Ligand 4-X pyridine (X ce:hsp>= ce:hsp>Cl, Br, I) dependence in Hofmann-type spin crossover complexes: Fe(4-Xpyridine)2[Au(CN)2]2
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- 作者：Jun Okabayashia ; jun@chem.s.u-tokyo.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Shotaro Uenob ; Takeshi Kawasakib ; Takafumi Kitazawab ; c ; kitazawa@chem.toho-u.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Spin crossover complexes ; X-ray absorption fine structure ; Fe&ndash ; Au complexes ; Aurophilic interaction
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 April 2016
- 年：2016
- 卷：445
- 期：Complete
- 页码：17-21
- 全文大小：688 K
文摘
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Novel spin crossover complexes Fe(4-Xpy)2[Au(CN)2]2 with axial 4-X pyridine ligands (X = Cl, Br, and I).
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The halogen-element dependence in the lattice parameters on the magnetic properties.
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Structure parameters determined by EXAFS of Fe K edge and Au Ledge.
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Aurophilic interaction studied.
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