Hydrolysis of cellulose in 1-allyl-3-methylimidazolium chloride catalyzed by methyltrioxorhenium
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- 作者：Yuguo Yuan ; Jingyun Wang ; Nihong Fu ; Shuliang Zang ; ShuliangZang@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Microcrystalline cellulose ; Hydrolysis ; Methyltrioxorhenium ; Ionic liquid
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：10 February 2016
- 年：2016
- 卷：76
- 期：Complete
- 页码：46-49
- 全文大小：267 K
文摘
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Methyltrioxorhenium (MTO) is for the first time applied as catalyst to promote the cellulose hydrolysis in ionic liquid.
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MTO displays good catalytic performance for cellulose hydrolysis.
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The nucleophilic attack of O atom of β-1,4-glycosidic bond to Re atom of MTO leads to the broken of β-1,4-glycosidic bond.
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