Pentaindenocorannulene: Properties, Assemblies, and C₆₀ Complex

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• 作者：Dr. Samuel Lampart ; Loï ; c M. Roch ; Dr. Amit K. Dutta ; Yujia Wang ; Dr. Rangana Warshamanage ; Dr. Aaron D. Finke ; Prof. Dr. Anthony Linden ; Prof. Dr. Kim K. Baldridge and Prof. Dr. Jay S. Siegel
• 刊名：Angewandte Chemie International Edition
• 出版年：2016
• 出版时间：November 14, 2016
• 年：2016
• 卷：55
• 期：47
• 页码：14648-14652
• 全文大小：2450K
• ISSN：1521-3773

文摘

Pentaindenocorannulene (C₅₀H₂₀ , 1), a deep bowl polynuclear aromatic hydrocarbon, accepts 4 electrons, crystallizes in columnar bowl-in-bowl assemblies and forms a nested C₆₀@1₂ complex. Spectra, structures and computations are presented.