Kinetics and mechanism of the exothermic first-stage decomposition reaction for 1,5-dimethyl-2,6-bis(2,2,2-trinitroethyl)-4,8-dinitroglycoluril

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• 作者：Hongan ; Zhao ; Rongzu ; Hu ; Desuo ; Yang ; Shengli ; Gao ; Qizhen ; Shi
• 关键词：Decomposition ; 1 ; 4-Dinitro-3 ; 6-bis(trinitroethyl)glycoluril ; DSC ; Kinetics ; Mechanism ; TG
• 刊名：Thermochimica Acta
• 出版年：2004
• 出版时间：June 24, 2004
• 年：2004
• 卷：416
• 期：1-2
• 页码：1-4
• 全文大小：82.7 K

文摘

Under linear temperature increase condition the thermal behavior, mechanism and kinetic parameters of the exothermic first-stage decomposition reaction of the title compound have been studied by means of DSC, TG–DTG and IR. The reaction mechanism was proposed.