微生物对低品位铝土矿生物浸矿的应用潜力
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摘要
目前,对中低品位铝土矿的利用主要依赖于对传统炼铝工艺及传统选矿工艺的改进。该文在综述微生物在中低品位铝土矿中的运用研究进展,主要集中在微生物对中低品位铝土矿的生物脱硅及生物浸铝,并分析了其作用机制,揭示了利用微生物(细菌和真菌)对铝土矿进行生物脱硅或生物浸铝具有理论和实际可行性,并可对传统炼铝工业形成有效补充。在此基础上,探讨微生物在中低品位铝土矿脱硅及浸铝运用中面临的困难,并逐一展开讨论相应的解决方案,对微生物在中低品位铝土矿中的运用提供参考。
At present,low grade bauxite ores is mainly used by some improved aluminium smelting process and bauxite beneficiation process. Here,the research status of biological desilication and bioleaching of low grade bauxite ores mediated by microbe is summarized and their mechanisms is discussed. There are theoretical and practical feasibility in biological desilication and bioleaching in low grade bauxite ores by using microbe( bacteria or fungi). Based on these,it suggested that the biological desilication and bioleaching show considerable potential in using of low grade bauxite ores and make an excellent complement to the traditional aluminium smelting process. At last,the challenges and solutions is discussed to improve this new strategy for usage of low grade bauxite ores.
At present,low grade bauxite ores is mainly used by some improved aluminium smelting process and bauxite beneficiation process. Here,the research status of biological desilication and bioleaching of low grade bauxite ores mediated by microbe is summarized and their mechanisms is discussed. There are theoretical and practical feasibility in biological desilication and bioleaching in low grade bauxite ores by using microbe( bacteria or fungi). Based on these,it suggested that the biological desilication and bioleaching show considerable potential in using of low grade bauxite ores and make an excellent complement to the traditional aluminium smelting process. At last,the challenges and solutions is discussed to improve this new strategy for usage of low grade bauxite ores.
引文
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[3]Qinghua Lu,Yuehua Hu,Meng Wang.Photocatalytic activity of bauxite-tailings supported nano-Ti O2[J].Journal of Central South University of Technology,2010,17(4):755-759.
[4]Yaqin Zhang,Lei He,Aihua Ma,et al.CaO-based sorbent derived from lime mud and bauxite tailings for cyclic CO2capture[J].Environmental Science and Pollution Research,2018,25(28):28015-28024.
[5]Shaoyun Shan,Aihua Ma,Yicheng Hu,et al.Development of sintering-resistant CaO-based sorbent derived from eggshells and bauxite tailings for cyclic CO2capture[J].Environmental Pollution,2016,208(Part B):546-552.
[6]Qinghua Lu,Yuehua Hu.Synthesis of aluminum tri-polyphosphate anticorrosion pigment from bauxite tailings[J].Transactions of Nonferrous Metals Society of China,2012,22(2):483-488.
[7]聂万洪,王维,冉芬,等.矿物原料制备聚合氯化铝的研究进展[J].云南化工,2016,43(2):38-41.[Nie wanghong,Wang Wei,Ran Feng,et al.Research progress in preparation of polymeric aluminum chloride from mineral raw materials[J].Yunnan Chemical Technology,2016,43(2):8-41].
[8]Dong Yang,Naixing Feng,Yaowu Wang,et al.Preparation of primary Al-Si alloy from bauxite tailings by carbothermal reduction process[J].Transactions of Nonferrous Metals Society of China,2010,20(1):147-152.
[9]Xiaochao Li,Shusen Chen,Hao Ding,et al.Preparation and characterization of corundum-mullite-spinel refractories from lowgrade bauxite and magnesite ores[J].Journal of the Ceramic Society of Japan,2016,124(1):88-91.
[10]Xianjiang Shen,Guibo Qiu,Changsheng Yue,et al.Multiple copper adsorption and regeneration by zeolite 4A synthesized from bauxite tailings[J].Environmental Science and Pollution Research,2017,24(27):21829-21835.
[11]Pengcheng Lei,Xianjiang Shen,Yang Li,et al.An improved implementable process for the synthesis of zeolite 4A from bauxite tailings and its Cr3+removal capacity[J].International Journal of Minerals Metallurgy and Materials,2016,23(7):850-857.
[12]Liyang Liu,Tao Du,Gang Li,et al.Using one waste to tackle another:preparation of a CO2capture material zeolite X from laterite residue and bauxite[J].Journal of Hazardous Materials,2014,278:551-558(DOI:10.1016/j.jhazmat.2014.06.041).
[13]Bin Chen,Xiao Li,Xianmin Tang.Digestion technology of Guizhou diasporic bauxite with low and medium grades by lime Bayer process[J].Journal of Central South University(Science and Technology),2014,45(5):1397-1402.
[14]Gaofeng Fu,Fuquan Tian,Kun Quan.Study on digestion of chinese middle/low grade bauxite in lime Bayer process[J].Journal of Northeastern University(Natural Science),2005,26(11):1093-1095.
[15]Tingan Zhang,Xiaofeng Zhu,Guozhi Lv,et al.Calcification-carbonation method for Alumina production by using low-grade bauxite[J].TMS Light Metals,2013,18(1):233-238.
[16]Qiuyue Zhao,Zimu Zhang,Xiaofeng Zhu,et al.Economic analysis of producing Alumina with low-grade bauxite(Red Mud)by calcification-carbonization method[J].TMS Light Metals,2014:165-168(DOI:10.1007/978-3-319-48144-9_29).
[17]吕国志,郭芳芳,李欣,等.钙化一碳化法利用中低品位铝土矿生产氧化铝的实验研究[J].材料与冶金学报,2015,14(3):182-192.[Lv Guozhi,Guo Fangfang,Li Xin,et al.Experimental study on calcification-carbonation process for alumina production by using mid-low grade bauxite[J].2015,14(3):182-192].
[18]Xiaofeng Zhu,Tingan Zhang,Yanxiu Wang,et al.Recovery of alkali and alumina from Bayer red m ud by the calcification-carbonation method[J].International Journal of Minerals,Metallurgy,and Materials,2016,23(3):257-268.
[19]Hongying Yang,Xiaocai He,Zhanliang Yu,et al.The experimental study on high temperature dissolution process by Bayer process[J].Yunnan Metallurgy,2015,45(3):61-66.
[20]Aichun Zhao,Yan Liu,Tingan Zhang,et al.Thermodynamics study on leaching process of gibbsitic bauxite by hydrochloric acid[J].Transactions of Nonferrous Metals Society of China,2013,23(1):266-270.
[21]赵爱春.酸法处理高铁铝土矿的基础研究[D].沈阳:东北大学材料与冶金学院,2013.
[22]Xinyang Yu,Xinan Wei,An Zeng,et al.Flotation of a low-grade bauxite ore using an organosilicon cationic collector[J].Minerals and Metallurgical Processing,2015,32(4):209-214.
[23]Xinyang Yu,Haolin Wang,Qiangqiang Wang,et al.Flotation of low-grade bauxite using organosilicon cationic collector and starch depressant[J].Transactions of Nonferrous Metals Society of China,2016,26(4):1112-1117.
[24]洪亚旭,李振中,王生宁.选矿拜耳法生产氧化铝工艺研究[J].酒钢科技,2015,2:36-40.[Hong Yaxu,Li Zhenzhong,Wang Shengning.The process research on the alumina production by ore dressing bayer process[J].Jiu Gang Ke Ji,2015,2:36-40].
[25]满李阳,肖国光,张贤珍,等.“硅酸盐”细菌浸出铝土矿及细菌群落结构的变化[J].中南大学学报:自然科学版,2015,46(2):394-403.[Man Liyang,Xiao Guoguang,Zhang Xianzhen,et al.Bioleaching of bauxite by silicate bacteria and change of bacterial community structure during leaching process[J].Journal of Central South University(Science and Technology),2015,46(2):394-403].
[26]张贤珍.硅酸盐细菌在铝土矿生物脱硅中的应用与机理研究[D].北京:北京科技大学土木与环境工程学院,2015.
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