Safety evaluating of Beckmann rearrangement of cyclohexanone oxime in microreactors using inherently safer design concept
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- 作者：J.S. Zhang ; K. Wang ; C.Y. Zhang ; G.S. Luo ; gsluo@tsinghua.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Safety evaluating ; Inherently safer design ; Beckmann rearrangement ; Microreactor ; Risk transfer
- 刊名：Chemical Engineering & Processing
- 出版年：2016
- 出版时间：December 2016
- 年：2016
- 卷：110
- 期：Complete
- 页码：44-51
- 全文大小：712 K
文摘
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An inherently safer design (ISD) is applied to Beckmann rearrangement.
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Organocatalyzed rearrangement in batch is unacceptable considering ISD concept.
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Microreactor can increase process safety with making inventories much smaller.
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The hazard conflicts due to microreactors have been evaluated.
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