Inside Back Cover: Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines (Angew. Chem. Int. Ed. 1/2017)

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• 作者：Longin Justin Clair Bonazaba Milandou ; Dr. Hé ; lè ; ne Carreyre ; Dr. Sé ; bastien Alazet ; Gino Greco ; Dr. Agnè ; s Martin-Mingot ; Dr. Cé ; lestine Nkounkou Loumpangou ; Prof. Jean-Maurille Ouamba ; Dr. Fodil Bouazza ; Dr. Thierry Billard and Dr. Sé ; bastien Thibaudeau
• 刊名：Angewandte Chemie International Edition
• 出版年：2017
• 出版时间：January 2, 2017
• 年：2017
• 卷：56
• 期：1
• 页码：417
• 全文大小：2844K
• ISSN：1521-3773

文摘

Superacid activation of N-SCF₃ sulfenamide reagents generates diprotonated superelectrophilic species for the trifluoromethylthiolation of aromatic amines, as shown by T. Billard, S. Thibaudeau, and co-workers in their Communication on page 173 ff. This method can be used for the late-stage functionalization of complex biomolecules such as alkaloids and steroids.