Nickel- or Iron-Catalyzed Cross-Coupling of Aryl Carbamates with Arylsilanes

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• 作者：Wen-Juan Shi ; Hong-Wei Zhao ; Yang Wang ; Zhi-Chao Cao ; Li-Sheng Zhang ; Da-Gang Yu and Zhang-Jie Shi
• 刊名：Advanced Synthesis & Catalysis
• 出版年：2016
• 出版时间：July 28, 2016
• 年：2016
• 卷：358
• 期：15
• 页码：2410-2416
• 全文大小：1189K
• ISSN：1615-4169

文摘

Aryl carbamates were for the first time applied as electrophiles in the cross-coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non-sensitivity to steric hindrance on both aryl carbamates and arylsilanes.