Preparation of wrapped carbon nanotubes poly(4-vinylpyridine)/MTO based heterogeneous catalysts for the oxidative desulfurization (ODS) of model and synthetic diesel fuel
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- 作者：Davide Piccininoa ; Issam Abdalghanib ; Giorgia Bottaa ; Marcello Crucianellib ; marcello.crucianelli@univaq.it" class="auth_mail" title="E-mail the corresponding author ; Maurizio Passacantandob ; Maria Laura Di Vacric ; Raffaele Saladinoa ; saladino@unitus.it" class="auth_mail" title="E-mail the corresponding author
- 关键词：Multiwall carbon nanotubes ; Heterogeneous hybrid catalysts ; Methyltrioxorhenium ; Oxidative desulfurization ; Hydrogen peroxide
- 刊名：Applied Catalysis B: Environmental
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：200
- 期：Complete
- 页码：392-401
- 全文大小：1402 K
文摘
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Novel wrapped carbon nanotubes poly(4-vinylpyridine)/methyl trioxorhenium (MTO) based catalysts have been prepared.
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The catalysts acted as efficient systems in the oxidation of recalcitrant aromatic sulfur derivatives to sulfones, with H2O2.
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The activity of the catalysts was tuned on the basis of the procedure used for the immobilization of the active species.
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