Hydrogen bonding-inspired organocatalysts for CO2 fixation with epoxides to cyclic carbonates
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- 作者：Xiao-Fang Liua ; b ; Qing-Wen Songa ; b ; Shuai Zhanga ; b ; Liang-Nian Hea ; b ; heln@nankai.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Carbon dioxide fixation ; Synergetic effect ; Cycloaddition ; Cyclic carbonate ; Organocatalysis ; Multi-site hydrogen bonding
- 刊名：Catalysis Today
- 出版年：2016
- 出版时间：1 April 2016
- 年：2016
- 卷：263
- 期：Complete
- 页码：69-74
- 全文大小：1030 K
文摘
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EDTA/TBAB, bifunctional metal-free catalyst is effective for CO2 fixation.
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Synergistic effects of COOH and Br− render the reaction performing at 5 bar CO2.
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Multi-carboxyl in one molecule is more efficient than monocarboxylic acid.
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The intramolecular hydrogen bonding is more active than intermolecular counterpart.
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