Dipolar-Distribution Cavity γ-Fe₂O₃@C@α-MnO₂ Nanospindle with Broadened Microwave Absorption Bandwidth by Chemically Etching

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• 作者：Wenbin You ; Han Bi ; Wen She ; Yu Zhang and Renchao Che
• 刊名：Small
• 出版年：2017
• 出版时间：February 3, 2017
• 年：2017
• 卷：13
• 期：5
• 全文大小：4301K
• ISSN：1613-6829

文摘

Developing microwave absorption materials with ultrawide bandwidth and low density still remains a challenge, which restricts their actual application in electromagnetic signal anticontamination and defense stealth technology. Here a series of olive-like γ-Fe₂O₃@C core–shell spindles with different shell thickness and γ-Fe₂O₃@C@α-MnO₂ spindles with different volumes of dipolar-distribution cavities were successfully prepared. Both series of absorbers exhibit excellent absorption properties. The γ-Fe₂O₃@C@α-MnO₂ spindle with controllable cavity volume exhibits an effective absorption (<−10 dB) bandwidth as wide as 9.2 GHz due to the chemically dipolar etching of the core. Reflection loss of the γ-Fe₂O₃@C spindle reaches as high as −45 dB because of the optimized electromagnetic impedance balance between polymer shell and γ-Fe₂O₃ core. Intrinsic ferromagnetism of the anisotropy spindle is confirmed by electron holography. Strong coupling of magnetic flux stray lines between spindles is directly imaged. This unique morphology and facile etching technique might facilitate the study of core–shell type microwave absorbers.