矿物颗粒度对粉末颜色的影响
|
摘要
当一种有色材料被研磨后,在某些情况下被研磨成的粉末会呈现出与原有材料不同的颜色。运用控制变量法,仅对微米级别的有色材料进行研磨,并结合Mie散射理论探究在研磨前后其颜色的变化规律,并以明度(亮度)、色调(色相)、饱和度(纯度)定义颜色。选取4种不同颜色的材料,分别为色光三原色中的红色材料Fe2O3、绿色材料Cu2(OH)2CO3、明度最高的白色材料Zr SiO4以及明度最低的黑色材料Fe3O4。结果表明,对于微米级别的矿物颗粒,粒度越小,粉末的明度也就越高,而其色调和饱和度基本保持不变。
When a colored material is ground,in some cases the ground powder will exhibit a different color than the original material. In this paper,we use the control variable method to grind only the micronsized colored materials,and combine the Mie scattering theory to explore the color change before and after grinding,and define it by brightness,hue and saturation. A total of four different color materials were selected,namely red material Fe2 O3,green material Cu2(OH)2 CO3,white material Zr SiO4 with the brightest brightness and Fe3 O4 with the lowest brightness. The results show that for micronsized mineral particles: the smaller the particle size,the higher the brightness of the powder,while the hue and saturation remain essentially unchanged.
When a colored material is ground,in some cases the ground powder will exhibit a different color than the original material. In this paper,we use the control variable method to grind only the micronsized colored materials,and combine the Mie scattering theory to explore the color change before and after grinding,and define it by brightness,hue and saturation. A total of four different color materials were selected,namely red material Fe2 O3,green material Cu2(OH)2 CO3,white material Zr SiO4 with the brightest brightness and Fe3 O4 with the lowest brightness. The results show that for micronsized mineral particles: the smaller the particle size,the higher the brightness of the powder,while the hue and saturation remain essentially unchanged.
引文
[1] LAI Xin-min,PENG Lin-fa,HU Peng,et al. Material Bebhavior modelling in micro/meso-scale forming process with considering size/scale effects[J]. Computational Materials Science,2008,43(4):1003-1009.
[2] PENG Lin-fa,LAI Xin-min,LEE H J,et al. Analysis of micro/mesoscale sheet forming process with uniform size dependent material constitutive model[J]. Materials Science and Engineering:A,2009,526(1-2):93-99.
[3] Kelly K L,Coronado E,Zhao L L,et al. The 0ptical properties of metal nanoparticles:The influence of size,shape,and dielectric environment[J]. The Journal of Physical Chemistry B,2003,107(3):668-677.
[4] Delacourt C,Poizot P,Levasseur S,et al. Size effects on carbonfree Li Fe PO powders[J]. Electrochemical and Solid-State Letters,2006,9(7):A352.
[5] Vandenbroucke B, Kruth Jean P. Selective laser melting of biocompatible metals for rapid manufacturing of medical parts[J].Rapid Prototyping Journal,2007,13(4):196-203.
[6] Chelazzi D,Poggi G,Jaidar Y,et al. Hydroxide nanoparticles for cultural heritage:consolidation and protection of wall paintings and carbonate materials[J]. Journal of Colloid and Interface Science,2013,392:42-49.
[7] Bang J H,Kenneth S. Suslick. Applications of ultrasound to the synthesis of nanostructured materials[J]. Advanced Materials,2010,22(10):1039-1059.
[8] Wilkinson C. D. W,Riehle M,Wood M,et al. The use of materials patterned on a nano-and micro-metric scale in cellular engineering[J]. Materials Science and Engineering:C,2002,19(1-2):263-269.
[9] Gordon D J, Holzwarth G. Optical activity of membrane suspensions:Calculation of artifacts by Mie scattering theory[J].Proceedings of the National Academy of Sciences,1971,68(10):2365-2369.
[10] Ware C. Color sequences for univariate maps:theory,experiments and principles[J]. IEEE Computer Graphics and Applications,1988,8(5):41-49.
[11] Mikhailov M M,Vlasov V A. A size effect in the optical properties of powdered Ti O2[J]. Russian Physics Journal,1998,41(12):1222-1228.
[12] Melamed N T. Optical properties of powders. Part I. optical absorption coefficients and the absolute value of the diffuse reflectance. Part II. properties of luminescent powders[J]. Journal of Applied Physics,1963,34(3):560-570.
[13]高田利夫．酸化鉄(Fe2O3)の色調に及ぼす粒子形態の影響に就いて[J]．粉体および粉末冶金，1958(4):160-168.
[14]张瑾瑾，王志法，张行健，等．高能球磨工艺对Mo颗粒尺寸的影响[J]．中国钼业，2005,29(1):28-30.
[15] Mie G. Beitrge zur Optik trüber Medien, speziell kolloidaler Metall? sungen[J]. Annalen der physik, 1908, 330(3):377-445.
[16]李召好，李法强，马培华．超细粉末团聚机理及其消除方法[J]．盐湖研究，2005,13(1):31-36.
[17]荆其城，焦书兰，哈柏林等．色度学[M]．北京:科学出版社，1979:3-84.
[18]戴兵，罗向东，王亚伟．椭圆截面非球形颗粒群的多重光散射[J]．物理学报，2009,58(6):3864-3869.
[19]王亚伟．光散射理论及其应用技术[M]．北京:科学出版社，2013:27-49,86-109.
[20]卜敏．血液细胞逼近模型及其光散射特征的研究[D]．镇江:江苏大学，2011:25-27.
[2] PENG Lin-fa,LAI Xin-min,LEE H J,et al. Analysis of micro/mesoscale sheet forming process with uniform size dependent material constitutive model[J]. Materials Science and Engineering:A,2009,526(1-2):93-99.
[3] Kelly K L,Coronado E,Zhao L L,et al. The 0ptical properties of metal nanoparticles:The influence of size,shape,and dielectric environment[J]. The Journal of Physical Chemistry B,2003,107(3):668-677.
[4] Delacourt C,Poizot P,Levasseur S,et al. Size effects on carbonfree Li Fe PO powders[J]. Electrochemical and Solid-State Letters,2006,9(7):A352.
[5] Vandenbroucke B, Kruth Jean P. Selective laser melting of biocompatible metals for rapid manufacturing of medical parts[J].Rapid Prototyping Journal,2007,13(4):196-203.
[6] Chelazzi D,Poggi G,Jaidar Y,et al. Hydroxide nanoparticles for cultural heritage:consolidation and protection of wall paintings and carbonate materials[J]. Journal of Colloid and Interface Science,2013,392:42-49.
[7] Bang J H,Kenneth S. Suslick. Applications of ultrasound to the synthesis of nanostructured materials[J]. Advanced Materials,2010,22(10):1039-1059.
[8] Wilkinson C. D. W,Riehle M,Wood M,et al. The use of materials patterned on a nano-and micro-metric scale in cellular engineering[J]. Materials Science and Engineering:C,2002,19(1-2):263-269.
[9] Gordon D J, Holzwarth G. Optical activity of membrane suspensions:Calculation of artifacts by Mie scattering theory[J].Proceedings of the National Academy of Sciences,1971,68(10):2365-2369.
[10] Ware C. Color sequences for univariate maps:theory,experiments and principles[J]. IEEE Computer Graphics and Applications,1988,8(5):41-49.
[11] Mikhailov M M,Vlasov V A. A size effect in the optical properties of powdered Ti O2[J]. Russian Physics Journal,1998,41(12):1222-1228.
[12] Melamed N T. Optical properties of powders. Part I. optical absorption coefficients and the absolute value of the diffuse reflectance. Part II. properties of luminescent powders[J]. Journal of Applied Physics,1963,34(3):560-570.
[13]高田利夫．酸化鉄(Fe2O3)の色調に及ぼす粒子形態の影響に就いて[J]．粉体および粉末冶金，1958(4):160-168.
[14]张瑾瑾，王志法，张行健，等．高能球磨工艺对Mo颗粒尺寸的影响[J]．中国钼业，2005,29(1):28-30.
[15] Mie G. Beitrge zur Optik trüber Medien, speziell kolloidaler Metall? sungen[J]. Annalen der physik, 1908, 330(3):377-445.
[16]李召好，李法强，马培华．超细粉末团聚机理及其消除方法[J]．盐湖研究，2005,13(1):31-36.
[17]荆其城，焦书兰，哈柏林等．色度学[M]．北京:科学出版社，1979:3-84.
[18]戴兵，罗向东，王亚伟．椭圆截面非球形颗粒群的多重光散射[J]．物理学报，2009,58(6):3864-3869.
[19]王亚伟．光散射理论及其应用技术[M]．北京:科学出版社，2013:27-49,86-109.
[20]卜敏．血液细胞逼近模型及其光散射特征的研究[D]．镇江:江苏大学，2011:25-27.