Catalytic degradation of recalcitrant pollutants by Fenton-like process using polyacrylonitrile-supported iron (II) phthalocyanine nanofibers: Intermediates and pathway
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- 作者：Zhexin Zhu ; Yi Chen ; Yan Gu ; Fei Wu ; Wangyang Lu ; luwy@zstu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Tiefeng Xu ; Wenxing Chen ; wxchen@zstu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polyacrylonitrile nanofibers ; Iron (II) phthalocyanine ; Hydroxyl radicals ; Recalcitrant pollutants ; Transformation products ; Degradation pathways
- 刊名：Water Research
- 出版年：2016
- 出版时间：15 April 2016
- 年：2016
- 卷：93
- 期：Complete
- 页码：296-305
- 全文大小：2747 K
文摘
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FePc/PAN nanofiber catalysts were prepared by electrospinning method.
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FePc molecules were isolated in PAN nanofibers to prevent the formation of dimers.
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FePc/PAN nanofibers are efficient and stable for recalcitrant pollutant degradation.
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The pathways of CBZ and RhB degradation were proposed.
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Transformation products of CBZ and RhB were finally transformed to small acids.
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