Highly Stereoselective Synthesis of Imidazolidines through the Palladium(0)-Catalyzed Three-Component Reaction of 2,3-Allenylamines, Organic Halides, and Imines

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• 作者：Jinxing Hu ; Bo Kong ; Yue Liu ; Boxuan Xu ; Prof. Yanfang Zhao and Ping Gong
• 刊名：ChemCatChem
• 出版年：2017
• 出版时间：February 6, 2017
• 年：2017
• 卷：9
• 期：3
• 页码：403-406
• 全文大小：840K
• ISSN：1867-3899

文摘

A new and efficient method for the synthesis of polysubstituted imidazolidines through the Pd⁰-catalyzed double addition/cyclization of 2,3-allenylamines with aryl iodides and imines was explored. This catalytic reaction afforded the desired products in good yields with high diastereoselectivities.