Hydrogenation and hydrodeoxygenation of difurfurylidene acetone to liquid alkanes over Raney Ni and the supported Pt catalysts
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- 作者：Yuping Li liyp@ms.giec.ac.cn" class="auth_mail" title="E-mail the corresponding author ; Xiaoming Huang ; Qian Zhang ; Lungang Chen ; Xinghua Zhang ; Tiejun Wang ; wangtj@ms.giec.ac.cn" class="auth_mail" title="E-mail the corresponding author ; Longlong Ma
- 关键词：Hydrogenation/hydrodeoxygenation ; Difurfurylidene acetone ; Liquid alkanes ; Raney Ni ; Pt catalysts ; Catalytic conversion
- 刊名：Applied Energy
- 出版年：2015
- 出版时间：15 December 2015
- 年：2015
- 卷：160
- 期：Complete
- 页码：990-998
- 全文大小：1092 K
文摘
- •
The C8
C14 alkane yield of 82.9% was obtained in the two-step hydrogenation/HDO process.- •
Protonation effect from methanol solvent increased F2A conversion in the two-step process.
- •
The rate-determining step was acyl C
O bond hydrogenation in the first step of F2A hydrogenation.- •
The acidic centers from SiO2
ZrO2 activated the acyl and oxygen atoms of intermediates.- •
Acidity of SiO2
ZrO2 and Pt active centers of 1 wt%Pt/SiO2ZrO2 resulted stable HDO performance.
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