Co-N-Doped Mesoporous Carbon Hollow Spheres as Highly Efficient Electrocatalysts for Oxygen Reduction Reaction

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• 作者：Feng Hu ; Hongchao Yang ; Changhong Wang ; Yejun Zhang ; Huan Lu and Qiangbin Wang
• 刊名：Small
• 出版年：2017
• 出版时间：January 18, 2017
• 年：2017
• 卷：13
• 期：3
• 全文大小：2268K
• ISSN：1613-6829

文摘

Rational design of cost-effective, nonprecious metal-based catalysts with desirable oxygen reduction reaction (ORR) performance is extremely important for future fuel cell commercialization, etc. Herein, a new type of ORR catalyst of Co-N-doped mesoporous carbon hollow sphere (Co-N-mC) was developed by pyrolysis from elaborately fabricated polystyrene@polydopamine-Co precursors. The obtained catalysts with active Co sites distributed in highly graphitized mesoporous N-doped carbon hollow spheres exhibited outstanding ORR activity with an onset potential of 0.940 V, a half-wave potential of 0.851 V, and a small Tafel slope of 45 mV decade⁻¹ in 0.1 m KOH solution, which was comparable to that of the Pt/C catalyst (20%, Alfa). More importantly, they showed superior durability with little current decline (less than 4%) in the chronoamperometric evaluation over 60 000 s. These features make the Co-N-mC one of the best nonprecious-metal catalysts to date for ORR in alkaline condition.