Polymerization of ethylene and propene promoted by binaphthyl-bridged Schiff base complexes of titanium

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• 作者：Maria Strianese ; Marina Lamberti ; Mina Mazzeo ; Consiglia Tedesco and Claudio Pellecchia
• 关键词：Binaphthyl-bridged Schiff base ; Ti(IV) complexes ; Catalyst ; Polymerization ; Polyethylene (PE)
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2006
• 出版时间：2 October 2006
• 年：2006
• 卷：258
• 期：1-2
• 页码：284-291
• 全文大小：194 K

文摘

Three new binaphthyl-bridged Schiff base complexes featuring different phenolate substituents (meta-Me, ortho,para-di-Cl, ortho,para-di-Br) were synthesized. ¹H and ¹³C NMR analyses indicated that the cis-β isomers are preferentially formed in any case. These complexes were tested as precatalysts for ethylene and propene polymerization comparing their behaviour to that of related titanium and zirconium complexes previously reported.

The beneficial effect on polymerization activity of halogen atoms in the ortho, para positions of the phenolate rings was also demonstrated.