Inside Cover: A Simple Approach to Enhance the Water Stability of a Metal-Organic Framework (Chem. Eur. J. 1/2017)

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• 作者：Dr. Yung-Han Shih ; Yu-Ching Kuo ; Stephen Lirio ; Kun-Yun Wang ; Prof. Chia-Her Lin and Prof. Hsi-Ya Huang
• 刊名：Chemistry - A European Journal
• 出版年：2017
• 出版时间：January 1, 2017
• 年：2017
• 卷：23
• 期：1
• 页码：2
• 全文大小：1660K
• ISSN：1521-3765

文摘

Metal–organic frameworks (MOFs) are usually unstable in aqueous solution, thus limiting their applications. A new strategy, involving the embedding of moisture-sensitive MOFs into a polymer monolith with different compartments by microwave-assisted in situ polymerization is described. A larger compartment led to structural collapse of the MOF; when a narrow compartment was used, the crystalline MOF structure was retained. The resultant composites show high stabilities even when soaked in acid solution for 24 h. More information can be found in the Communication by H. Y. Huang et al. on page 42 ff.