Inside Cover: Immobilizing Molecular Metal Dithiolene-Diamine Complexes on 2D Metal-Organic Frameworks for Electrocatalytic H₂ Production (Chem. Eur. J. 10/2017)

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• 作者：Dr. Renhao Dong ; Dr. Zhikun Zheng ; Dr. Diana C. Tranca ; Dr. Jian Zhang ; Dr. Naisa Chandrasekhar ; Dr. Shaohua Liu ; Dr. Xiaodong Zhuang ; Prof. Dr. Gotthard Seifert and Prof. Dr. Xinliang Feng
• 刊名：Chemistry - A European Journal
• 出版年：2017
• 出版时间：February 16, 2017
• 年：2017
• 卷：23
• 期：10
• 页码：2234
• 全文大小：918K
• ISSN：1521-3765

文摘

Two-dimensional metal–organic framework (MOF) sheets were synthesized by incorporation of the molecular metal dithiolene–diamine (MS₂N₂, M=Co and Ni), metal bis(dithiolene) (MS₄), and metal bis(diamine) (MN₄) complexes. 2D MOFs were applied as model carbon-rich electrocatalysts for the hydrogen evolution reaction in water, and these studies provided an in-depth understanding of the catalytic active sites, thus paving the way for the future development of metal complexes in carbon-rich electrode materials for energy generation. More information can be found in the Communication by G. Seifert and X. Feng et al. on page 2255 ff.