SALE-Ing a MOF-Based “Ship of Theseus.” Sequential Building-Block Replacement for Complete Reformulation of a Pillared-Paddlewheel Metal-Organic Framework

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• 作者：Yan Xu ; Nicolaas A. Vermeulen ; Yangyang Liu ; Joseph T. Hupp and Omar K. Farha
• 刊名：European Journal of Inorganic Chemistry
• 出版年：2016
• 出版时间：September 2016
• 年：2016
• 卷：2016
• 期：27
• 页码：4345-4348
• 全文大小：1133K
• ISSN：1099-0682c

文摘

A complete structure and composition evolution of a pillared-paddlewheel metal-organic framework was achieved using a combination of solvent-assisted linker exchange (SALE) and node transmetalation. In this example, each building unit – the di-topic carboxylate strut, the di-topic nitrogen-based pillar, and the di-zinc node – of the original metal-organic framework is replaced in sequential fashion to produce a nickel-based daughter metal-organic framework with entirely different components.