A model compound (methyl oleate, oleic acid, triolein) study of triglycerides hydrodeoxygenation over alumina-supported NiMo sulfide
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- 作者：A.E. Coumans ; E.J.M. Hensen ; e.j.m.hensen@tue.nl" class="auth_mail" title="E-mail the corresponding author
- 关键词：Triglycerides ; Hydrodeoxygenation ; Metal sulfides ; Model compounds ; Deactivation
- 刊名：Applied Catalysis B: Environmental
- 出版年：2017
- 出版时间：February 2017
- 年：2017
- 卷：201
- 期：Complete
- 页码：290-301
- 全文大小：2580 K
文摘
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Methyl ester and triglyceride hydrodeoxygenation studied by sulfided NiMoS/Al2O3.
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Hydrolysis ester in triglycerides easier than in methyl esters, catalyzed by Al2O3.
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Different active sites for hydrodeoxygenation and decarbonation.
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Hydrogenation activity decreases stronger than deoxygenation activity.
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Metal sulfide stable, deactivation due to heavy product deposition.
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