Equilateral triangle Mg2Si phases appear on the surface of Al–Zn–Si–xMg coatings.
Mg-rich phase can obviously improve the corrosion resistance of Al–Zn–Si–xMg coatings.
Zn–Al LDH more easily precipitates on the Al–Zn–Si–xMg coatings with Mg2+.
Mg2Si has better anti-corrosion effects than MgZn2.
De-alloying stage of Mg2Si contributes to prolong the cathodic protection effect.
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