ChemInform Abstract: Photoinduced C—S Bond Cleavage of Thioglycosides and Glycosylation.

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• 作者：Run-Ze Mao ; Fan Guo ; De-Cai Xiong ; Qin Li ; Jinyou Duan and Xin-Shan Ye
• 关键词：glycosylation ; carbohydrates ; photochemistry ; radiation chemistry ; chemoluminescence
• 刊名：ChemInform
• 出版年：2016
• 出版时间：March, 2016
• 年：2016
• 卷：47
• 期：13
• 全文大小：21K
• ISSN：1522-2667

文摘

Activation of thioglycosides upon UV irradiation followed by cupric triflate oxidation leads to the in situ formation of an oxacarbenium ion which is able to undergo glycosylation reactions with a wide variety of substrates such as sugars, amino acids, terpenes, and sterols.