Organometallic complexes for nonlinear optics. Part 29. Quadratic and cubic hyperpolarizabilities of stilbenylethynyl–gold and -ruthenium complexes

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• 作者：Hurst ; Stephanie K. ; Lucas ; Nigel T. ; Humphrey ; Mark G. ; Isoshima ; Takashi ; Wostyn ; Kurt ; Asselberghs ; Inge ; et. al.
• 关键词：Ruthenium ; Gold ; Hyperpolarizability ; Acetylide ; Electrochemistry ; Nonlinear optics
• 刊名：Inorganica Chimica Acta
• 出版年：2003
• 出版时间：July 4, 2003
• 年：2003
• 卷：350
• 期：Complete
• 页码：62-76
• 全文大小：422 K

文摘

The compounds (E)-4-XCCC₆H₄CHCHPh [X=SiMe₃ (1), H (2)], 1,3,5-{(E)-4-XC₆H₄CHCH}₃C₆H₃ [X=I (3), CCSiMe₃ (4), CCH (5)], [Au{(E)-4-CCC₆H₄CHCHPh}(L)] [L=PPh₃ (6), PMe₃ (7)], [Au(4-CCC₆H₄CCPh)(L)] [L=PPh₃ (8), PMe₃ (9)], 1,3,5-[(Ph₃P)Au{(E)-4-CCC₆H₄CHCH}]₃C₆H₃ (10), trans-[Ru{(E)-4-CCHC₆H₄CHCHPh}Cl(dppm)₂]PF₆ (11), trans-[Ru{(E)-4-CCC₆H₄CHCHPh}Cl(L₂)₂] [L₂