ChemInform Abstract: One-Pot Dichotomous Construction of Inside-Azayohimban and Pro-Azayohimban Systems via an Enantioselective Organocatalytic Cascade; Their Use as a Model to Probe the (Aza-)Indole Local Solvent Environment.

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• 作者：Van-Wei Yang ; Bor-Cherng Hong ; Hsin-Kai Kao ; Ting-Hsun Tu ; Jiun-Yi Shen ; Chi-Lin Chen ; Gene-Hsiang Lee and Pi-Tai Chou
• 关键词：isoquinoline derivatives ; fused pyridine derivatives ; fused pyrrole derivatives ; diastereoselective syntheses ; enantioselective syntheses (incl. cis/trans-isomerism) ; organocatalysis
• 刊名：ChemInform
• 出版年：2016
• 出版时间：April, 2016
• 年：2016
• 卷：47
• 期：17
• 全文大小：32K
• ISSN：1522-2667

文摘

Five contiguous stereocenters containing inside-azayohimban (X) and pro-azayohimban (IVa) as well as derivatives thereof are prepared and their photochemical properties are examined.