活化过硫酸盐处理酚类废水的研究进展
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摘要
综述了过渡金属活化、活性炭及含碳材料活化、UV活化、热活化以及复合活化等方法的研究进展,论述不同活化方法对酚类废水处理的效果及优劣,并探讨了反应影响因素及存在的问题。提出结合酚类废水特性探究反应机理、选取合适活化方法、开发新型催化剂、优化工艺条件、展开环境影响评价等都将是过硫酸盐高级氧化技术未来发展的方向。
The research progress of transition metal activation,carbon activation,UV activation,thermal activation and composite activation are summarized.The effects and advantages of different activation methods on phenolic wastewater treatment are discussed.The influencing factors and problems are discussed.It is proposed that the future development direction of persulfate advanced oxidation technology is to explore reaction mechanism,select appropriate activation method,develop new catalyst,optimize process conditions and carry out environmental impact assessment.
The research progress of transition metal activation,carbon activation,UV activation,thermal activation and composite activation are summarized.The effects and advantages of different activation methods on phenolic wastewater treatment are discussed.The influencing factors and problems are discussed.It is proposed that the future development direction of persulfate advanced oxidation technology is to explore reaction mechanism,select appropriate activation method,develop new catalyst,optimize process conditions and carry out environmental impact assessment.
引文
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[3] Tian S C,Zhang Z H.Photo-electrochemical oxidation of hypophosphite and phosphorous recovery by UV/Fe2+/peroxydisulfate with electrochemical process[J].Chemical Engineering Journal,2019,359:1075-1085.
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[13] 史宸菲,贾淑敏,李雨濛,等.水稻秸秆生物炭-过硫酸盐去除水中p-硝基酚[J].化工环保,2017,37(6):632-637.
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[17] Guan C T,Jiang J,Luo C W,et al.Oxidation of bromophenols by carbon nanotube activated peroxymonosulfate (PMS) and formation of brominated products:Comparison to peroxydisulfate (PDS)[J].Chemical Engineering Journal,2018,337:40-50.
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[22] 侯先宇,陈炜鸣,李启彬,等.微波活化过硫酸盐耦合混凝处理二硝基重氮酚工业废水[J].中国环境科学,2018,38(12):4551-4558.
[23] Shun H Y,Chang M C,Tsai M K.Degradation and mineralization of Bisphenol A in wastewater by the UV/H2O2 and UV/persulfate processes[J].Desalination and Water Treatment,2017,61:68-81.
[24] Akbar E,Marjan H,Farshid G.Degradation of 4-chlorophenol using catalyzed peroxymonosulfate with nano-MnO2/UV irradiation:Toxicity assessment and evaluation for industrial wastewater treatment[J].Journal of Cleaner Production,2018,195:1389-1397.
[25] Li Q,Wang L F,Zhang L,et al.Rapid degradation of tetrabromobisphenol A under the UV/TiO2/KPS systems in alkaline aqueous solutions[J].Research on Chemical Intermediates,2019,45:757-768.
[26] Shang K,Wang H,Li J,et al.Activation of peroxydisulfate by gas-liquid pulsed discharge plasma to enhance the degradation of p-nitrophenol[J].Plasma Science and Technology,2017,19(6):122-129.
[27] Jiang M,Lu J,Ji Y,et al.Bicarbonate-activated persulfate oxidation of acetaminophen[J].Water Research,2017,116:324-331.
[28] Aseev D G,Batoeva A A,Sizykh M R,et al.Sono-photocatalytic degradation of 4-chlorophenolin aqueous solutions[J].Russian Journal of Physical Chemistry A,2018,92(6):1813-1819.
[29] Takdastana A,Kakavandic B,Azizib M,et al.Efficient activation of peroxymonosulfate by using ferroferric oxide supported on carbon/UV/US system:A new approach into catalytic degradation of bisphenol A[J].Chemical Engineering Journal,2018,331:729-743.
[30] Park S M,Lee S W,Jeon P Y,et al.Iron anode-mediated activation of persulfate[J].Water Air & Soil Pollution,2016,227(12):462-469.
[31] Luo C W,Gao J,Wu D J,et al.Oxidation of 2,4-bromophenol by UV/PDS and formation of bromate and brominated products:A comparison to UV/H2O2[J].Chemical Engineering Journal,2019,358:1342-1350.
[32] 李一凡,王应军,廖鑫.CuO/Ac催化过硫酸盐对模拟废水中苯酚的降解效果[J].环境科学研究,2018,31(11):1949-1956.
[33] 刘阔,金浩,董为,等.钴活化过一硫酸盐氧化过程中卤代副产物的生成[J].环境科学,2016,37(5):1823-1830.
[34] Deng J,Shao Y,Gao N,et al.Zero-valent iron/persulfate(Fe0/PS)oxidation acetaminophen in water[J].International Journal of Environmental Science & Technology,2014,11(4):881-890.
[2] Wang Z Y,Shao Y S,Gao N Y,et al.Degradation kinetic of phthalate esters and the formation of brominated byproducts in heat-activated persulfate system[J].Chemical Engineering Journal,2019,359:1086-1096.
[3] Tian S C,Zhang Z H.Photo-electrochemical oxidation of hypophosphite and phosphorous recovery by UV/Fe2+/peroxydisulfate with electrochemical process[J].Chemical Engineering Journal,2019,359:1075-1085.
[4] Gu Na,Wu Y,Gao J,et al.Microcystis aeruginosa removal by in situ chemical oxidation using persulfate activated by Fe2+ ions[J].Ecological Engineering,2017,99:290-297.
[5] 赵文莉,王广智,弋凡,等.过硫酸盐活化技术的研究进展[J].现代化工,2018,38(7):53-56.
[6] Guerra-Rodriguez S,Rodriguez E,Singh D N,et al.Assessment of sulfate radical-based advanced oxidation processes for water and wastewater treatment:A review[J].Water,2018,10(12):1828-1848.
[7] Huang Y,Huang Y.Behavioral evidence of the dominant radicals and intermediates involved in Bisphenol A degradation using an efficient Co2+/PMS oxidation process[J].Journal of Hazardous Materials,2009,167(1/2/3):418-426.
[8] Xia D,Yin R,Sun J,et al.Natural magnetic pyrrhotite as a high——Efficient persulfate activator for micropollutants degradation:Radicals identification and toxicity evaluation[J].Journal of Hazardous Materials,2017,340:435-444.
[9] Ma Q Q,Cui L,Zhou S,et al.Iron nanoparticles in situ encapsulated in lignin-derived hydrochar as an effective catalyst for phenol removal[J].Environmental Science and Pollution Research,2018,25:20833-20840.
[10] Ali R R,Ali P,Fahime Z,et al.Activated persulfate by chelating agent Fe/complex for in situ degradation of phenol:intermediate identification and optimization study[J].Research on Chemical Intermediates,2018,44:5501-5519.
[11] Peng W,Liu J,Li C,et al.A multipath peroxymonosulfate activation process over supported by magnetic CuO-Fe3O4 nanoparticles for efficient degradation of 4-chlorophenol[J].Korean Journal of Chemical Engineering,2018,35(8):1662-1672.
[12] 张昊楠,唐海,沙俊鹏,等.热辅助CuO/ZSM-5活化过硫酸盐降解苯酚废水研究[J].化工新型材料,2017,45(3):186-189.
[13] 史宸菲,贾淑敏,李雨濛,等.水稻秸秆生物炭-过硫酸盐去除水中p-硝基酚[J].化工环保,2017,37(6):632-637.
[14] Liu C M,Diao Z H,Huo W Y,et al.Simultaneous removal of Cu2+ and bisphenol A by a novel biochar-supported zero valent iron from aqueous solution:Synthesis,reactivity and mechanism[J].Environmental Pollution,2018,239:698-705.
[15] Duan X,Sun H,Tade M,et al.Metal-free activation of persulfate by cubic mesoporous carbons for catalytic oxidation via radical and nonradical processes[J].Catalysis Today,2017,307(6):140-146.
[16] Xu X Y,Qin J Y,Wei Y,et al.Heterogeneous activation of persulfate by NiFe2-xCoxO4-RGO for oxidative degradation of bisphenol A in water[J].Chemical Engineering Journal,2019,365:259-269.
[17] Guan C T,Jiang J,Luo C W,et al.Oxidation of bromophenols by carbon nanotube activated peroxymonosulfate (PMS) and formation of brominated products:Comparison to peroxydisulfate (PDS)[J].Chemical Engineering Journal,2018,337:40-50.
[18] 刘国强,王斌楠,廖云燕,等.热活化过硫酸盐降解水中的2-氯苯酚[J].环境化学,2014,33(8):1396-1403.
[19] Ma J,Li H Y,Chi L P,et al.Changes in activation energy and kinetics of heat-activated persulfate oxidation of phenol in response to changes in pH and temperature[J].Chemosphere,2017,189:86-93.
[20] Wang Q,Lu X H,Cao Y,et al.Degradation of Bisphenol S by heat activated persulfate:Kinetics study,transformation pathways and influences of co-existing chemicals[J].Chemical Engineering Journal,2017,328:236-245.
[21] Qi C,Liu X,Lin C,et al.Activation of peroxymonosulfate by microwave irradiation for degradation of organic contaminants[J].Chemical Engineering Journal,2017,315:201-209.
[22] 侯先宇,陈炜鸣,李启彬,等.微波活化过硫酸盐耦合混凝处理二硝基重氮酚工业废水[J].中国环境科学,2018,38(12):4551-4558.
[23] Shun H Y,Chang M C,Tsai M K.Degradation and mineralization of Bisphenol A in wastewater by the UV/H2O2 and UV/persulfate processes[J].Desalination and Water Treatment,2017,61:68-81.
[24] Akbar E,Marjan H,Farshid G.Degradation of 4-chlorophenol using catalyzed peroxymonosulfate with nano-MnO2/UV irradiation:Toxicity assessment and evaluation for industrial wastewater treatment[J].Journal of Cleaner Production,2018,195:1389-1397.
[25] Li Q,Wang L F,Zhang L,et al.Rapid degradation of tetrabromobisphenol A under the UV/TiO2/KPS systems in alkaline aqueous solutions[J].Research on Chemical Intermediates,2019,45:757-768.
[26] Shang K,Wang H,Li J,et al.Activation of peroxydisulfate by gas-liquid pulsed discharge plasma to enhance the degradation of p-nitrophenol[J].Plasma Science and Technology,2017,19(6):122-129.
[27] Jiang M,Lu J,Ji Y,et al.Bicarbonate-activated persulfate oxidation of acetaminophen[J].Water Research,2017,116:324-331.
[28] Aseev D G,Batoeva A A,Sizykh M R,et al.Sono-photocatalytic degradation of 4-chlorophenolin aqueous solutions[J].Russian Journal of Physical Chemistry A,2018,92(6):1813-1819.
[29] Takdastana A,Kakavandic B,Azizib M,et al.Efficient activation of peroxymonosulfate by using ferroferric oxide supported on carbon/UV/US system:A new approach into catalytic degradation of bisphenol A[J].Chemical Engineering Journal,2018,331:729-743.
[30] Park S M,Lee S W,Jeon P Y,et al.Iron anode-mediated activation of persulfate[J].Water Air & Soil Pollution,2016,227(12):462-469.
[31] Luo C W,Gao J,Wu D J,et al.Oxidation of 2,4-bromophenol by UV/PDS and formation of bromate and brominated products:A comparison to UV/H2O2[J].Chemical Engineering Journal,2019,358:1342-1350.
[32] 李一凡,王应军,廖鑫.CuO/Ac催化过硫酸盐对模拟废水中苯酚的降解效果[J].环境科学研究,2018,31(11):1949-1956.
[33] 刘阔,金浩,董为,等.钴活化过一硫酸盐氧化过程中卤代副产物的生成[J].环境科学,2016,37(5):1823-1830.
[34] Deng J,Shao Y,Gao N,et al.Zero-valent iron/persulfate(Fe0/PS)oxidation acetaminophen in water[J].International Journal of Environmental Science & Technology,2014,11(4):881-890.