Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides

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• 作者：Ju-You Lu ; Hong Wan ; Jianwei Zhang ; Zhixuan Wang ; Yang Li ; Yongmei Du ; Chunying Li ; Prof. Zhao-Tie Liu ; Prof. Zhong-Wen Liu and Prof. Jian Lu
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：December 5, 2016
• 年：2016
• 卷：22
• 期：49
• 页码：17542-17546
• 全文大小：584K
• ISSN：1521-3765

文摘

A palladium-catalyzed direct C-arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides.