmentation chain transfer:The RAFT process [J]. Macromolecules,31: 5559-5562.
(21)Moad G., Chiefari J., Chong Y. K., et al.2000. Living free radical polymerization with reversible addition-fragmentation chain transfer (the life of RAFT) [J]. Polymer International,49: 993-1001.
(22)Convertine A. J., Lokitz B. S., Vasileva Y, et al.2006. Direct synthesis of thermally responsive DMA/NIPAM diblock and DMA/NIPAM/DMA triblock copolymers via aqueous, room temperature RAFT polymerization [J]. Macromolecules,39:1724-1730.
(23)Chong Y. K., Le T. P. T., Moad G, et al.1999. A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization:The RAFT process [J]. Macromolecules,32:2071-2074.
(24)Lowe A. B., Wang R., Tiriveedhi V., et al.2007. RAFT synthesis and solution properties of pH-responsive styrenic-based AB diblock copolymers of 4-vinylbenzyltrimethylphosphonium chloride with N,N-dimethylbenzylvinylamine [J]. Macromolecular Chemistry and Physics,208: 2339-2347.
(25)Convertine A. J. and McCormick C. L.2005. Synthesis of temperature responsive block copolymers via aqueous room temperature RAFT polymerization [J]. Abstracts of Papers of the American Chemical Society,230:U4124-U4125.
(26)Donovan M. S., Sumerlin B. S., Lowe A. B., et al.2002. Controlled/"living" polymerization of sulfobetaine monomers directly in aqueous media via RAFT [J]. Macromolecules,35: 8663-8666.
(27)Zhang Y. F., Luo S. Z. and Liu S. Y.2005. Fabrication of hybrid nanoparticles with thermoresponsive coronas via a self-assembling approach [J]. Macromolecules,38:9813-9820.
(28)Yusa S., Shimada Y., Mitsukami Y., et al.2004. Heat-induced association and dissociation behavior of amphiphilic diblock copolymers synthesized via reversible addition-fragmentation chain transfer radical polymerization [J]. Macromolecules,37:7507-7513.
(29)Schilli C. M., Zhang M. F., Rizzardo E., et al.2004. A new double-responsive block copolymer synthesized via RAFT polymerization: Poly(N-isopropylacrylamide)-block-poly(acrylic acid) [J]. Macromolecules,37:7861-7866.
(30)Veregin R. P. N., Georges M. K.; Kazmaier P. M., et al.1993. Free-Radical Polymerizations for Narrow Polydispersity Resins-Electron-Spin-Resonance Studies of the Kinetics and Mechanism [J]. Macromolecules,26:5316-5320.
(31)Debuigne A., Chan-Seng D., Li L. C., et al.2007. Synthesis and evaluation of sterically hindered 1,1-diadamantyl nitroxide as a low-temperature mediator for the stable free radical polymerization process [J]. Macromolecules,40:6224-6232.
(32)Debuigne A., Radhakrishnan T. and Georges M. K.2006. Stable free radical polymerization of acrylates promoted by alpha-hydroxycarbonyl compounds [J]. Macromolecules,39:5359-5363.
(33)Flakus S., Mandel K., Bartsch M., et al.2005. A new acyclic alpha-hydrogen bearing nitroxide and its corresponding alkoxyamine for stable free radical polymerization [J]. Macromolecular Rapid Communications,26:1698-1703.
(34)Gopalan P. and Ober C. K.2001. Highly reactive 2,5-disubstituted styrene-based monomer polymerized via stable free radical polymerization:Effect of substitution and liquid crystallinity on polymerization [J]. Macromolecules,34:5120-5124.
(35)Zou Y. S., Lin J., Zhuang R. C., et al.2000. Synthesis of block copolymer from dissimilar vinyl monomer by stable free radical polymerization [J]. Macromolecules,33:4745-4749.
(36)Pasquale A. J. and Long T. E.1999. Real-time monitoring of the stable free radical polymerization of styrene via in-situ mid-infrared spectroscopy [J]. Macromolecules,32: 7954-7957.
(37)Moffat K. A., Hamer G. K. and Georges M. K.1999. Stable free radical polymerization process:Kinetic and mechanistic study of the thermal decomposition of MB-TMP monitored by NMR and ESR spectroscopy [J]. Macromolecules,32:1004-1012.
(38)Listigovers N. A., Georges M. K., Odell P. G, et al.1996. Narrow-polydispersity diblock and triblock copolymers of alkyl acrylates by a "living" stable free radical polymerization [J]. Macromolecules,29:8992-8993.
(39)Ropson N., Dubois P., Jerome R., et al.1995. Macromolecular Engineering of Polylactones and Polylactides.20. Effect of Monomer, Solvent, and Initiator on the Ring-Opening Polymerization as Initiated with Aluminum Alkoxides [J]. Macromolecules,28:7589-7598.
(40)Ropson N., Dubois P., Jerome R., et al.1994. Macromolecular Engineering of Polylactones and Polylactides.17. Cryometric and Viscosimetric Analysis of the Species Active in the Ring-Opening Polymerization of Lactones, Lactides, and Cyclic Anhydrides as Initiated by Aluminum Triisopropoxide [J]. Macromolecules,27:5950-5956.
(41)Ropson N., Dubois P., Jerome R., et al.1993. Macromolecular Engineering of Polylactones and Polylactides.14. A C-13 and Al-27 Nmr-Study of the Effect of Gamma-Butyrolactone on the Structure of Aluminum Isopropoxide in Toluene [J]. Macromolecules,26:6378-6385.
(42)Dubois P., Ropson N., Jerome R., et al.1996. Macromolecular engineering of polylactones and polylactides.19. Kinetics of ring-opening polymerization of epsilon-caprolactone initiated with functional aluminum alkoxides [J]. Macromolecules,29:1965-1975.
(43)Habraken G. J. M., Koning C. E. and Heise A.2009. Peptide Block Copolymers by N-Carboxyanhydride Ring-Opening Polymerization and Atom Transfer Radical Polymerization: The Effect of Amide Macroinitiators [J]. Journal of Polymer Science Part a-Polymer Chemistry, 47:6883-6893.
(44)Lu H., Wang J., Lin Y, et al.2009. One-Pot Synthesis of Brush-Like Polymers via Integrated Ring-Opening Metathesis Polymerization and Polymerization of Amino Acid N-Carboxyanhydrides [J]. Journal of the American Chemical Society,131:13582-+.
(45)Rao J. Y., Zhu Z. Y and Liu S. Y 2009. Synthesis and micellization behavior of stimuli-responsive polypeptide hybrid triblock copolymer [J]. Chinese Science Bulletin,54: 1912-1917.
(46)Rao J. Y, Zhang Y F., Zhang J. Y, et al.2008. Facile Preparation of Well-Defined AB(2) Y-Shaped Miktoarm Star Polypeptide Copolymer via the Combination of Ring-Opening Polymerization and Click Chemistry [J]. Biomacromolecules,9:2586-2593.
(47)Rao J. Y., Luo Z. E, Ge Z. S., et al.2007. "Schizophrenic" micellization associated with coil-to-helix transitions based on polypeptide hybrid double hydrophilic rod-coil diblock copolymer [J]. Biomacromolecules,8:3871-3878.
(48)Yu H. J., Chen X. S., Lu T. C., et al.2007. Poly(L-lysine)-graft-chitosan copolymers: Synthesis, characterization, and gene transfection effect [J]. Biomacromolecules,8:1425-1435.
(49)Wieringa R. H., Siesling E. A., Geurts P. F. M., et al.2001. Surface grafting of poly (L-glutamates).1. Synthesis and characterization [J]. Langmuir,17:6477-6484. (50) Yu M. E. and Deming T. J.1998. Synthetic polypeptide mimics of marine adhesives [J]. Macromolecules,31:4739-4745.
(51)Trnka T. M., Day M. W. and Grubbs R. H.2001. Olefin metathesis with 1,1-difluoroethylene [J]. Angewandte Chemie-International Edition,40:3441-+.
(52)Trnka T. M. and Grubbs R. H.2001. The development of L2X2Ru= CHR olefin metathesis catalysts:An organometallic success story [J]. Accounts of Chemical Research,34:18-29.
(53)Singh R., Czekelius C. and Schrock R. R.2006. Living ring-opening metathesis polymerization of cyclopropenes [J]. Macromolecules,39:1316-1317.
(54)Buchmeiser M. and Schrock R. R.1995. Synthesis of Polyenes That Contain Metallocenes Via the Living Polymerization of Ethynylferrocene and Ethynylruthenocene [J]. Macromolecules, 28:6642-6649.
(55)Schrock R. R., Lee J. K., Odell R., et al.1995. Exploring Factors That Determine Cis/Trans Structure and Tacticity in Polymers Prepared by Ring-Opening Metathesis Polymerization with Initiators of the Type Syn-Mo(Nar)(Chcme(2)Ph)(or)(2) and Anti-Mo(Nar)(Chcme(2)Ph)(or)(2)-Observation of a Temperature-Dependent Cis/Trans Ratio [J]. Macromolecules,28:5933-5940.
(56)Howard T. R., Lee J. B. and Grubbs R. H.1980. Titanium metallacarbene-metallacyclobutane reactions:stepwise metathesis [J]. Journal of the American Chemical Society 102:6876-6878
(57)Yokoyama A. and Yokozawa T.2007. Converting step-growth to chain-growth condensation polymerization [J]. Macromolecules,40:4093-4101.
(58)Yokozawa T. and Yokoyama A.2009. Chain-Growth Condensation Polymerization for the Synthesis of Well-Defined Condensation Polymers and pi-Conjugated Polymers [J]. Chemical Reviews,109:5595-5619.
(59)Masukawa T., Yokoyama A. and Yokozawa T.2009. Synthesis of Well-Defined Polybenzamide-block-Polystyrene by Combination of Chain-Growth Condensation Polymerization and RAFT Polymerization [J]. Macromolecular Rapid Communications,30: 1413-1418.
(60)Ohta Y, Fujii S., Yokoyama A., et al.2009. Synthesis of Well-Defined Hyperbranched Polyamides by Condensation Polymerization of AB(2) Monomer through Changed Substituent Effects [J]. Angewandte Chemie-International Edition,48:5942-5945.
(61)Yokoyama A., Masukawa T., Yamazaki Y., et al.2009. Successive Chain-Growth Condensation Polymerization for the Synthesis of Well-Defined Diblock Copolymers of Aromatic Polyamide and Aromatic Polyether [J]. Macromolecular Rapid Communications,30:24-28.
(62)Ohishi T., Sugi R., Yokoyama A., et al.2008. Synthesis via Chain-Growth Condensation Polymerization and Gelating Properties of a Variety of Block Copolymers-of Meta-and Para-Substituted Aromatic Polyamides [J]. Macromolecules,41:9683-9691.
(63)Ajioka N., Yokoyama A. and Yokozawa T.2008. Synthesis of well-defined rod-coil diblock copolymer of aromatic polyether and polyacrylonitrile by chain-growth condensation polymerization and atom transfer radical polymerization [J]. Macromolecular Rapid Communications,29:665-671.
(64)Yokozawa T., Adachi I., Miyakoshi R., et al.2007. Catalyst-transfer condensation polymerization for the synthesis of well-defined polythiophene with hydrophilic side chain and of diblock copolythiophene with hydrophilic and hydrophobic side chains [J]. High Performance Polymers,19:684-699.
(65)Ajioka N., Suzuki Y., Yokoyama A., et al.2007. Synthesis of well-defined polystyrene-b-aromatic polyether using an orthogonal initiator for atom transfer radical polymerization and chain-growth condensation polymerization [J]. Macromolecules,40: 5294-5300.
(66)Finn M. G, Kolb H. C., Fokin V. V., et al.2008. Click chemistry-Definition and aims [J]. Progress in Chemistry,20:1-4.
(67)Kolb H. C., Finn M. G. and Sharpless K. B.2001. Click chemistry:Diverse chemical function from a few good reactions [J]. Angewandte Chemie-International Edition,40:2004-+.
(68)Ossipov D. A. and Hilborn J.2006. Poly(vinyl alcohol)-based hydrogels formed by "click chemistry" [J]. Macromolecules,39:1709-1718.
(69)Xu J. and Liu S. Y.2009. Synthesis of Well-Defined 7-Arm and 21-Arm Poly (N-isopropylacrylamide) Star Polymers with beta-Cyclodextrin Cores via Click Chemistry and Their Thermal Phase Transition Behavior in Aqueous Solution [J]. Journal of Polymer Science Part a-Polymer Chemistry,47:404-419.
(70)Gao H. F. and Matyjaszewski K.2006. Synthesis of star polymers by a combination of ATRP and the "click" coupling method [J]. Macromolecules,39:4960-4965.
(71)Shi G. Y, Tang X. Z. and Pan C. Y.2008. Tadpole-shaped amphiphilic copolymers prepared via RAFT polymerization and click reaction [J]. Journal of Polymer Science Part a-Polymer Chemistry,46:2390-2401.
(72)Piirma I., polymeric Surfactants:Sufanctant Science 42.1992, New York:Marcel Dekker.
(73)Alexandridis P. and lindman B., Amphiphilic Block Copolymers:Self-assembly and Application.2000, Amsterdam:Elsevier.
(74)何天白 and 胡汉杰,海外高分子科学的新进展.1997,北京：化学工业出版社.
(75)Gan Z. H., Jim T. F., Li M., et al.1999. Enzymatic biodegradation of poly(ethylene oxide-b-epsilon-caprolactone) diblock copolymer and its potential biomedical applications [J]. Macromolecules,32:590-594.
(76)Kataoka K., Harada A. and Nagasaki Y.2001. Block copolymer micelles for drug delivery: design, characterization and biological significance [J]. Advanced Drug Delivery Reviews,47: 113-131.
(77)Antonietti M., Forster S., Hartmann J., et al.1996. Novel amphiphilic block copolymers by polymer reactions and their use for solubilization of metal salts and metal colloids [J]. Macromolecules,29:3800-3806.
(78)Moffitt M. and Eisenberg A.1997. Scaling relations and size control of block ionomer microreactors containing different metal ions [J]. Macromolecules,30:4363-4373.
(79)Halperin A., Tirrell M. and Lodge T. P.1992. Tethered Chains in Polymer Microstructures [J]. Advances in Polymer Science,100:31-71.
(80)Zhang L. F., Yu K. and Eisenberg A.1996. Ion-induced morphological changes in "crew-cut" aggregates of amphiphilic block copolymers [J]. Science,272:1777-1779.
(81)Zhang L. F. and Eisenberg A.1995. Multiple Morphologies of Crew-Cut Aggregates of Polystyrene-B-Poly(Acrylic Acid) Block-Copolymers [J]. Science,268:1728-1731.
(82)Zhang L. F. and Eisenberg A.1999. Crew-cut aggregates from self-assembly of blends of polystyrene-b-poly(acrylic acid) block copolymers and homopolystyrene in solution [J]. Journal of Polymer Science Part B-Polymer Physics,37:1469-1484.
(83)Zhang L. F. and Eisenberg A.1998. Formation of crew-cut aggregates of various morphologies from amphiphilic block copolymers in solution [J]. Polymers for Advanced Technologies,9:677-699.
(84)Zhang L. F. and Eisenberg A.1996. Morphogenic effect of added ions on crew-cut aggregates of polystyrene-b-poly(acrylic acid) block copolymers in solutions [J]. Macromolecules,29: 8805-8815.
(85)Thurmond K. B., Kowalewski T. and Wooley K. L.1996. Water-soluble knedel-like structures: The preparation of shell-cross-linked small particles [J]. Journal of the American Chemical Society,118:7239-7240.
(86)Colfen H.2001. Double-hydrophilic block copolymers:Synthesis and application as novel surfactants and crystal growth modifiers [J]. Macromolecular Rapid Communications,22: 219-252.
(87)Gil E. S. and Hudson S. A.2004. Stimuli-reponsive polymers and their bioconjugates [J]. Progress in Polymer Science,29:1173-1222.
(88)Wang D., Wu T., Wan X. J., et al.2007. Purely salt-responsive micelle formation and inversion based on a novel schizophrenic sulfobetaine block copolymer:Structure and kinetics of micellization [J]. Langmuir,23:11866-11874.
(89)Butun V., Billingham N. C. and Armes S. P.1998. Unusual aggregation behavior of a novel tertiary amine methacrylate-based diblock copolymer:Formation of micelles and reverse micelles in aqueous solution [J]. Journal of the American Chemical Society,120:11818-11819.
(90)Wu C. and Zhou S. Q.1995. Thermodynamically Stable Globule State of a Single Poly(N-Isopropylacrylamide) Chain in Water [J]. Macromolecules,28:5388-5390.
(91)徐建，基于聚(N-异丙基烯酰胺)的多种拓扑缝构水溶性高分子制备及其溶液性爱研
究.2008,中国科学技术大学：合肥.
(92)Schild H. G.1992. Poly (N-Isopropylacrylamide)-Experiment, Theory and Application [J]. Progress in Polymer Science,17:163-249.
(93)Lutz J. F.2008. Polymerization of oligo(ethylene glycol) (meth)acrylates:Toward new generations of smart biocompatible materials [J]. Journal of Polymer Science Part a-Polymer Chemistry,46:3459-3470.
(94)Lutz J. E, Weichenhan K., Akdemir O., et al.2007. About the phase transitions in aqueous solutions of thermoresponsive copolymers and hydrogels based on 2-(2-methoxyethoxy)ethyl methacrylate and oligo(ethylene glycol) methacrylate [J]. Macromolecules,40:2503-2508.
(95)Lutz J. F., Akdemir O. and Hoth A.2006. Point by point comparison of two thermosensitive polymers exhibiting a similar LCST:Is the age of poly(NIPAM) over? [J]. Journal of the American Chemical Society,128:13046-13047.
(96)Arotcarena M., Heise B., Ishaya S., et al.2002. Switching the inside and the outside of aggregates of water-soluble block copolymers with double thermoresponsivity [J]. Journal of the American Chemical Society,124:3787-3793.
(97)Martin T. J., Prochazka K., Munk P., et al.1996. pH-dependent micellization of poly(2-vinylpyridine)-block-poly(ethylene oxide) [J]. Macromolecules,29:6071-6073.
(98)Liu S. Y. and Armes S. P.2003. Synthesis and aqueous solution behavior of a pH-responsive schizophrenic diblock copolymer [J]. Langmuir,19:4432-4438.
(99)Butun V., Armes S. P., Billingham N. C., et al.2001. The remarkable "flip-flop" self-assembly of a diblock copolymer in aqueous solution [J]. Macromolecules,34:1503-1511.
(100)Liu S. Y., Billingham N. C. and Armes S. P.2001. A schizophrenic water-soluble diblock copolymer [J]. Angewandte Chemie-International Edition,40:2328-+.
(101)Liu S. Y. and Armes S. P.2002. Polymeric surfactants for the new millennium:A pH-responsive, zwitterionic, schizophrenic diblock copolymer [J]. Angewandte Chemie-International Edition,41:1413-1416.
(102)Butun V., Vamvakaki M., Billingham N. C., et al.2000. Synthesis and aqueous solution properties of novel neutral/acidic block copolymers [J]. Polymer,41:3173-3182.
(103)Cai Y. L. and Armes S. P.2004. A Zwitterionic ABC triblock copolymer that forms a "Trinity" of micellar aggregates in aqueous solution [J]. Macromolecules,37:7116-7122.
(104)Gohy J. E, Creutz S., Garcia M., et al.2000. Aggregates formed by amphoteric diblock copolymers in water [J]. Macromolecules,33:6378-6387.
(105)Dai S., Ravi P., Tam K. C., et al.2003. Novel pH-responsive amphiphilic diblock copolymers with reversible micellization properties [J]. Langmuir,19:5175-5177.
(106)Virtanen J., Arotcarena M., Heise B., et al.2002. Dissolution and aggregation of a poly(NIPA-block-sulfobetaine) copolymer in water and saline aqueous solutions [J]. Langmuir,18: 5360-5365.
(107)Hu F. Q., Wei L., Zhou Z., et al.2006. Preparation of biocompatible magnetite nanocrystals for in vivo magnetic resonance detection of cancer [J]. Advanced Materials,18:2553-+.
(108)Haynes C. L. and Van Duyne R. P.2001. Nanosphere lithography:A versatile nanofabrication tool for studies of size-dependent nanoparticle optics [J]. Journal of Physical Chemistry B,105:5599-5611.
(109)Walter E. C., Penner R. M., Liu H., et al.2002. Sensors from electrodeposited metal nanowires [J]. Surface and Interface Analysis,34:409-412.
(110)Zhu M. Q., Wang L. Q., Exarhos G. J., et al.2004. Thermosensitive gold nanoparticles [J]. Journal of the American Chemical Society,126:2656-2657.
(111)Xie J., Xu C., Kohler N., et al.2007. Controlled PEGylation of monodisperse Fe3O4 nanoparticles for reduced non-specific uptake by macrophage cells [J]. Advanced Materials,19: 3163-+.
(1)Alexandridis P.1996. Amphiphilic copolymers and their applications [J]. Current Opinion in Colloid & Interface Science,1:490-501.
(2)Zhang L. F. and Eisenberg A.1995. Multiple Morphologies of Crew-Cut Aggregates of Polystyrene-B-Poly(Acrylic Acid) Block-Copolymers [J]. Science,268:1728-1731.
(3)Balogh L., Samuelson L., Alva K. S., et al.1998. Synthesis, homopolymerization, and block copolymerization of N-ethyl-2-ethynyl-pyridinium trifluoromethanesulfonate with styrene and butadiene [J]. Journal of Polymer Science Part a-Polymer Chemistry,36:703-712.
(4)Hong H. Y., Mai Y. Y., Zhou Y. F., et al.2008. Synthesis and supramolecular self-assembly of thermosensitive amphiphilic star copolymers based on a hyperbranched polyether core [J]. Journal of Polymer Science Part a-Polymer Chemistry,46:668-681.
(5)Ge Z. S., Chen D. Y., Zhang J. Y., et al.2007. Facile synthesis of dumbbell-shaped dendritic-linear-dendritic triblock copolymer via reversible addition-fragmentation chain transfer polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:1432-1445.
(6)Ge Z. S., Luo S. Z. and Liu S. Y.2006. Syntheses and self-assembly of poly(benzyl ether)-b-poly(N-isopropylacrylamide) dendritic-linear diblock copolymers [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:1357-1371.
(7)Babin J., Taton D., Brinkmann M., et al.2008. Synthesis and self-assembly in bulk of linear and Mikto-arm star block copolymers based on polystyrene and poly(glutamic acid) [J]. Macromolecules,41:1384-1392.
(8)Havrankova J., Limpouchova Z., Stepanek M., et al.2007. Self-assembly of heteroarm star copolymers-A Monte Carlo study [J]. Macromolecular Theory and Simulations,16:386-398.
(9)Hadjichristidis N., Iatrou H., Pitsikalis M., et al.2005. Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk [J]. Progress in Polymer Science,30:725-782.
(10)Li Z. B., Kesselman E., Talmon Y., et al.2004. Multicompartment micelles from ABC miktoarm stars in water [J]. Science,306:98-101.
(11)Li Z. B., Hillmyer M. A. and Lodge T. P.2006. Morphologies of multicompartment micelles formed by ABC miktoarm star terpolymers [J]. Langmuir,22:9409-9417.
(12)Li Z. B., Hillmyer M. A. and Lodge T. P.2006. Laterally nanostructured vesicles, polygonal bilayer sheets, and segmented wormlike micelles [J]. Nano Letters,6:1245-1249.
(13)Erdogan T., Gungor E., Durmaz H., et al.2006. Photoresponsive poly(methyl methacrylate)(2)-(polystyrene)(2) miktoarm star copolymer containing an azobenzene moiety at the core [J]. Journal of Polymer Science Part A-Polymer Chemistry,44:1396-1403.
(14)Saito N., Liu C., Lodge T. P., et al.2008. Multicompartment Micelles from Polyester-Containing ABC Miktoarm Star Terpolymers [J]. Macromolecules,41:8815-8822.
(15)Sioula S., Hadjichristidis N. and Thomas E. L.1998. Direct evidence for confinement of junctions to lines in an 3 miktoarm star terpolymer microdomain structure [J]. Macromolecules, 31:8429-8432.
(16)Van Butsele K., Stoffelbach F., Jerome R., et al.2006. Synthesis of novel amphiphilic and pH-sensitive ABC miktoarm star terpolymers [J]. Macromolecules,39:5652-5656.
(17)Yamauchi K., Takahashi K., Hasegawa H., et al.2003. Microdomain morphology in an ABC 3-miktoarm star terpolymer:A study by energy-filtering TEM and 3D electron tomography [J]. Macromolecules,36:6962-6966.
(18)Tunca U., Ozyurek Z., Erdogan T., et al.2004. Novel miktofunctional initiator for the preparation of an ABC-type miktoarm star polymer via a combination of controlled polymerization techniques [J]. Journal of Polymer Science Part A-Polymer Chemistry,42: 4228-4236.
(19)Lu T., He X. H. and Liang H. J.2004. Ordered microstructures by assembly of ABC 3-miktoarm star terpolymers and linear homopolymers [J]. Journal of Chemical Physics,121: 9702-9707.
(20)Hadjichristidis N. and Pispas S.2006. Designed block copolymers for ordered polymeric nanostructures [J]. Advances in Polymer Science,200:37-55.
(21)Huang R., Jiang Y. and Liang H. J.2006. Effect of architecture on the tensile properties of triblock copolymers in a lamellar phase [J]. Chemphyschem,7:1950-1956.
(22)Birshtein T. M., Polotsky A. A. and Abetz V.2004. Theory of the lamellar superstructure of an ABC 3-miktoarm star-terpolymer [J]. Macromolecular Theory and Simulations,13:512-519.
(23)Kou D. Z., Jiang Y. and Liang H. J.2006. Microstructures from a mixture of ABC 3-miktoarm star terpolymers and homopolymers in two-dimensional space [J]. Journal of Physical Chemistry B,110:23557-23563.
(24)Zhu Y. T., Li R. K. Y. and Jiang W.2006. A Monte Carlo simulation for the micellization of ABC 3-miktoarm star terpolymers in a selective solvent [J]. Chemical Physics,327:137-143.
(25)Zhulina E. B. and Borisov O. V.2008. Scaling theory of 3-miktoarm ABC copolymer micelles in selective solvent [J]. Macromolecules,41:5934-5944.
(26)M. Ciampolini a. N. N.1966. Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine [J]. Inorganic Chemistry,5:41-44.
(27)Mantovani G., Ladmiral V., Tao L., et al.2005. One-pot tandem living radical polymerisation-Huisgens cycloaddition process ("click") catalysed by N-alkyl-2-pyridylmethanimine/Cu(I)Br complexes [J]. Chemical Communications,2089-2091.
(28)Wu P., Feldman A. K., Nugent A. K., et al.2004. Efficiency and fidelity in a click-chemistry route to triazole dendrimers by the copper(Ⅰ)-catalyzed ligation of azides and alkynes [J]. Angewandte Chemie-International Edition,43:3928-3932.
(29)Pitsikalis M., Pispas S., Mays J. W., et al.1998. Nonlinear block copolymer architectures [J]. Advances in Polymer Science,135:1-137.
(30)Durmaz H., Karatas F., Tunca U., et al.2006. Preparation of ABC miktoarm star terpolymer containing poly(ethylene glycol), polystyrene, and poly(tert-butylacrylate) arms by combining Diels-Alder reaction, atom transfer radical, and stable free radical polymerization routes [J]. Journal of Polymer Science Part A-Polymer Chemistry,44:499-509.
(31)He T., Li D. J., Sheng X., et al.2004. Synthesis of ABC 3-miktoarm star terpolymers from a trifunctional initiator by combining ring-opening polymerization, atom transfer radical polymerization, and nitroxide-mediated radical polymerization [J]. Macromolecules,37: 3128-3135.
(32)Wang G. W. and Huang J. L.2007. Preparation of star-shaped ABC copolymers of polystyrene-poly(ethylene oxide)-polyglycidol using ethoxyethyl glycidyl ether as the cap molecule [J]. Macromolecular Rapid Communications,28:298-304.
(33)Wang G. W. and Huang J. L.2008. Synthesis and characterization of well-defined ABC 3-Miktoarm star-shaped terpolymers based on poly(styrene), poly(ethylene oxide), and poly(epsilon-caprolactone) by combination of the "Living" anionic polymerization with the ring-opening polymerization [J]. Journal of Polymer Science Part A-Polymer Chemistry,46: 1136-1150.
(34)Feng X. S. and Pan C. Y.2002. Synthesis of amphiphilic miktoarm ABC star copolymers by RAFT mechanism using maleic anhydride as linking agent [J]. Macromolecules,35:4888-4893.
(35)Feng X. S. and Pan C. Y.2002. Block and star block copolymers by mechanism transformation.7. Synthesis of polytetrahydrofuran/poly(1,3-dioxepane)/polystyrene ABC miktoarm star copolymers by combination of CROP and ATRP [J]. Macromolecules,35: 2084-2089.
(36)He X. H., Huang L., Liang H. J., et al.2003. Localizations of junction points of ABC 3-miktoarm star terpolymers [J]. Journal of Chemical Physics,118:9861-9863.
(37)Shi P. H., Li Y. G. and Pan C. Y.2004. Block and star block copolymers by mechanism transformation-X. Synthesis of poly(ethylene oxide) methyl ether/polystyrene/poly(L-lactide) ABC miktoarm star copolymers of by combination of RAFT and ROP [J]. European Polymer Journal,40:1283-1290.
(38)Li Y. G., Wang Y. M. and Pan C. Y.2003. Block and star block copolymers by mechanism transformation 9:Preparation and characterization of poly(methyl methacrylate)/poly(1,3-dioxepane)/polystyrene ABC miktoarm star copolymers by combination of reversible addition-fragmentation chain-transfer polymerization and cationic ring-opening polymerization [J]. Journal of Polymer Science Part A-Polymer Chemistry,41:1243-1250.
(39)Altintas 0., Hizal G. and Tunca U.2006. ABC-type hetero-arm star terpolymers through "click" chemistry [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:5699-5707.
(40)Yang L. P., Zhou H. X., Shi G. Y., et al.2008. Synthesis of ABCD 4-miktoarm star polymers by combination of RAFT, ROP, and "Click chemistry'" [J]. Journal of Polymer Science Part A-Polymer Chemistry,46:6641-6653.
(41)Deng G. H., Ma D. Y. and Xu Z. Z.2007. Synthesis of ABC-type miktoarm star polymers by "click" chemistry, ATRP and ROP [J]. European Polymer Journal,43:1179-1187.
(42)Yuan Y. Y., Wang Y. C., Du J. Z., et al.2008. Synthesis of Amphiphilic ABC 3-Miktoarm Star Terpolymer by Combination of Ring-Opening Polymerization and "Click" Chemistry [J]. Macromolecules,41:8620-8625.
(43)Altintas O., Yankul B., Hizal G., et al.2007. One-pot preparation of 3-miktoarm star terpolyrmers via click [3+2] reaction [J]. Journal of Polymer Science Part A-Polymer Chemistry, 45:3588-3598.
(44)Braunecker W. A. and Matyjaszewski K.2007. Controlled/living radical polymerization: Features, developments, and perspectives [J]. Progress in Polymer Science,32:93-146.
(45)Matyjaszewski K.2003. Controlled/living radical polymerization:State of the art in 2002 [J]. ACS Symposium Series,854:2-9.
(46)Qiu J., Charleux B. and Matyjaszewski K.2001. Progress in controlled/living polymerization (CLP) in aqueous media-Part Ⅲ. Controlled/living polymerization in aqueous media [J]. Polimery,46:663-672.
(47)Mecerreyes D., Moineau G., Dubois P., et al.1998. Simultaneous dual living polymerizations: A novel one-step approach to block and graft copolymers [J]. Angewandte Chemie-International Edition,37:1274-1276.
(48)Duxbury C. J., Wang W. X., de Geus M., et al.2005. Can block copolymers be synthesized by a single-step chemoenzymatic route in supercritical carbon dioxide? [J]. Journal of the American Chemical Society,127:2384-2385.
(49)Wang W. X., Howdle S. M. and Yan D. Y.2005. One-step seed dispersion polymerisation in supercritical carbon dioxide [J]. Chemical Communications,3939-3941.
(50)Zhou J. X., Villarroya S., Wang W. X., et al.2006. One-step chemoenzymatic synthesis of poly(epsilon-caprolactone-block-methyl methacrylate) in supercritical C02 [J]. Macromolecules, 39:5352-5358.
(51)Golas P. L. and Matyjaszewski K.2007. Click chemistry and ATRP:A beneficial union for the preparation of functional materials [J]. Qsar & Combinatorial Science,26:1116-1134.
(52)Lutz J. F., Borner H. G. and Weichenhan K.2006. Combining ATRP and "click" chemistry:a promising platform toward functional biocompatible polymers and polymer bioconjugates [J]. Macromolecules,39:6376-6383.
(53)Mespouille L., Vachaudez M., Suriano F., et al.2007. One-pot synthesis of well-defined amphiphilic and adaptative block copolymers via versatile combination of "Click" chemistry and ATRP [J]. Macromolecular Rapid Communications,28:2151-2158.
(54)Geng J., Lindqvist J., Mantovani G., et al.2008. Simultaneous copper(Ⅰ)-catalyzed azide-alkyne cycloaddition (CuAAC) and living radical polymerization [J]. Angewandte Chemie-International Edition,47:4180-4183.
(55)Perrier S., Jackson S. G., Haddleton D. M., et al.2002. Preparation of fluorinated methacrylic copolymers by copper mediated living radical polymerization [J]. Tetrahedron,58:4053-4059.
(56)Butun V., Liu S., Weaver J. V. M., et al.2006. A brief review of'schizophrenic'block copolymers [J]. Reactive & Functional Polymers,66:157-165.
(57)Xu Y. L., Shi L. Q., Ma R. J., et al.2007. Synthesis and micellization of thermo-and pH-responsive block copolymer of poly (N-isopropylacrylamide)-block-poly(4-vinylpyridine) [J]. Polymer,48:1711-1717.
(58)Agut W., Brulet A., Taton D., et al.2007. Thermoresponsive micelles from jeffamine-b-poly(L-glutamic acid) double hydrophilic block copolymers [J]. Langmuir,23: 11526-11533.
(59)Rao J. Y., Luo Z. F., Ge Z. S., et al.2007. "Schizophrenic" micellization associated with coil-to-helix transitions based on polypeptide hybrid double hydrophilic rod-coil diblock copolymer [J]. Biomacromolecules,8:3871-3878.
(60)Cai C. H., Zhang L. S., Lin J. P., et al.2008. Self-assembly behavior of pH-and thermosensitive amphiphilic triblock copolymers in solution:Experimental studies and self-consistent field theory simulations [J]. Journal of Physical Chemistry B,112:12666-12673.
(61)Li J. G., Wang T., Wu D. L., et al.2008. Stimuli-Responsive Zwitterionic Block Copolypeptides:Poly(N-isopropylacrylamide)-block-poly(lysine-co-glutamic acid) [J]. Biomacromolecules,9:2670-2676.
(62)Zhang X. Q., Li J. G., Li W., et al.2007. Synthesis and characterization of thermo-and pH-responsive double-hydrophilic diblock copolypeptides [J]. Biomacromolecules,8:3557-3567.
(63)Schilli C. M., Zhang M. F., Rizzardo E., et al.2004. A new double-responsive block copolymer synthesized via RAFT polymerization: Poly(N-isopropylacrylamide)-block-poly(acrylic acid) [J]. Macromolecules,37:7861-7866.
(64)Zhang Y. F., Wu T. and Liu S. Y.2007. Micellization kinetics of a novel multi-responsive double hydrophilic diblock copolymer studied by stopped-flow pH and temperature jump [J]. Macromolecular Chemistry and Physics,208:2492-2501.
(65)Andre X., Zhang M. F. and Muller A. H. E.2005. Thermo-and pH-responsive micelles of poly(acrylic acid)-block-poly(N,N-diethylacrylamide) [J]. Macromolecular Rapid Communications,26:558-563.
(66)Zeng J. G., Shi K. Y., Zhang Y. Y., et al.2008. Construction and micellization of a noncovalent double hydrophilic block copolymer [J]. Chemical Communications,3753-3755.
(67)Arotcarena M., Heise B., Ishaya S., et al.2002. Switching the inside and the outside of aggregates of water-soluble block copolymers with double thermoresponsivity [J]. Journal of the American Chemical Society,124:3787-3793.
(68)Cai Y. L., Burguiere C. and Armes S. P.2004. Direct synthesis and aqueous solution properties of Y-shaped, stimulus-responsive block copolymer surfactants [J]. Chemical Communications,802-803.
(69)Xu J., Ge Z. S., Zhu Z. Y., et al.2006. Synthesis and micellization properties of double hydrophilic A(2)BA(2) and A(4)BA(4) non-linear block copolymers [J]. Macromolecules,39: 8178-8185.
(70)Rao J. Y., Zhang Y. F., Zhang J. Y., et al.2008. Facile Preparation of Well-Defined AB(2) Y-Shaped Miktoarm Star Polypeptide Copolymer via the Combination of Ring-Opening Polymerization and Click Chemistry [J]. Biomacromolecules,9:2586-2593.
(71)Ge Z. S., Cai Y. L., Yin J., et al.2007. Synthesis and'Schizophrenic'micellization of double hydrophilic AB(4) miktoarm star and AB diblock copolymers:Structure and kinetics of micellization [J]. Langmuir,23:1114-1122.
(72)Wang X. F., Zhang Y. F., Zhu Z. Y., et al.2008. Fabrication of fullerene-containing hybrid vesicles via supramolecular self-assembly of a well-defined amphiphilic block copolymer incorporated with a Single C-60 moiety at the diblock junction point [J]. Macromolecular Rapid Communications,29:340-346.
(73)Schlaad H.2006. Solution properties of polypeptide-based copolymers [J]. Advances in Polymer Science,202:53-73.
(74)Dimitrov I., Kukula H., Colfen H., et al.2004. Advances in the synthesis and characterization of polypeptide-based hybrid block copolymers [J]. Macromolecular Symposia,215:383-393.
(75)Lowik D. W. P. M., Ayres L., Smeenk J. M., et al.2006. Synthesis of bio-inspired hybrid polymers using peptide synthesis and protein engineering [J]. Advances in Polymer Science,202: 19-52.
(76)Deming T. J.2006. Polypeptide and polypeptide hybrid copolymer synthesis via NCA polymerization [J]. Advances in Polymer Science,202:1-18.
(77)Deming T. J.2007. Synthetic polypeptides for biomedical applications [J]. Progress in Polymer Science,32:858-875.
(78)Gauthier M. A. and Klok H. A.2008. Peptide/protein-polymer conjugates:synthetic strategies and design concepts [J]. Chemical Communications,2591-2611.
(79)Abraham S., Ha C. S. and Kim I.2006. Self-assembly of star-shaped polystyrene-block-polypeptide copolymers synthesized by the combination of atom transfer radical polymerization and ring-opening living polymerization of alpha-amino acid-N-carboxyanhydrides [J]. Journal of Polymer Science Part A-Polymer Chemistry,44: 2774-2783.
(1)Hu F. Q., Wei L., Zhou Z., et al.2006. Preparation of biocompatible magnetite nanocrystals for in vivo magnetic resonance detection of cancer [J]. Advanced Materials,18:2553-+.
(2)Haynes C. L. and Van Duyne R. P.2001. Nanosphere lithography:A versatile nanofabrication tool for studies of size-dependent nanoparticle optics [J]. Journal of Physical Chemistry B,105: 5599-5611.
(3)Walter E. C., Penner R. M., Liu H., et al.2002. Sensors from electrodeposited metal nanowires [J]. Surface and Interface Analysis,34:409-412.
(4)Chen X. Y. and Armes S. P.2003. Surface polymerization of hydrophilic methacrylates from ultrafine silica sols in protic media at ambient temperature:A novel approach to surface functionalization using a polyelectrolytic macroinitiator [J]. Advanced Materials,15:1558-1562.
(5)Chen X. Y, Armes S. P., Greaves S. I, et al.2004. Synthesis of hydrophilic polymer-grafted ultrafine inorganic oxide particles in protic media at ambient temperature via atom transfer radical polymerization:use of an electrostatically adsorbed polyelectrolytic macroinitiator [J]. Langmuir, 20:587-595.
(6)Wu K. H., Shin M., Yang C. C., et al.2006. Preparation and ferromagnetic properties of Ni0.5Fe2O4/polyaniline core-shell nanocomposites [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:2657-2664.
(7)Golden J. H., Deng H. B., Disalvo F. J., et al.1995. Monodisperse Metal-Clusters 10-Angstroms in Diameter in a Polymeric Host-the Monomer-as-Solvent Approach [J]. Science, 268:1463-1466.
(8)Alivisatos A. P.1996. Semiconductor clusters, nanocrystals, and quantum dots [J]. Science, 271:933-937.
(9)Daniel M. C. and Astruc D.2004. Gold nanoparticles:Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J]. Chemical Reviews,104:293-346.
(10)Qiao X. G., Chen M., Zhou J., et al.2007. Synthesis of raspberry-like silica/polystyrene/silica multilayer hybrid particles via miniemulsion polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:1028-1037.
(11)Garcia I., Zafeiropoulos N. E., Janke A., et al.2007. Functional ization of iron oxide magnetic nanoparticles with poly(methyl methacrylate) brushes via grafting-from atom transfer radical polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:925-932.
(12)Gravano S. M., Dumas R., Liu K., et al.2005. Methods for the surface functionalization of gamma-Fe2O3 nanoparticles with initiators for atom transfer radical polymerization and the formation of core-shell inorganic-polymer structures [J]. Journal of Polymer Science Part a-Polymer Chemistry,43:3675-3688.
(13)Montagne F., Mondain-Monval O., Pichot C., et al.2006. Highly magnetic latexes from submicrometer oil in water ferrofluid emulsions [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:2642-2656.
(14)Pyun J. and Matyjaszewski K.2001. Synthesis of nanocomposite organic/inorganic hybrid materials using controlled/"living" radical polymerization [J]. Chemistry of Materials,13: 3436-3448.
(15)Zhang H., Wang C. L., Li M. J., et al.2005. Fluorescent nanocrystal-polymer complexes with flexible processability [J]. Advanced Materials,17:853-857.
(16)Brennan J. L., Hatzakis N. S., Tshikhudo T. R., et al.2006. Bionanoconjugation via click chemistry:The creation of functional hybrids of lipases and gold nanoparticles [J]. Bioconjugate Chemistry,17:1373-1375.
(17)Luo S. Z., Xu J., Zhang Y. F., et al.2005. Double hydrophilic block copolymer monolayer protected hybrid gold nanoparticles and their shell cross-linking [J]. Journal of Physical Chemistry B,109:22159-22166.
(18)Xu H. X.,-Xu J., Jiang X. Z., et al.2007. Thermosensitive unimolecular micelles surface-decorated with gold nanoparticles of tunable spatial distribution [J]. Chemistry of Materials,19:2489-2494.
(19.)Kotal A., Mandal T. K. and Walt D. R.2005. Synthesis of gold-poly(methyl methacrylate) core-shell nanoparticles by surface-confined atom transfer radical polymerization at elevated temperature [J]. Journal of Polymer Science Part a-Polymer Chemistry,43:3631-3642.
(20)Prucker O. and Ruhe J.1998. Synthesis of poly(styrene) monolayers attached to high surface area silica gels through self-assembled monolayers of azo initiators [J]. Macromolecules,31: 592-601.
(21)Prucker O. and Ruhe J.1998. Mechanism of radical chain polymerizations initiated by azo compounds covalently bound to the surface of spherical particles [J]. Macromolecules,31: 602-613.
(22)Pyun J., Kowalewski T. and Matyjaszewski K.2003. Synthesis of polymer brushes using atom transfer radical polymerization [J]. Macromolecular Rapid Communications,24:1043-1059.
(23)Ohno K., Morinaga T., Koh K., et al.2005. Synthesis of monodisperse silica particles coated with well-defined, high-density polymer brushes by surface-initiated atom transfer radical polymerization [J]. Macromolecules,38:2137-2142.
(24)von Werne T. and Patten T. E.1999. Preparation of structurally well-defined polymer-nanoparticle hybrids with controlled/living radical polymerizations [J]. Journal of the American Chemical Society,121:7409-7410.
(25)von Werne T. and Patten T. E.2001. Atom transfer radical polymerization from nanoparticles: A tool for the preparation of well-defined hybrid nanostructures and for understanding the chemistry of controlled/"living" radical polymerizations from surfaces [J]. Journal of the American Chemical Society,123:7497-7505.
(26)Kim K. M., Keum D. K. and Chujo Y.2003. Organic-inorganic polymer hybrids using polyoxazoline initiated by functionalized silsesquioxane [J]. Macromolecules,36:867-875.
(27)Mori H., Seng D. C., Zhang M. E, et al.2002. Hybrid nanoparticles with hyperbranched polymer shells via self-condensing atom transfer radical polymerization from silica surfaces [J], Langmuir,18:3682-3693.
(28)Carrot G, Rutot-Houze D., Pottier A., et al.2002. Surface-initiated ring-opening polymerization:A versatile method for nanoparticle ordering [J]. Macromolecules,35:8400-8404.
(29)Bartholome C., Beyou E., Bourgeat-Lami E., et al.2003. Nitroxide-mediated polymerizations from silica nanoparticle surfaces:"Graft from" polymerization of styrene using a triethoxysilyl-terminated alkoxyamine initiator [J]. Macromolecules,36:7946-7952.
(30)Perruchot C., Khan M. A., Kamitsi A., et al.2001. Synthesis of well-defined, polymer-grafted silica particles by aqueous ATRP [J]. Langmuir,17:4479-4481.
(31)Li C. Z. and Benicewicz B. C.2005. Synthesis of well-defined polymer brushes grafted onto silica nanoparticles via surface reversible addition-fragmentation chain transfer polymerization [J]. Macromolecules,38:5929-5936.
(32)Li D. J., Jones G. L., Dunlap J. R., et al.2006. Thermosensitive hairy hybrid nanoparticles synthesized by surface-initiated atom transfer radical polymerization [J]. Langmuir,22: 3344-3351.
(33)Parvole J., Laruelle G, Guimon C., et al.2003. Initiator-grafted silica particles for controlled free radical polymerization:Influence of the initiator structure on the grafting density [J]. Macromolecular Rapid Communications,24:1074-1078.
(34)Ueda J., Yamaguchi H., Yamauchi T., et al.2007. Radical graft polymerization of vinyl monomers onto nanoparticles in ionic liquid initiated by azo groups introduced onto the surface [J]. Journal of Polymer Science Part a-Polymer Chemistry,45:1143-1149.
(35)Ramakrishnan A., Dhamodharan R. and Ruhe J.2006. Growth of poly(methyl methacrylate) brushes on silicon surfaces by atom transfer radical polymerization [J]. Journal of Polymer Science Part a-Polymer Chemistry,44:1758-1769.
(36)Mansky P., Liu Y., Huang E., et al.1997. Controlling polymer-surface interactions with random copolymer brushes [J]. Science,275:1458-1460.
(37)Lindenblatt G, Schartl W., Pakula T., et al.2000. Synthesis of polystyrene-grafted polyorganosiloxane microgels and their compatibility with linear polystyrene chains [J]. Macromolecules,33:9340-9347.
(38)Ranjan R. and Brittain W. J.2007. Combination of Living Radical Polymerization and Click Chemistry for Surface Modification [J]. Macromolecules,40:6217-6223.
(39)Zhu M. Q., Wang L. Q., Exarhos G. J., et al.2004. Thermosensitive gold nanoparticles [J]. Journal of the American Chemical Society,126:2656-2657.
(40)Zhao B. and Brittain W. J.2000. Polymer brushes:surface-immobilized macromolecules [J]. Progress in Polymer Science,25:677-710.
(41)Koh K., Ohno K., Tsujii Y, et al.2003. Precision synthesis of organic/inorganic hybrid nanocapsules with a silanol-functionalized micelle template [J]. Angewandte Chemie-International Edition in English,42:4194-4197.
(42)Du J. Z. and Chen Y. M.2004. Organic-inorganic hybrid nanoparticles with a complex hollow structure [J]. Angewandte Chemie-International Edition in-English,43:5084-5087.
(43)Du J. Z. and Chen Y. M.2004. Atom-transfer radical polymerization of a reactive monomer: 3-(Trimethoxysilyl)propyl methacrylate [J]. Macromolecules,37:6322-6328.
(44)Du J. Z. and Chen Y. M.2004. Organic-inorganic hybrid nanoparticles with a complex hollow structure [J]. Angewandte Chemie-International Edition,43:5084-5087.
(45)Du J. Z. and Chen Y. M.2005. Hairy nanospheres by gelation of reactive block copolymer micelles [J]. Macromolecular Rapid Communications,26:491-494.
(46)Chen Y. M., Du J. Z., Xiong M., et al.2006. Gelation inside block copolymer aggregates and organic/inorganic nanohybrids [J]. Macromolecular Rapid Communications,27:741-750.
(47)Ionov L., Sapra S., Synytska A., et al.2006. Fast and spatially resolved environmental probing using stimuli-responsive polymer layers and fluorescent nanocrystals [J]. Advanced Materials,18:1453-1457.
(48)Willner I., Basnar B. and Willner B.2007. From molecular machines to microscale motility of objects:Application as "smart materials", sensors, and nanodevices [J]. Advanced Functional Materials,17:702-717.
(49)Barbosa P. C., Silva M. M., Smith M. J., et al.2007. Studies of solid-state electrochromic devices based on PEO/siliceous hybrids doped with lithium perchlorate [J]. Electrochimica Acta, 52:2938-2943.
(50)Lecommandoux S., Sandre O., Checot F., et al.2006. Smart hybrid magnetic self-assembled micelles and hollow capsules [J]. Progress in Solid State Chemistry,34:171-179.
(51)Li J., Liu B. and Li J. H.2006. Controllable self-assembly of CdTe/poly(N-isopropylacrylamide acrylic acid) microgels in response to pH stimuli [J]. Langmuir, 22:528-531.
(52)Sanchez C., Julian B., Belleville P., et al.2005. Applications of hybrid organic-inorganic nanocomposites [J]. Journal of Materials Chemistry,15:3559-3592.
(53)Zhu P. W. and Napper D. H.1994. Entanglement Knotting in Globule-to-Coil Transitions of Poly(N-Isopropyacrylamide) at Interfaces [J]. Journal of Colloid and Interface Science,168: 380-385.
(54)Zhu P. W. and Napper D. H.1994. Studies of Aggregation Kinetics of Polystyrene Latices Sterically Stabilized by Poly(N-Isopropylacrylamide) [J].Physical Review E,50:1360-1366.
(55)Zhu P. W. and Napper D. H.1994. Experimental-Observation of Coil-to-Globule Type Transitions at Interfaces [J]. Journal of Colloid and Interface Science,164:489-494.
(56)Zhao J., Shan J., Van Assche G., et al.2009. Demixing and Remixing Kinetics in Aqueous Dispersions of Poly(N-isopropylacrylamide) (PNIPAM) Brushes Bound to Gold Nanoparticles Studied by Means of Modulated Temperature Differential Scanning Calorimetry [J]. Macromolecules,42:5317-5327.
(57)Rezende C. A., Shan J., Lee L. T., et al.2009. Tuning the Structure of Thermosensitive Gold Nanoparticle Monolayers [J]. Journal of Physical Chemistry B,113:9786-9794.
(58)Shan J. and Tenhu H.2007. Recent advances in polymer protected gold nanoparticles: synthesis, properties and applications [J]. Chemical Communications,4580-4598.
(59)Raula J., Shan J., Nuopponen M., et al.2003. Synthesis of gold nanoparticles grafted with a thermoresponsive polymer by surface-induced reversible-addition-fragmentation chain-transfer polymerization [J]. Langmuir,19:3499-3504.
(60)Du J. Z. and Armes S. P.2005. pH-responsive vesicles based on a hydrolytically self-cross-linkable copolymer [J]. Journal of the American Chemical Society,127:12800-12801.
(61)Butun V., Billingham N. C. and Armes S. P.1997. Synthesis and aqueous solution properties of novel hydrophilic-hydrophilic block copolymers based on tertiary amine methacrylates [J]. Chemical Communications,671-672.
(62)Butun V., Billingham N. C. and Armes S. P.1998. Unusual aggregation behavior of a novel tertiary amine methacrylate-based diblock copolymer:Formation of micelles and reverse micelles in aqueous solution [J]. Journal of the American Chemical Society,120:11818-11819.
(63)Vamvakaki M., Billingham N. C. and Armes S. P.1999. Synthesis of controlled structure water-soluble diblock copolymers via oxyanionic polymerization [J]. Macromolecules,32: 2088-2090.
(64)Vamvakaki M:, Unali G. F., Butun V, et al.2001. Effect of partial quaternization on the aqueous solution properties of tertiary amine-based polymeric surfactants:Unexpected separation of surface activity and cloud point behavior [J]. Macromolecules,34:6839-6841.
(65)Butun V., Armes S. P. and Billingham N. C.2001. Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers [J]. Polymer,42:5993-6008.
(66)Xu J., Luo S. Z., Shi W. E, et al.2006. Two-stage collapse of unimolecular micelles with double thermoresponsive coronas [J]. Langmuir,22:989-997.
(67)Rungsardthong U., Deshpande M., Bailey L., et al.2001. Copolymers of amine methacrylate with poly(ethylene glycol) as vectors for gene therapy [J]. Journal of Controlled Release,73: 359-380.
(68)Licciardi M., Tang Y., Billingham N. C., et al.2005. Synthesis of novel folic acid-functionalized biocompatible block copolymers by atom transfer radical polymerization for gene delivery and encapsulation of hydrophobic drugs [J]. Biomacromolecules,6:1085-1096.
(69)Xie J.; Xu C., Kohler N., et al.2007. Controlled PEGylation of monodisperse Fe3O4 nanoparticles for reduced non-specific uptake by macrophage cells [J]. Advanced Materials,19: 3163-+.
(70)Wan S. R., Zheng Y., Liu Y. Q., et al.2005. Fe3O4 nanoparticles coated with homopolymers of glycerol mono(meth) acrylate and their block copolymers [J]. Journal of Materials Chemistry, 15:3424-3430.
(71)Guo M., Yan Y., Zhang H. K., et al.2008. Magnetic and pH-responsive nanocarriers with multilayer core-shell architecture for anticancer drug delivery [J]. Journal of Materials Chemistry, 18:5104-5112.
(72)Si S., Kotal A., Mandal T. K., et al.2004. Size-controlled synthesis of magnetite nanoparticles in the presence of polyelectrolytes [J]. Chemistry of Materials,16:3489-3496.
(73)Euliss L. E., Grancharov S. G., O'Brien S., et al.2003. Cooperative assembly of magnetic nanoparticles and block copolypeptides in aqueous media [J]. Nano Letters,3:1489-1493.
(74)Ai H., Flask C., Weinberg B., et al.2005. Magnetite-loaded polymeric micelles as ultrasensitive magnetic-resonance probes [J]. Advanced Materials,17:1949-+.
(75)Sanchez-Gaytan B. L., Cui W. H., Kim Y. J., et al.2007. Interfacial assembly of nanoparticles in discrete block-copolymer aggregates [J]. Angewandte Chemie-International Edition,46: 9235-9238.
(76)Wang X. E, Zhang Y F.; Zhu Z. Y, et al.2008. Fabrication of fullerene-containing hybrid vesicles via supramolecular self-assembly of a well-defined amphiphilic block copolymer incorporated with a Single C-60 moiety at the diblock junction point [J]. Macromolecular Rapid Communications,29:340-346.
(77)Lee H., Lee B. P. and Messersmith P. B.2007. A reversible wet/dry adhesive inspired by mussels and geckos [J]. Nature,448:338-U334.
(78)Xu J., Ye J. and Liu S. Y.2007. Synthesis of well-defined cyclic poly(N-isopropylacrylamide) via click chemistry and its unique thermal phase transition behavior [J]. Macromolecules,40: 9103-9110.