Inside Cover: BAB-random-C Monomer Sequence via Radical Terpolymerization of Limonene (A), Maleimide (B), and Methacrylate (C): Terpene Polymers with Randomly Distributed Periodic Sequences (Angew. Chem. Int. Ed. 7/2017)

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• 作者：Masataka Ojika ; Prof. Dr. Kotaro Satoh and Prof. Dr. Masami Kamigaito
• 刊名：Angewandte Chemie International Edition
• 出版年：2017
• 出版时间：February 6, 2017
• 年：2017
• 卷：56
• 期：7
• 页码：1680
• 全文大小：2899K
• ISSN：1521-3773

文摘

One of the most naturally abundant terpenes, limonene (A), can be radically copolymerized with maleimide (B) and methacrylate (C) in a fluorinated alcohol to result in a terpolymer with unprecedented BAB-random-C sequences. In their Communication on page 1789 ff., K. Satoh, M. Kamigaito, and M. Ojika show that the sequence is a consequence of selective BAB polymerization between limonene and maleimide, almost exclusive homopolymerization of methacrylate during copolymerization of limonene and methacrylate, and random copolymerization between methacrylate and maleimide.