Cover Picture: Two Different Pathways in the Reduction of [(S=)PCl(μ-NtBu)]2 with Na (Chem. Eur. J. 34/2016)

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• 作者：Deependra Bawari ; Dr. Billa Prashanth ; Satyam Ravi ; Dr. K. R. Shamasundar ; Dr. Sanjay Singh and Prof. Dominic S. Wright
• 刊名：Chemistry - A European Journal
• 出版年：2016
• 出版时间：August 16, 2016
• 年：2016
• 卷：22
• 期：34
• 页码：11873
• 全文大小：486K
• ISSN：1521-3765

文摘

A sulfur-bridged inorganic macrocycle and a room temperature singlet biradicaloid dianion have been isolated in the Wurtz reduction of a mixture of cis- and trans-dichlorophosph(V)azane. It appears that these products from the same reaction are the outcome of two different reduction pathways. This approach may facilitate the discovery of new types of inorganic macrocycles and new polymeric assemblies similar to those observed in this work. More information can be found in the Full Paper by S. Singh, D. S. Wright et al. on p://dx.doi.org/10.1002/chem.201600839" rel="references:http://dx.doi.org/10.1002/chem.201600839">page 12027 ff.