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Oxidation kinetics of dibenzothiophenes using cumene hydroperoxide as an oxidant over MoO3/Al2O3 catalyst
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文摘

Catalytic oxidation kinetics of the representative dibenzothiophenes in the presence of oil-soluble cumene hydroperoxide on a MoO3/Al2O3 catalyst was firstly studied in detail.

This oxidation system is promising for developing a cost-effective process to produce ultra-clean diesel.

The presence of alkyl groups around the sulfur atom in dibenzothiophenes have significant effect on their oxidative reactivity, and more than 95% conversion of all dibenzothiophenes can be achieved at 75 °C.

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