Long wavelength visible light to UV and short wavelength upconversion by Er3+:Al2O3.
Higher photoactivity of rutile due to extra short-wavelength visible light adsorption.
Er3+:Al2O3/TiO2-SAC possessed high photocatalytic capability under visible light.
RSM model is significant and predicts well for the actual experimental values.
Photocatalytic degradation followed the Langmiur–Hinshelwood kinetics.
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